Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-26T07:56:34.505Z Has data issue: false hasContentIssue false
  • English
  • Français

Interaction of aminotriazole with montmorillonite and Mg-vermiculite at pH 4

Published online by Cambridge University Press:  09 July 2018

E. Morillo ,
J. L. Perez-Rodriguez ,
P. Rodriguez-Rubio  and
C. Maqueda
E. Morillo
Affiliation:
Instituto de Recursos Naturales y Agrobiología, CSIC, Apdo. 1052, 41080 Sevilla, Spain
J. L. Perez-Rodriguez
Affiliation:
Instituto de Ciencia de Materiales, CSIC, Apdo. 1115, 41080 Sevilla, Spain
P. Rodriguez-Rubio
Affiliation:
Escuela Politécnica Superior Campus de La Rábida, Universidad de Huelva, Spain
C. Maqueda
Affiliation:
Instituto de Recursos Naturales y Agrobiología, CSIC, Apdo. 1052, 41080 Sevilla, Spain
Get access Rights & Permissions [Opens in a new window]

Abstract

The interaction of aminotriazole (AMT) at pH 4 on Wyoming montmorillonite (mainly with Na ions) and Mg-vermiculite has been studied by X-ray diffraction and infrared spectroscopy. The AMT is adsorbed on montmorillonite in the cationic form by cation exchange. The amount of pesticide adsorbed was 71 mEq/100 g, which comprises ∼91% of the CEC of this sample (78.2 mEq/100 g). Saturation was reached in 24 h, giving rise to a complex with basal spacing 12.5 Å. Vermiculite adsorbs 167 mEq/100 g, almost 20% greater than the CEC (141 mEq/100 g), and the basal spacing was stabilized at 13.68 Å after five weeks of treatment with AMT. A part of the AMT is adsorbed in cationic form, displacing a great part of the exchangeable Mg2+ cations. The rest is adsorbed in molecular form by coordination to the Mg2+ cations which remain in the interlamellar space, removing a great amount of water, and remaining in the interlamellar space of vermiculite after washing with water, probably because of a steric hindrance from the AMT cations adsorbed.

Type
Research Article
Information
Clay Minerals , Volume 32 , Issue 2 , June 1997 , pp. 307 - 313
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aragön, F., Ruiz-Amil, A. and Ruiz-Conde, A. (1992) Intercalation of organic compounds in interstratified kaolinite-smectite mineral. Miner. Petrogr. Acta, 35, 307–313.Google Scholar
Bellamy, L.J. (1975) The Infrared Spectra of Complex Molecules. Vol. I. Chapman & Hall, London.Google Scholar
Bosetto, M., Arfaioli, P. & Fusi, P. (1993) Interactions of alachlor with homoionic montmorillonites. Soil Sci. 155, 105–113.CrossRefGoogle Scholar
Dios-Cancela, G., Romero-Taboada, E. & Sáinchez-Rasero, F. (1992) Carbendazim adsorption on montmorillonite, peat and soils. J. Soil Sci. 43, 99–111.Google Scholar
Grim, R.E. (1968) Clay Mineralogy, 2nd edition. McGraw-Hill, New York.Google Scholar
Jeffrey, G.A., Ruble, J.R. & Yates, J.H. (1983) Neutron diffraction at 15 and 120 K and “ab initio” molecular orbital studies of the molecular structure of 1,2,4- triazole. Acta Cryst. B39, 388–394.CrossRefGoogle Scholar
Justo, A. (1984) Estudio fisicoqufmico y mineral6gico de vermiculitas de Andalucfa y Badajoz. PhD thesis, Sevilla, Spain.Google Scholar
Khünel, R.A. (1992) Clays and clay minerals in environmental research. Miner. Petrogr. Acta. XXXV, 1-11.Google Scholar
Knight, B.A.G. & Tomlinson, T.E. (1967) The interaction of paraquat with mineral soils. J. Soil Sci. 18, 233–243.Google Scholar
Kowalska, M., Guler, H. & Cocke, D.L. (1994) Interactions of clay minerals with organic pollutants. Sci. Total Environ. 141, 223–240.CrossRefGoogle Scholar
Micera, C., Pusino, A., Gessa, C. & Petretto, S. (1988) Interaction of fluazifop with Al3+, Fe3+ and Cu2+ saturated montmorillonite. Clays Clay Miner. 36, 354–358.Google Scholar
Morillo, E., Pérez-Rodríguez, J.L. & Maqueda, C. (1991) Mechanisms of interaction between montmorillonite and aminotriazole. Clay Miner. 26, 269–279.Google Scholar
Nearpass, D.C. (1970) Exchange adsorption of 3-aminotriazole by montmorillonite. Soil Sci. 109, 77–84.Google Scholar
Russell, J.D., Cruz, M.I. & White, J.L. (1968) The adsorption of 3-aminotriazole by montmorillonite. J. Agr. Food Chem. 16, 21–24.Google Scholar
Sánchez-Camazano, M. & Sánchez-Martín, M.J. (1990) Effect of colloidal soil components on the adsorption of mevinphos. Bull. Environ. Contam. Toxicol. 44, 106–113.CrossRefGoogle ScholarPubMed
Serratosa, J.M. (1968) Infrared study of benzonitrile (C6H5-CN)-montmorillonite complexes. Am. Miner. 53, 1244–1251.Google Scholar
Vila, E. & Ruiz-Amil, A. (1988) Computer program for analysing interstratified structures by Fourier transform methods. Powder Diffraction 3, 7–11.Google Scholar
Yariv, S., Russell, J.D. & Farmer, V.C. (1966) Infrared study of the adsorption of benzoic acid and nitrobenzene in montmorillonite. Israel J. Chem. 4, 201–213.CrossRefGoogle Scholar