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Layered double hydroxides: matrices for storage and source of boron for plant growth

Published online by Cambridge University Press:  13 March 2018

Gustavo Franco de Castro ,
Jader Alves Ferreira ,
Denise Eulálio ,
Silas Junior de Souza ,
Sarah Vieira Novais ,
Roberto Ferreira Novais ,
Frederico Garcia Pinto  and
Jairo Tronto
Gustavo Franco de Castro
Affiliation:
Universidade Federal de Viçosa, Campus de Viçosa, Departamento de Solos, Viçosa, CEP: 36570-900, Brazil
Jader Alves Ferreira
Affiliation:
Universidade Federal de Viçosa, Instituto de Ciências Exatas e Tecnológicas, Campus de Rio Paranaíba, Rodovia MG-230 km 08, Cx. Postal 22 - Rio Paranaíba - MG, CEP:38810-000, Brazil
Denise Eulálio
Affiliation:
Universidade Federal de Viçosa, Instituto de Ciências Exatas e Tecnológicas, Campus de Rio Paranaíba, Rodovia MG-230 km 08, Cx. Postal 22 - Rio Paranaíba - MG, CEP:38810-000, Brazil
Silas Junior de Souza
Affiliation:
Universidade Federal de Viçosa, Instituto de Ciências Exatas e Tecnológicas, Campus de Rio Paranaíba, Rodovia MG-230 km 08, Cx. Postal 22 - Rio Paranaíba - MG, CEP:38810-000, Brazil
Sarah Vieira Novais
Affiliation:
Escola Superior de Agricultura “Luiz de Queiroz”, Departamento de Ciências do Solo, Universidade de São Paulo, Av. Pádua Dias, 11 - Cx. Postal 9 - Piracicaba - SP, CEP: 13418-900 – Brazil
Roberto Ferreira Novais
Affiliation:
Universidade Federal de Viçosa, Instituto de Ciências Exatas e Tecnológicas, Campus de Rio Paranaíba, Rodovia MG-230 km 08, Cx. Postal 22 - Rio Paranaíba - MG, CEP:38810-000, Brazil
Frederico Garcia Pinto
Affiliation:
Universidade Federal de Viçosa, Instituto de Ciências Exatas e Tecnológicas, Campus de Rio Paranaíba, Rodovia MG-230 km 08, Cx. Postal 22 - Rio Paranaíba - MG, CEP:38810-000, Brazil
Jairo Tronto*
Affiliation:
Universidade Federal de Viçosa, Instituto de Ciências Exatas e Tecnológicas, Campus de Rio Paranaíba, Rodovia MG-230 km 08, Cx. Postal 22 - Rio Paranaíba - MG, CEP:38810-000, Brazil
*
*E-mail: [email protected]
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Abstract

The increase of the absorption efficiency of boron (B) by plants is essential for increasing crop productivity. The intercalation of B in MgAl layered double hydroxides (LDHs) is an alternative to evaluating how these materials can provide B to plants. In this work, a MgAl LDH intercalated with borate ions (Mg2Al-B-LDH) was synthesized by the constant pH coprecipitation method, and the material produced was evaluated as a matrix for storage and as a source of B for plants. The Mg2Al-B-LDH was characterized by XRD, ATR-FTIR, TGA-DTA, specific surface area, pore size and volume, and SEM. A bioassay was performed to verify the supply of B to plants from the two sources in the forms of H3BO3 and of Mg2Al-B-LDH to sunflower plants grown in pots. The LDH basal spacing value of 12.0 Å is characteristic of intercalation of tetraborate octahydrate ions [B4O5(OH)42−]·8H2O between the layers. There was an increase in the dry matter (DM) and B content of the plants relative to those treatments where no B was added. The lack of statistical difference for plant yield between the two sources of B suggests a lack of stability of the Mg2Al-B-LDH structure under the acidic condition of the soil.

Keywords

slow-release fertilizerplant nutritionLDH matrixmicronutrientbioassay
Type
Article
Information
Clay Minerals , Volume 53 , Issue 1 , March 2018 , pp. 79 - 89
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

This paper was presented during session MISC-01-‘LDHs: from design and characterization to applications’ at the International Clay Conference 2017.

Guest Associate Editor: Vanessa Prevot

References

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