Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-20T07:17:56.295Z Has data issue: false hasContentIssue false
  • English
  • Français

Photocatalytic degradation of indigo carmine using [Zn-Al] LDH supported on PAN nanofibres

Published online by Cambridge University Press:  02 January 2018

K. Abderrazek ,
A. Uheida ,
M. Seffen ,
M. Muhammed ,
N. Frini Srasra  and
E. Srasra
K. Abderrazek*
Affiliation:
National Research Center of Materials Science, Technopark of Borj Cedria, Tunisia Faculty of Sciences of Tunis, Tunis El Manar University, Tunisia
A. Uheida
Affiliation:
Functional Materials Division, Royal Institute of Technology (KTH), Sweden
M. Seffen
Affiliation:
Laboratory of Energy and Materials (LABEM), High School of Sciences and Technology, 4011 Hammam Sousse (Sousse University), Tunisia
M. Muhammed
Affiliation:
Functional Materials Division, Royal Institute of Technology (KTH), Sweden
N. Frini Srasra
Affiliation:
National Research Center of Materials Science, Technopark of Borj Cedria, Tunisia Faculty of Sciences of Tunis, Tunis El Manar University, Tunisia
E. Srasra
Affiliation:
National Research Center of Materials Science, Technopark of Borj Cedria, Tunisia
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Zn-Al layered double hydroxides (LDH), before and after calcination, were tested for the removal of indigo carmine (IC) dye from solution. These LDH photocatalysts were characterized by powder x-ray diffraction (PXRD), Fourier transform infrared (FTIR) spectroscopy, thermogravimetry/differential thermogravimetry (TG/DTG), nitrogen physisorption at −196°C, scanning electron microscopy (SEM) and diffuse reflectance spectrophotometry (DRS). The different photocatalysts were supported on polyacrylonitrile (PAN) nanofibres, so that filtration was unnecessary.

The PXRD and FTIR analyses showed that the IC adsorption on c-Zn-Al-3-500 (LDH calcined at 500°C) was enhanced by construction of the hydrotalcite matrix intercalated with the dye. The intercalation was clearly evidenced by the appearance of a peak at low °2θ values. All of the materials prepared exhibited photocatalytic activity, which for the c-Zn-Al-3-500 was comparable to that of commercial PAN-supported ZnO nanoparticles (100% degradation after 180 min). Kinetic studies showed that the degradation of the IC followed a pseudo-first order rate. The high activity and the ease of both synthesis and separation processes rendered this photocatalyst a promising candidate for environmental remediation.

Keywords

[Zn-Al] LDHnanofibresindigo carmineretentionphotocatalysis
Type
Research Article
Information
Clay Minerals , Volume 50 , Issue 2 , June 2015 , pp. 185 - 197
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ahmed, A.A.A., Talib, Z.A., Bin Hussein, M.Z. & Zakaria, A. (2012) Zn-Al layered double hydroxide prepared at different molar ratios: Preparation, characterization, optical and dielectric properties. Journal of Solid State Chemistry, 191, 271–278.CrossRefGoogle Scholar
Barriga, C., Jones, W., Malet, P., Rives, V. & Ulibarri, M.A. (1998) Synthesis and characterization of polyoxovanadate-pillared Zn-Al layered double hydroxides: An X-ray absorption and diffraction study. Inorganic Chemistry, 37, 1812–1820.CrossRefGoogle Scholar
Braterman, P.S., Xu, Z.P. & Yarberry, F. (2004) Layered double hydroxides (LDHs). Pp. 373–474 in: Handbook of Layered Materials, Marcel Dekker Inc., New York.Google Scholar
Carriazo, D., Del Arco, M., Garcia-Lopez, E., Marci, G., Martin, C., Palmisano, L. & Rives, V. (2011) Zn, Al hydrotalcites calcined at different temperatures: Preparation, characterization and photocatalytic activity in gas–solid regime. Journal of Molecular Catalysis A, 342–343, 83–90.Google Scholar
Cavani, F., Trifiro, F. & Vaccari, A. (1991) Hydrotalcitetype anionic clays: preparation, properties and applications. Catalysis Today, 11, 173–301.CrossRefGoogle Scholar
Cheng, X., Huang, X., Wang, X. & Sun, D. (2010) Influence of calcination on the adsorptive removal of phosphate by Zn–Al layered double hydroxides from excess sludge liquor. Journal of Hazardous Materials, 177, 516–523.CrossRefGoogle ScholarPubMed
Forgacs, E., Cserháti, T. & Oros, G. (2004) Removal of synthetic dyes from wastewaters: a review. Environment International, 30, 953–971.Google Scholar
Frunza, L., Gheorghe, N., Iova, F., Ganea, P., Neatu, F. & Parvulescu, V.I. (2011) Spectroscopic analysis of the interstitial anions in some layered double hydroxide materials. Revista de Chimie, 62, 766–772.Google Scholar
Gutmann, N. & Müller, B. (1996) Insertion of the dinuclear dihydroxo-bridged Cr(III) aquo complex into the layered double hydroxides of hydrotalcitetype. Journal of Solid State Chemistry, 122, 214.CrossRefGoogle Scholar
Hongb, F., Chengshi, P., Wenqing, Y. & Yongfa, Z. (2005) Visible-light-induced degradation of Rhodamine B by nanosized Bi2WO6. The Journal of Physical Chemistry B, 22432–22439.Google Scholar
Hosni, K. & Srasra, E. (2010) Evaluation of phosphate removal from water by calcined-LDH synthesized from the dolomite. Colloid Journal, 72, 423–431.Google Scholar
Jenkins, C.L. (1978) Textile dyes are potential hazards. Archives of Environmental Health, 40, 7–12.Google Scholar
Kang, M.J., Rhee, S.W. & Hahn, P.S. (2003) Sorption of aqueous toxic anions on calcined Mg/Al layered double hydroxide: an approach to mechanism. Environmental Engineering Research, 8, 22–30.Google Scholar
Kloprogge, J.T., Hickey, L. & Frost, R.L. (2004) The effects of synthesis pH and hydrothermal treatment on the formation of zinc aluminum hydrotalcites. Journal of Solid State Chemistry, 177, 4047–4057.Google Scholar
Lacombe, S., Tran-Thi, , Guillard, C., Herrmann, J.M., V., Keller-Spitzer, Keller, N., Maurette, M.T., Pichat, P., Pigot, T., Pulgarin, C., Rincon, A.G. & Robert, D. (2007) La photocatalyse pour l’élimination des pollutants. L’Actualité Chimique, 308–309.Google Scholar
Hadnaev-Kostić, M.S., Vulić, T.J., Zorić, D.B., & Marinković-Nedučin, R.P. (2012) The influence of the UV irradiation intensity on photocatalytic activity of Zn Al layered double hydroxides and derived mixed oxides. Chemical Industry & Chemical Engineering Quarterly, 18(2) 295–303.Google Scholar
Miyata, S. (1975) The syntheses of hydrotalcite-like compounds and their structures and physico chemical properties – I. The systems Mg2+-Al3+-NO3 −, Mg2+-Al3+-Cl−, Mg2+-Al3+-ClO3 −, Ni2+-Al3+-Cl− and Zn2+-Al3+-Cl− . Clays and Clay Minerals, 23, 369–375.Google Scholar
Muslim, M., Habib, M.A., Mahmood, A.J., Islam, T.S.A. & Ismail, I.M.I. (2012) Zinc oxide mediated photocatalytic decolorization of Ponceau S in aqueous suspension by visible light. International Nano Letters, 2–30.Google Scholar
Ohtani, B. (2011) Photocatalysis A to Z – What we know and what we do not know in a scientific sense. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 11, 157–158.Google Scholar
Olanrewaju, J., Newalkar, B.L., Mancino, C. & Komarneni, S. (2000) Simplified synthesis of nitrate form of layered double hydroxide. Materials Letters, 45, 307–310.CrossRefGoogle Scholar
Parida, K.M. & Mohapatra, L. (2012) Carbonate intercalated Zn/Fe layered double hydroxides: A novel photocatalyst for the enhanced photodegradation of azo dyes. Chemical Engineering Journal, 179, 131–139.CrossRefGoogle Scholar
Reutergårdh, L.B. & Iangphasuk, M. (1997) Photocatalytic decolourization of reactive azo dye: a comparison between TiO2 and CdS photocatalysts. Chemosphere, 35, 585–596.Google Scholar
Smith, R.A. (1978) Semiconductors. 2nd edition. Cambridge University Press, Cambridge, UK.Google Scholar
Swati, Munesh & Meena, R.C. (2012) Photocatalytic degradation of textile dye through an alternative photocatalyst methylene blue immobilized resin dowex 11 in presence of solar light. Archives of Applied Science Research, 4, 472–479.Google Scholar
Theiss, F.L., Sear-Hall, M.J., Palmer, S.J. & Frost, R.L. (2012) Zinc aluminium layered double hydroxides for the removal of iodine and iodide from aqueous solutions. Desalination and Water Treatment, 39, 166–175.Google Scholar
Vaccari, A. (1999) Clays and catalysis; a promising future. Applied Clay Science, 14, 161–198.Google Scholar
Vautier, M., Guillard, C. & Herrmann, J. (2001) Photocatalytic degradation of dyes in water: case study of indigo and of indigo carmine. Journal of Catalysis, 201, 46–59.Google Scholar
Vinu, R., Spurti, U.A. & Giridhar, M. (2010) Investigation of dye functional group on the photocatalytic degradation of dyes by nano-TiO2. Journal of Hazardous Materials, 176, 765–773.Google Scholar
Wang, S.L. & Wang, P.C. (2007) In situ XRD and ATRFTIR study on the molecular orientation of interlayer nitrate in Mg/Al layered double hydroxide in water. Colloids and Surfaces A, 292, 131.Google Scholar
Yang, L. & Kruse, B. (2004) Revised Kubelka–Munk theory – I. Theory and application. Journal of the Optical Society of America, A 21, 1933–1941.Google Scholar