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The influence of octahedral and tetrahedral cation substitution on the structure of smectites and serpentines as observed through infrared spectroscopy

Published online by Cambridge University Press:  09 July 2018

J . Bishop ,
E. Murad  and
M. D. Dyar
J . Bishop*
Affiliation:
SETI Institute/NASA-Ames Research Center, Moffett Field, CA 94035, USA
E. Murad
Affiliation:
Bayerisches Geologisches Landesamt, Leopoldstrasse 30, D-95603 Marktredwitz, Germany
M. D. Dyar
Affiliation:
Department of Earth and Environment, Mount Holyoke College, South HadleyMA 01075, USA
*
*E-mail: [email protected]
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Abstract

Analysis of the near-infrared (NIR) spectral bands of phyllosilicates, together with the mid-infrared bands, enables testing and confirmation of band assignments for the structural OH vibrations. Spectral analyses of selected smectites and serpentine-kaolin minerals are presented here. The results of this study indicate that dioctahedral smectites may contain both in-plane and out-of-plane OH-bending vibrations, as suggested by Farmer (1974). In-plane bands occur near 800 ­ 915 cm–1, while the weaker out-of-plane vibrations occur near 600 ­ 700 cm–1 and are enhanced in dioctahedral smectites when the structure is disrupted by substitutions. Analysis of the OH-stretching vibrations and their NIR overtone bands is also presented for both smectites and serpentine-kaolin minerals. These overtones are more straightforward for serpentines than for kaolinite, and a strong overtone associated with the kaolinite OH-stretching band at 3620 cm–1 is found that supports its assignment as an OH-stretching band.

Keywords

infrared spectroscopysmectitesserpentineskaolinitestructural OH
Type
Research Article
Information
Clay Minerals , Volume 37 , Issue 4 , December 2002 , pp. 617 - 628
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2002

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References

Anderson, J.H. & Wickersheim, K.A. (1964) Near infrared characterization of water and hydroxyl groups on silica surfaces. Surface Science, 2, 252–260.Google Scholar
Bailey, S.W. (1980) Structures of layer silicates. Pp. 1–124 in. Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. & Brown, G., editors). Monograph 5, Mineralogical Society, London.Google Scholar
Bell, J.F., III (1996) Iron, sulfate, carbonate, and hydrated minerals on Mars. Pp. 359–380 in: Mineral Spectroscopy: A tribute to Roger G. Burns (Dyar, M.D., McCammon, C. & Schaefer, M.W., editors). The Geochemical Society, Houston, Texas, USA.Google Scholar
Besson, G. & Drits, V.A. (1997) Refined relationships between chemical composition of dioctahedral finegrained micaceous minerals and their infrared spectra within the OH stretching region. Part II: The main factors affecting OH vibrations and quantitative analysis. Clays and Clay Minerals, 45, 170–183.Google Scholar
Bish, D. (1993) Rietveld refinement of the kaolinite structure at 1.5 K. Clays and Clay Minerals, 41, 738–744.Google Scholar
Bishop, J.L. & Murad, E. (1996) Schwertmannite on Mars? Spectroscopic analyses of schwertmannite, its relationship to other ferric minerals, and its possible presence in the surface material on Mars. Pp. 337–358 in: Mineral Spectroscopy: A tribute to Roger G. Burns (Dyar, M.D., McCammon, C. & Schaefer, M.W., editors). The Geochemical Society, Houston, Texas, USA.Google Scholar
Bishop, J.L., Pieters, C.M. & Edwards, J.O. (1994) Infrared spectroscopic analyses on the nature of water in montmorillonite. Clays and Clay Minerals, 42, 701–715.Google Scholar
Bishop, J.L., Murad, E., Madejová, J., Komadel, P., Wagner, U. & Scheinos t, A. (1999) Visible, Mössbauer and infrared spectroscopy of dioctahedral smectites: Structural analyses of the Fe-bearing smectite s Sampor, SWy-1 and SWa-1. Pp. 413–419 in: 11th International Clay Conference, June, 1997.Google Scholar
Bishop, J.L., Schiffman, P. & Southard, R.J. (2001) Geochemical and mineralogical analyses of palagonitic tuffs and altered rinds of pillow lavas on Iceland and applications to Mars. Pp. 371-392 in. Volcano- Ice Interaction on Earth and Mars (Smellie, J.L. and Chapman, M.G., editors). Special Publication, 202, Geological Society, London.Google Scholar
Bishop, J.L., Madejová, J., Komadel, P. & Froeschl, H. (2002) The influence of structural Fe, Al and Mg on the infrared OH bands in spectra of dioctahedral smectites. Clay Minerals, 37, 607–616.Google Scholar
Breen, C., Madejová, J. & Komadel, P. (1995) Characterisation of moderately acid-treated, sizefractionated montmorillonites using IR and MAS NMR spectroscopy and thermal analysis. Journal of Material Chemistry, 5, 469–474.CrossRefGoogle Scholar
Burns, R.G. (1993) Rates and mechanisms of chemical weathering of ferromagnesian silicate minerals on Mars. Geochimica et Cosmochimica Acta, 57, 4555–4574.Google Scholar
Burt, D.M. (1989) Iron-rich minerals on Mars: Potential sources or sinks for hydrogen and indicators of hydrogen loss over time. Pp. 423–432 in: 19th Lunar and Planetary Science Conference.Google Scholar
Clark, R.N., King, T.V.V., Klejwa, M. & Swayze, G.A. (1990) High spectral resolution reflectance spectroscopy of minerals. Journal of Geophysical Research, 95, 12653–12680.Google Scholar
Cornell, R.M. & Schwertmann, U. (1996) The Iron Oxides. VCH, New York.Google Scholar
Farmer, V.C. (1974) The layer silicates. Pp. 331–363 in. The Infrared Spectra of Minerals (Farmer, V.C., editor). Monograph 4, The Mineralogical Society, London.CrossRefGoogle Scholar
Farmer, V.C. (1998) Differing effects of particle size and shape in the infrared and Raman spectra of kaolinite. Clay Minerals, 33, 601–604.CrossRefGoogle Scholar
Fialips, C.-I., Huo, D., Yan, L., Wu, J. & Stucki, J.W. (2001) Effect of iron oxidation state on the IR spectra of Gar f ield nontroni te. American Mineralogist, 86, 630–641.Google Scholar
Goodman, B.A., Russell, J.D., Fraser, A.R. & Woodhams, F.W.D. (1976) A Mössbauer and IR spectroscopy study of the structure of nontronite. Clays and Clay Minerals, 24, 53–59.Google Scholar
Hayashi, H. & Oinuma, K. (1965) Relationship between infrared absorption spectra in the region of 450–900cm­1 and chemical composition of chlorite. American Mineralogist, 50, 476–483.Google Scholar
Huheey, J.E., Keiter, E.A. & Keiter, R.L. (1993) Inorganic Chemistry. Principles of Structure and Reactivity. Harper Collins, New York.Google Scholar
King, T.V.V. & Clark, R.N. (1989) Spectral characteristics of chlorites and Mg-serpentines using highresolution reflectance spectroscopy. Journal of Geophysical Research, 94, 13,997 ­ 14,008.CrossRefGoogle Scholar
Komadel, P., Madejová, J. & Stucki, J.W. (1995) Reduction and reoxidation of nontronite: Questions of reversibility. Clays and Clay Minerals, 43, 105–110.Google Scholar
Komadel, P., Madejová, J., Janek, M., Gates, W.P., Kirkpatrick, R.J. & Stucki, J.W. (1996) Dissolution of hectorite in inorganic acids. Clays and Clay Minerals, 44, 228–236.Google Scholar
Köster, H.M., Ehrlicher, U., Gilg, H.A., Jordan, R., Murad, E. & Onnich, K. (1999) Mineralogical and chemical characteristics of five nontronites and Fe-rich smectites. Clay Minerals, 34, 579–599.Google Scholar
Liese, H.C. (1967) Supplemental data on the correlation of infrared absorption spectra and composition in biotites. American Mineralogist, 52, 877–880.Google Scholar
Madejová, J., Bednáriková, E., Komadel, P. & Číčel, B. (1990) Structural study of acid-treated smectites by IR spectroscopy. Pp. 267–271 in: 11th Conference on Clay Mineralogy and Petrology.Google Scholar
Madejová, J., Komadel, P. & Číčel, B. (1994) Infrared study of octahedral site populations in smectites. Clay Minerals, 29, 319–326.Google Scholar
Manceau, A., Drits, V.A., Lanson, B., Chateigner, D., Wu, J., Huo, D., Gates, W.P. & Stucki, J.W. (2000) Oxidation-reduction mechanism of iron in dioctahedral smectites: II. Crystal chemistry of reduced Garfield nontronite. American Mineralogist, 85, 153–172.CrossRefGoogle Scholar
Jr.McSween, H.Y., & Keil, K. (2000) Mixing relationships in the Martian regolith and the composition of the globally homogeneous dust. Geochimica Cosmochimica Acta, 64, 2155–2166.CrossRefGoogle Scholar
Mendelovici, E., Yariv, S. & Villalba, R. (1979) Ironbearing kaolinite in Venezuelan laterites. 1. Infrared spectroscopy and chemical dissolution evidence. Clay Minerals, 14, 323–331.Google Scholar
Murad, E. & Bishop, J.L. (2000) The infrared spectrum of synthe tic akagané ite, ß-FeOOH. American Mineralogist, 85, 716–721.Google Scholar
O’Hanley, D.S. & Dyar, M.D. (1993) The composition of lizardite 1Tand the formation of magnetite in serpentines. American Mineralogist, 78, 391–404.Google Scholar
O’Hanley, D.S. & Dyar, M.D. (1998) The composition of chrysotile and its relationship with lizardite. The Canadian Mineralogist, 36, 727–739.Google Scholar
Russell, J.D. & Farmer, V.C. (1964) Infra-red spectroscopic study of the dehydration of montmorillonite and saponite. Clay Minerals Bulletin, 5, 443–464.CrossRefGoogle Scholar
Schwertmann, U. & Cornell, R.M. (2000) Iron Oxides in the Laboratory. Wiley-VCH, New York.Google Scholar
Stubican, V. & Roy, R. (1961a) A new approach to the assignment of infrared absorption bands in layer silicates. Zeitschrift für Kristallographie, 115, 200–214.CrossRefGoogle Scholar
Stubican, V. & Roy, R. (1961b) Isomorphous substitution and infra-red spectra of the layer lattice silicates. American Mineralogist, 46, 32–51.Google Scholar
Vantelon, D., Pelletier, M., Barres, O., Thomas, F. & Michot, L.J. (2001) Fe, Mg and Al distribution in the octahedral sheet of montmorillonites. An infrared study in the OH-bending region. Clay Minerals, 36, 369–379.CrossRefGoogle Scholar
Wise, M.S. & Eugster, H.P. (1964) Celadonite: Synthesis, thermal stabil ity and occurre nce. American Mineralogist, 49, 1031–1083.Google Scholar