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Identification and characterization of Fe-rich smectites in the Çamlıca Region of western Turkey

Published online by Cambridge University Press:  09 July 2018

Y. Seki  and
K. Yurdakoç
Y. Seki
Affiliation:
Dokuz Eylül University, Faculty of Arts & Sciences, Department of Chemistry, 35160 Buca, İzmir, Turkey
K. Yurdakoç*
Affiliation:
Dokuz Eylül University, Faculty of Arts & Sciences, Department of Chemistry, 35160 Buca, İzmir, Turkey
*
*E-mail: [email protected]
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Abstract

Fe-rich dioctahedral smectites are the main constituent of clays in Çamlıca Region of Turkey. The structural, chemical and morphological characteristics of these smectites after washing are examined by X-ray diffraction, electron microscopy, inductively coupled plasma mass spectrometry and Fourier transform infrared spectroscopy. Smectite particles occur as individual flakes 0.2–2.0 μm in size. These flakes are often aggregated into clusters up to 6.0 μm in size.

Keywords

bentonitecharacterizationSTEMTEMSEMXRDICP-MSFTIR
Type
Research Article
Information
Clay Minerals , Volume 42 , Issue 2 , June 2007 , pp. 153 - 160
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2007

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References

Alt, J.C. & Honnorez, J. (1984) Alteration of the upper oceanic crust, DSPD site 417: Mineralogy and chemistry. Contributions to Mineralogy and Petrology, 87, 149–169.CrossRefGoogle Scholar
Alt, J.C., Teagle, D.A.H., Brewer, T.S., Shanks, W.C. & Halliday, A.N. (1998) Alteration and mineralization of an oceanic forearc and the ophiolite-ocean crust analogy. Journal of Geophysical Research, 103, 12365–12380.Google Scholar
Brigatti, M.F. (1983) Relationships between composition and structure in Fe-rich smectites. Clay Minerals, 18, 177–186.Google Scholar
Brown, G. & Brindley, G.W. (1980) X-ray diffraction procedures for clay mineral dentification. Pp. 305–359 in: Crystal Structures of Clay Minerals and their X-ray Identification (Drindley, G.W. & Brown, G., editors). Monograph 5, Mineralogical Society, London.Google Scholar
Christidis, G.E. (2006) Genesis and compositional heterogeneity of smectites. Part III: Alteration of basic pyroclastic rocks. A case study from the Troodos Ophiolite Complex, Cyprus. American Mineralogist, 91, 685–701.Google Scholar
Čičel, B., Komadel, P., Bednarikova, E. & Madejová, J. (1992) Mineralogical composition and distribution of Si, Al, Fe, Mg and Ca in the fine fractions of some Czech and Slovak bentonites. Geologica Carpathica—Series Clays, 1, 3–7.Google Scholar
Cokca, E. & Birand, A. (1993), Determination of cation exchange capacity of clayey soils by the methylene blue test. Geotechnical Testing Journal, 16, 4518–524.Google Scholar
Cuadros, J., Sainz-Diaz, C.I., Ramirez, R. & Hernandez-Laguna, A. (1999) Analysis of Fe segregation in the octahedral sheet of bentonitic illite-smactite by means of FTIR, 27Al MAS NMR and reverse Monte Carlo simulations. American Journal of Science, 299, 289–308.Google Scholar
Decarreau, A., Colin, F., Herbillon, A., Manceau, A., Nahon, D., Paquet, H., Trauth-Badeaud, D. & Trescases, J.J. (1987) Domain segregation in Ni-Fe- Mg-smectites. Clays and Clay Minerals, 35, 1–10.Google Scholar
Drits, V.A., Lindgreen, H., Salyn, A.L., Ylagan, R. & McCarty, D.K. (1998) Semi quantitative determination of trans-vacant and cis-vacant 2:1 layers in illites and illite-smectites by thermal analysis and X-ray diffraction. American Mineralogist, 83, 1188–1198.Google Scholar
Gillis, K.M. & Robinson, P.T. (1990) Patterns and processes of alteration in the lavas and dykes of the Troodos ophiolite, Cyprus. Journal of Geophysical Research, 95, 21523–21548.Google Scholar
Grim, R.E. (1968) Clay Mineralogy. McGraw-Hill Book Company, New York, 596 pp.Google Scholar
Helvacı, C. (1994) Mineral assemblages and formation of the Kestelek and Sultançayırı borate deposits. Proceedings of the 29th International Geological Congress, Part A, pp. 245–264.Google Scholar
Helvacı, C. & Orti, F. (1998) Sedimentology and diagenesis of Miocene colemanite-ulexite deposits (Western Anatolia, Turkey). Journal of Sedimentary Research, 68, 1021–1033.CrossRefGoogle Scholar
Helvacı, C., Stamatakis, M., Zagouroğlou, C. & Kamaris, J. (1993) Borate minerals and related authigenic silicates in northeastern Mediterranean Late Miocene continental basins. Exploration and Mining Geology, 2, 171–178.Google Scholar
Kaya, A. & Oren, A.H. (2005) Adsorption of zinc from aqueous solutions to bentonite. Journal of Hazardous Materials, B125, 183–189.Google Scholar
Köster, H.M., Ehrlicher, U., Gilg, H.A., Jordan, R., Murad, E. & Onnich, K. (1999) Mineralogical and chemical characteristics of five nontronites and Fe-rich smectites. Clay Minerals, 34, 579–599.Google Scholar
Lacin, O., Bayrak, B., Korkut, O. & Sayan, E. (2005) Modeling of adsorption and ultrasonic desorption of cadmium(II) and zinc(II) on local bentonite. Journal of Colloid and Interface Science, 292, 330–335.Google Scholar
Letaief, S., Casal, B., Kbir-Ariguib, N., Trabelsi-Ayadi, M. & Ruiz-Hitzky, E. (2002) Fe-rich smectites from Gafsa (Tunisia): characterization and pillaring behaviour. Clay Minerals, 37, 517–529.Google Scholar
Mackenzie, R.C. (1957) The Differential Thermal Investigation of Clays. Monograph 2, The Mineralogical Society, London, 456 pp.Google Scholar
Mitchell, J.K. (1993) Fundamentals of Soil Behavior, 2 nd edition. John Wiley, New York.Google Scholar
Montes, G., Geraud, H.Y., Duplay, J. & Reuschle, T. (2005) ESEM observations of compacted bentonite submitted to hydration/dehydration conditions. Colloids and Surfaces A: Physicochemical Engineering Aspects, 262, 14–22.Google Scholar
Muller, F., Drits, V., Plançon, A. & Robert, J.-L. (2000) Structural transformation of 2:1 dioctahedral layer silicates during dehydroxylation-rehydroxylation reactions. Clays and Clay Minerals, 48, 572–585.Google Scholar
Orenberg, J. & Handy, J. (1992) Reflectance spectroscopy of palagonite and iron-rich montmorillonite clay mixtures: Implications for the surface composition of Mars. Icarus, 96, 219–225.CrossRefGoogle Scholar
Orti, F., Helvacı, C., Rosell, L. & Gündoğan, İ. (1998) Sulphate-borate relations in an evaporitic lacustrine environment: the Sultançayır Gypsum (Miocene, western Anatolia). Sedimentology, 45, 697–710.Google Scholar
Petit, S., Caillaud, J., Righi, D., Madejová, J., Elsass, F. & Köster, H.M. (2002) Characterization and crystal chemistry of an Fe-rich montmorillonite from Olberg, Germany. Clay Minerals, 37, 283–297.Google Scholar
Pusch, R. (1992) Use of bentonite for isolation of radioactive waste products. Clay Minerals, 27, 353–361.CrossRefGoogle Scholar
Schultz, L.G. (1969) Lithium and potassium adsorption, dehydroxylation temperature and structural water content of aluminous smectites. Clays and Clay Minerals, 17, 115–149.CrossRefGoogle Scholar