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A multi-site mechanism model for studying Pb and Cu retention from aqueous solutions by Fe-Mg-rich clays

Published online by Cambridge University Press:  29 June 2018

Z. Kypritidou  and
A. Argyraki
Z. Kypritidou*
Affiliation:
National and Kapodistrian University of Athens, Department of Geology and Geoenvironment, Panepistimiopolis Zographou 15784, Athens, Greece
A. Argyraki
Affiliation:
National and Kapodistrian University of Athens, Department of Geology and Geoenvironment, Panepistimiopolis Zographou 15784, Athens, Greece
*
*E-mail: [email protected]
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Abstract

The retention mechanisms of metal ions during interaction of clay with metal-rich aqueous solutions is usually investigated by sorption isotherms. Although classical isotherm models may provide sufficient information about the characteristics of the solid–liquid system, they do not distinguish among the various retention mechanisms. This study presents a methodological approach of combining batch experiment data and geochemical modelling for the characterization of the interaction of Mg-Fe-rich clay materials with monometallic solutions of Pb and Cu. For this purpose, a palygorskite clay (PCM), an Fe-smectite clay (SCM) and a natural palygorskite-Fe-smectite mixed clay (MCM) were assessed for their effectiveness as metal ion sorbents. The sorption capacity of the materials follows the order MCM > SCM > PCM and ranges between 27.6–52.1 mg g–1 for Pb and 7.7–17.6 mg g–1 for Cu. Based on the experimental results that allowed the speciation calculations, fitting of sorption isotherms and the investigation of relationships between protons, Mg and the metals studied we suggest that a combination of sorption mechanisms occurs during the interaction of clay materials with metal solutions. These involve surface complexation, ion exchange and precipitation of solid compounds onto the solid surface. A three-term isotherm model was employed to quantify the role of each of the above mechanisms in the overall retention process. The superior performance of mixed clay among the materials tested is attributed to the synergetic effect of exchange in the interlayer and specific sorption on the clay edges.

Keywords

palygorskiteFe-smectiteisothermsmetal speciationbatch experiments
Type
Article
Information
Clay Minerals , Volume 53 , Issue 2 , June 2018 , pp. 175 - 192
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

This paper was presented during session: ‘Environmental applications of clay minerals’ at the International Clay Conference 2017.

Guest Associate Editor: M. Elsayed

References

REFERENCES

Acebal, S.G. & Vico, L.I. (2017) Acid-base properties of aqueous suspensions of homoionic sepiolite and palygorskite. Natural Resources, 8, 432–444.Google Scholar
Al-Futaisi, A., Jamrah, A., Al-Rawas, A. & Al-Hanai, S. (2007) Adsorption capacity and mineralogical and physico-chemical characteristics of Shuwaymiyah palygorskite (Oman). Environmental Geology, 51, 1317–1327.Google Scholar
Alvarez-Ayuso, E. & Garcia-Sanchez, A. (2003) Palygorskite as a feasible amendment to stabilize heavy metal polluted soils. Environmental Pollution, 125, 337–344.Google Scholar
Alvarez-Ayuso, E. & Garcia-Sanchez, A. (2007) Removal of cadmium from aqueous solutions by palygorskite. Journal of Hazardous Materials, 147, 594–600.Google Scholar
Alvarez-Puebla, R.A., Aisa, C., Blasco, J., Echeverría, J.C., Mosquera, B. & Garrido, J.J. (2004a) Copper heterogeneous nucleation on a palygorskitic clay: An XRD, EXAFS and molecular modeling study. Applied Clay Science, 25, 103–110.Google Scholar
Alvarez-Puebla, R.A., Valenzuela-Calahorro, C. & Garrido, J.J. (2004b) Modeling the adsorption and precipitation processes of Cu(II) on humin. Journal of Colloid and Interface Science, 277, 55–61.Google Scholar
Argun, M.E., Dursun, S., Ozdemir, C. & Karatas, M. (2007) Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics. Journal of Hazardous Materials, 141, 77–85.Google Scholar
Bourliva, A., Michailidis, K., Sikalidis, C., Filippidis, A. & Betsiou, M. (2013) Lead removal from aqueous solutions by natural Greek bentonites. Clay Minerals, 48, 771–787.Google Scholar
Businelli, M., Casciari, F., Businelli, D. & Gigliotti, G. (2003) Mechanisms of Pb (II) sorption and desorption at some clays and goethite-water interfaces. Agronomie, 23, 219–225.Google Scholar
Carmona, M., Lucas, A. De, Valverde, J.L., Velasco, B. & Rodríguez, J.F. (2006) Combined adsorption and ion exchange equilibrium of phenol on Amberlite IRA-420. Chemical Engineering Journal, 117, 155–160.Google Scholar
Carolin, C.F., Kumar, P.S., Saravanan, A., Joshiba, G.J. & Naushad, M. (2017) Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of Environmental Chemical Engineering, 5, 2782–2799.Google Scholar
Chen, H. & Wang, A. (2007) Kinetic and isothermal studies of lead ion adsorption onto palygorskite clay. Journal of Colloid and Interface Science, 307, 309–316.Google Scholar
Chen, H., Zhao, Y. & Wang, A. (2007) Removal of Cu(II) from aqueous solution by adsorption onto acid-activated palygorskite. Journal of Hazardous Materials, 149, 346–354.Google Scholar
Christidis, G.E., Katsiki, P., Pratikakis, A. & Kacandes, G.H. (2010) Rheological properties of palygorskite-smectite suspensions from the Ventzia Basin, W. Macedonia, Greece. Bulletin of the Geological Society of Greece, 43, 2562–2569.Google Scholar
Chryssikos, G.D., Gionis, V., Kacandes, G.H., Stathopoulou, E.T., Suarez, M., Garcia-Romero, E. & Del Rio, M.S. (2009) Octahedral cation distribution in palygorskite. American Mineralogist, 94, 200–203.Google Scholar
Duc, M., Gaboriaud, F. & Thomas, F. (2005) Sensitivity of the acid-base properties of clays to the methods of preparation and measurement: 2. Evidence from continuous potentiometric titrations. Journal of Colloid and Interface Science, 289, 148–156.Google Scholar
Falayi, T. & Ntuli, F. (2013) Removal of heavy metals and neutralisation of acid mine drainage with un-activated attapulgite. Journal of Industrial and Engineering Chemistry, 20, 1285–1292.Google Scholar
Fan, Q., Li, Z., Zhao, H., Jia, Z., Xu, J. & Wu, W. (2009) Adsorption of Pb(II) on palygorskite from aqueous solution: Effects of pH, ionic strength and temperature. Applied Clay Science, 45, 111–116.Google Scholar
Galán, E. (1996) Properties and applications of palygorskite-sepiolite Clays. Clay Minerals, 31, 443–453.Google Scholar
Gionis, V., Kacandes, G.H.Kastritis, I.D. & Chryssikos, G.D. (2006) On the structure of palygorskite by mid- and near-infrared spectroscopy. American Mineralogist, 91, 1125–1133.Google Scholar
Gionis, V., Kacandes, G.H., Kastritis, I.D. & Chryssikos, G.D. (2007) Combined near-infrared and X-ray diffraction investigation of the octahedral sheet composition of palygorskite. Clays and Clay Minerals, 55, 543–553.Google Scholar
Guerra, D.J.L., Goco, J., Nascimento, J. & Melo, I. (2016) Adsorption of divalent metals on natural and functionalized nontronite hybrid surfaces: An evidence of the chelate effect. Journal of Saudi Chemical Society, 20, S552–S565.Google Scholar
He, M., Zhu, Y., Yang, Y., Han, B. & Zhang, Y. (2011) Adsorption of cobalt(II) ions from aqueous solutions by palygorskite. Applied Clay Science, 54, 292–296.Google Scholar
Heidmann, I., Christl, I., Leu, C. & Kretzschmar, R. (2005) Competitive sorption of protons and metal cations onto kaolinite: Experiments and modeling. Journal of Colloid and Interface Science, 282, 270–282.Google Scholar
Ismadji, S., Soetaredjo, F.E. & Ayucitra, A. (2015) Clay Materials for Environmental Remediation. Springer Briefs in Green Chemistry for Sustainability, 124 pp., Springer, Berlin.Google Scholar
Jaisi, D.P., Liu, C., Dong, H., Blake, R.E. & Fein, J.B. (2008) Fe2+ sorption onto nontronite (NAu-2). Geochimica et Cosmochimica Acta, 72, 5361–5371.Google Scholar
Kastritis, I.D. & Kacandes, G.H. (2003) The palygorskite and Mg-Fe-smectite clay deposits of the Ventzia basin, western Macedonia , Greece. Pp. 891–894 in: Mineral Exploration and Sustainable Development-Proceedings of the 7th SGA Meeting (Eliopoulos, D., editor). Millpress, Rotterdam.Google Scholar
Köster, H.M., Ehrlicher, U., Gilg, H.A., Jordan, R., Murad, E. & Onnich, K. (1999) Mineralogical and chemical characteristics of five nontronites and Fe-rich smectites. Clay Minerals, 34, 579–599.Google Scholar
Kurbatov, M.H., Wood, G.B. & Kurbatov, J.D. (1951) Isothermal adsorption of cobalt from dilute solutions. The Journal of Physical Chemistry, 55, 1170–1182.Google Scholar
Kypritidou, Z., Argyraki, A., Chryssikos, G.D. & Stamatakis, M. (2016) Interaction of clay materials with lead in aqeous solutions. Bulletin of the Geological Society of Greece, Proceedings of the 14th International Congress, Thessaloniki, May 2016, L, 2221–2230.Google Scholar
Lazarević, S., Janković-Častvan, I., Jovanović, D., Milonjić, S., Janaćković, D. & Petrović, R. (2007) Adsorption of Pb2+, Cd2+ and Sr2+ ions onto natural and acid-activated sepiolites. Applied Clay Science, 37, 47–57.Google Scholar
Limousin, G., Gaudet, J.P., Charlet, L., Szenknect, S., Barthes, V. & Krimissa, M. (2007) Sorption isotherms: A review on physical bases, modeling and measurement. Applied Geochemistry, 22, 249–275.Google Scholar
Mellis, E.V., Casagrande, J.C., Soares, M.R., da Cruz, P.M.C. & de Camargo, O.A. (2013) Sorption of heavy metals in tropical soils. Pp. 171–205 in: Competitive Sorption and Transport of Heavy Metals in Soils and Geological Media (Selim, H.M., editor). CRC Press, New York.Google Scholar
O'Day, P.A. & Vlassopoulos, D. (2010) Mineral-based amendments for remediation. Elements, 6, 375–381.Google Scholar
Önal, M. & Sarikaya, Y. (2009) Some physicochemical properties of a clay containing smectite and palygorskite. Applied Clay Science, 44, 161–165.Google Scholar
Parkhust, D. & Appelo, C. (1999) User's guide to PHREEQC (Version 2) – A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. U.S. Geological Survey.Google Scholar
Pereira, M., Ferreira, S., Rita, M. & Chaves, M. (2016) Natural palygorskite as an industrial dye remover in single and binary systems. Materials Research, 19, http://dx.doi.org/10.1590/1980-5373-mr-2015-0439Google Scholar
Potgieter, J.H., Potgieter-Vermaak, S.S. & Kalibantonga, P.D. (2006) Heavy metals removal from solution by palygorskite clay. Minerals Engineering, 19, 463–470.Google Scholar
Rhoades, J.D. (1982) Cation exchange capacity. pp. 149–157 in: Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties (A.L. Page, editor). Agronomy Monograph 9.2, American Society of Agronomy, Madison, Wisconsin, USA.Google Scholar
Rhouta, B., Zatile, E., Bouna, L., Lakbita, O., Maury, F., Daoudi, L., Lafont, M.C., Amjoud, M., Senocq, F., Jada, A. & Aït Aghzzaf, A. (2013) Comprehensive physicochemical study of dioctahedral palygorskite-rich clay from Marrakech High Atlas (Morocco). Physics and Chemistry of Minerals, 40, 411–424.Google Scholar
Rusmin, R., Sarkar, B., Biswas, B., Churchman, J., Liu, Y. & Naidu, R. (2016) Structural, electrokinetic and surface properties of activated palygorskite for environmental application. Applied Clay Science, 134, 95–102.Google Scholar
Schlegel, M.L. & Manceau, A. (2013) Binding mechanism of Cu(II) at the clay–water interface by powder and polarized EXAFS spectroscopy. Geochimica et Cosmochimica Acta, 113, 113–124.Google Scholar
Sheikhhosseini, A., Shirvani, M. & Shariatmadari, H. (2013) Competitive sorption of nickel, cadmium, zinc and copper on palygorskite and sepiolite silicate clay minerals. Geoderma, 192, 249–253.Google Scholar
Shirvani, M., Kalbasi, M., Shariatmadari, H., Nourbakhsh, F. & Najafi, B. (2006) Sorption-desorption of cadmium in aqueous palygorskite, sepiolite, and calcite suspensions: Isotherm hysteresis. Chemosphere, 65, 2178–2184.Google Scholar
Shirvani, M., Shariatmadari, H. & Kalbasi, M. (2007) Kinetics of cadmium desorption from fibrous silicate clay minerals: Influence of organic ligands and aging. Applied Clay Science, 37, 175–184.Google Scholar
Stathopoulou, E.T., Suarez, M., Garcia-Romero, E., Del Rio, M.S., Kacandes, G.H., Gionis, V. & Chryssikos, G.D. (2011) Trioctahedral entities in palygorskite: Near-infrared evidence for sepiolite-palygorskite polysomatism. European Journal of Mineralogy, 23, 567–576.Google Scholar
Strawn, D. & Sparks, D. (1999) The use of XAFS to distinguish between inner- and outer-sphere lead adsorption complexes on montmorillonite. Journal of Colloid and Interface Science, 216, 257–269.Google Scholar
Strawn, D.G., Palmer, N.E., Furnare, L.J., Goodell, C., Amonette, J.E. & Kukkadapu, R.K. (2004) Copper sorption mechanisms on smectites. Clays and Clay Minerals, 52, 321–333.Google Scholar
Stumm, W., editor (1992) Chemistry of the Interface. Wiley-Interscience Publications, New York, 425 pp.Google Scholar
Tran, H.N., You, S.J., Hosseini-Bandegharaei, A. & Chao, H.P. (2017) Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: A critical review. Water Research, 120, 88–116.Google Scholar
Vdovic, N., Jurina, I., Škapin, S.D. & Sondi, I. (2010) The surface properties of clay minerals modified by intensive dry milling – revisited. Applied Clay Science, 48, 575–580.Google Scholar
Wang, M., Liao, L., Zhang, X. & Li, Z. (2012) Adsorption of low concentration humic acid from water by palygorskite. Applied Clay Science, 67–68, 164–168.Google Scholar
Wang, W., Chen, H. & Wang, A. (2007) Adsorption characteristics of Cd(II) from aqueous solution onto activated palygorskite. Separation and Purification Technology, 55, 157–164.Google Scholar
Wang, W., Tian, G., Zhang, Z. & Wang, A. (2016) From naturally low-grade palygorskite to hybrid silicate adsorbent for efficient capture of Cu(II) ions. Applied Clay Science, 132–133, 438–448.Google Scholar
Worch, E. (2012) Adsorption Technology in Water Treatment: Fundamentals, Processes, and Modeling. de Gruyter, Berlin, 344 pp.Google Scholar
Zhang, H., Tong, Z., Wei, T. & Tang, Y. (2012) Sorption characteristics of Pb(II) on alkaline Ca-bentonite. Applied Clay Science, 65–66, 21–23.Google Scholar
Zorpas, A.A., Constantinides, T., Vlyssides, A.G., Haralambous, I. & Loizidou, M. (2000) Heavy metal uptake by natural zeolite and metals partitioning in sewage sludge compost. Bioresource Technology, 72, 113–119.Google Scholar
Zotiadis, V., Argyraki, A. & Theologou, E. (2012) A pilot scale application of attapulgitic clay for stabilization of toxic elements in contaminated soil. Journal of Geotechnical and Geoenvironmental Engineering, 138, 633–637.Google Scholar
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