Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-05T11:13:15.898Z Has data issue: false hasContentIssue false
  • English
  • Français

Organo-metallic clay complexes

VII. Thermal analysis of montmorillonite-diamine and glycol complexes*

Published online by Cambridge University Press:  09 July 2018

W. Bodenheimer ,
L. Heller  and
S. Yariv
W. Bodenheimer
Affiliation:
Geological Survey of Israel, Jerusalem, and Department of Inorganic Chemistry, The Hebrew University of Jerusalem
L. Heller
Affiliation:
Geological Survey of Israel, Jerusalem, and Department of Inorganic Chemistry, The Hebrew University of Jerusalem
S. Yariv
Affiliation:
Geological Survey of Israel, Jerusalem, and Department of Inorganic Chemistry, The Hebrew University of Jerusalem
Get access Rights & Permissions [Opens in a new window]

Abstract

Differential thermal analysis curves were obtained for a series of diamine and glycol complexes with natural and copper substituted montmorillonite, in air and in an inert atmosphere. Thermobalance curves of the diamine-clay systems were also determined. The exothermic peaks observed in air are characteristic for any particular system and reflect the nature and binding of the interlamellar material; no direct correlation was, however, observed with pyrolysis and oxidation processes in the clay. Organic matter is frequently liberated from the clay before oxidation, which then occurs within the reaction cell but outside the clay phase. The extent to which oxidation is completed at any particular temperature depends upon the supply of oxygen and the amount of organic material present.

Type
Research Article
Information
Clay Minerals , Volume 6 , Issue 3 , July 1966 , pp. 167 - 177
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1966

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

*

Part I : 1963, Israel J. Chem. 1, 69. Part II: 1962, Clay Min. Bull. 5, 145. Part III: 1963, Proc. Int. Clay Conf., Stockholm 2, 351. Part IV: 1963, Israel J. Chem. 1, 391. Part V: 1964, Israel J. Chem. 2, 201. Part VI: 1966, Proc. Int. Clay Conf., Jerusalem, 1, 251.

References

Aleshin, S.N. & Shackmukametov, M.S. (1961) Dokl. Akad. Timirgazeva 64, 75.Google Scholar
Allaway, W.H. (1949) Proc. Soil Sci. Soc. Am. 13, 183.Google Scholar
Bradley, W.F. & Grim, R.E. (1948) J. phys. Chem., Wash. 52, 1404.Google Scholar
Greene-Kelly, R. (1957) The Differential Thermal Investigation of Clays (Mackenzie, R.C., editor), chap. V, p. 160. Mineralogical Society, London.Google Scholar
Hendricks, S.B. Nelson R.A., & Alexander L.T., (1940) J. Am. chem. Soc. 62, 1457.Google Scholar
Jordan, J.W. (1949) Min. Mag. 28, 598.Google Scholar
Martin Vivaldi, J.L., Girela Vilchez, F. & Fenoll Hach-Ali, P. (1964) Clay Min. Bull. 5, 401.Google Scholar
Martin Vivaldi, J.L., Girela Vilchez, F., Hernaiz Bermudez de Castro, M. & Rodriguez Gallego, M. (1959) Clay Min. Bull. 4, 81.Google Scholar
Mcneal, B.L. (1964) Soil Sci. 97, 96.Google Scholar
Ramachandran, U.S., Garg, S.P. & Kacker, K.P. (1961) Chemy Ind. 790.Google Scholar
Ramachandran, U.S., Kacker, K.P. & Patwardhan, N.K. (1961) Nature, Lond. 191, 696.Google Scholar
Yariv, S. (1963) Organo-metallic Clay Complexes. Ph.D. thesis, Hebrew University, Jerusalem.Google Scholar