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Hydrotalcites with heterogeneous anion distributions: a first approach to producing new materials to be used as vehicles for the successive delivery of compounds

Published online by Cambridge University Press:  04 February 2020

Franchescoli D. Velázquez-Herrera  and
Geolar Fetter Open the ORCID record for Geolar Fetter [Opens in a new window]
Franchescoli D. Velázquez-Herrera
Affiliation:
Benemérita Universidad Autónoma de Puebla, Facultad de Ciencias Químicas, Blvd. 14 Sur y Av. San Claudio, C.P. 72570Puebla, PUE, Mexico
Geolar Fetter*
Affiliation:
Benemérita Universidad Autónoma de Puebla, Facultad de Ciencias Químicas, Blvd. 14 Sur y Av. San Claudio, C.P. 72570Puebla, PUE, Mexico
*
*Email: [email protected]
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Abstract

Hydrotalcites with heterogeneous distributions of anions between their layers were synthesized. Some synthesis parameters were studied to verify their influence on the anionic segregation properties of the hydrotalcites. The nature of the divalent cation and the crystallization method were most relevant. Zinc, in contrast to magnesium, assisted in discriminating carbonates and attracting nitrates to form hydrotalcites with heterogeneous distributions using microwave irradiation. Furthermore, the identification of this kind of hydrotalcite could be easily verified by determining the presence of a double reflection in the 003 X-ray diffraction (XRD) maximum, which definitively characterized a heterogeneous anion distribution. Finally, the reason as to why in some cases the hydrotalcite presented two reflections in the 003 XRD peak was elucidated.

Keywords

003 X-ray diffraction peakanion segregationanionic claysdrug deliverylayered double hydroxidesmicrowave irradiation
Type
Article
Information
Clay Minerals , Volume 55 , Issue 1 , March 2020 , pp. 31 - 39
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland, 2020

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Footnotes

Associate Editor: Chun Hui Zhou

References

Abderrazek, K., Srasra, N.F. & Srasra, E. (2017) Photocatalytic decolourization of methylene blue using [Zn–Al] layered double hydroxides synthesized at different molar cationic ratios. Clay Minerals, 52, 203–215.CrossRefGoogle Scholar
Ay, A.N., Zümreoglu-Karan, B. & Temel, A. (2007) Boron removal by hydrotalcite-like, carbonate-free Mg-Al-NO3-LDH and a rationale on the mechanism. Microporous and Mesoporous Materials, 98, 1–5.CrossRefGoogle Scholar
Balcomb, B., Singh, M. & Singh, S. (2015) Synthesis and characterization of layered double hydroxides and their potential as nonviral gene delivery Vehicles. Chemistry Open, 4, 137–145.Google ScholarPubMed
Benedictto, G.P., Sotelo, R.M., Dalla Costa, B.O., Fetter, G. & Basaldella, E.I. (2018) Potassium-containing hydroxylated hydrotalcite as efficient catalyst for the transesterification of sunflower oil. Journal of Materials Science, 53, 12828–12836.CrossRefGoogle Scholar
Bergadà, O., Vicente, I., Salagre, P., Cesteros, Y., Medina, F. & Sueiras, J.E. (2007) Microwave effect during aging on the porosity and basic properties of hydrotalcites. Microporous and Mesoporous Materials, 101, 363–373.CrossRefGoogle Scholar
Bhuiyan, M.M.R., Lin, S.D. & Hsiao, T.C. (2014) Effect of calcination on Cu–Zn-loaded hydrotalcite catalysts for C–C bond formation derived from methanol. Catalysis Today, 226, 150–159.CrossRefGoogle Scholar
Britto, S., Radha, A. V., Ravishankar, N. & Kamath, P.V. (2007) Solution decomposition of the layered double hydroxide (LDH) of Zn with Al. Solid State Sciences, 9, 279–286.CrossRefGoogle Scholar
Cavani, F., Trifirò, F. & Vaccari, A. (1991) Hydrotalcite-type anionic clays: preparation, properties and applications. Catalysis Today, 11, 173–301.CrossRefGoogle Scholar
Climent, M.J., Corma, A., Iborra, S., Epping, K. & Velty, A. (2004) Increasing the basicity and catalytic activity of hydrotalcites by different synthesis procedures. Journal of Catalysis, 225, 316–326.CrossRefGoogle Scholar
de Castro, G.F., Ferreira, J.A., Eulálio, D., de Souza, S.J., Novais, S.V., Novais, R.F., Pinto, F.G. & Tronto, J. (2018) Layered double hydroxides: matrices for storage and source of boron for plant growth. Clay Minerals, 53, 79–89.CrossRefGoogle Scholar
de la Hoz, A., Díaz-Ortiz, Á. & Moreno, A. (2005) Microwaves in organic synthesis. Thermal and non-thermal microwave effects. Chemical Society Reviews, 34, 164–178.CrossRefGoogle ScholarPubMed
de Roy, A., Forano, C., el Malki, K. & Besse, J.-P. (1992) Anionic clays: trends in pillaring chemistry. Pp. 108–169 in Expanded Clays and Other Microporous Solids, 1st edition (Occelli, M.L. & Robson, H., editors). Springer US, New York, NY, USA.CrossRefGoogle Scholar
del Arco, M., Fernández, A., Martín, C., Sayalero, M.L. (2008) Solubility and release of fenamates intercalated in layered double hydroxides. Clay Minerals, 43, 255–265.CrossRefGoogle Scholar
Eiby, S.H.J., Tobler, D.J., Nedel, S., Bischoff, A., Christiansen, B.C., Hansen, A.S., Kjaergaard, H.G. & Stipp, S.L.S. (2016) Competition between chloride and sulphate during the reformation of calcined hydrotalcite. Applied Clay Science, 132–133, 650–659.CrossRefGoogle Scholar
Fetter, G., Olguín, M.T., Bosch, P. & Bulbulian, S. (2000) Surface areas of nitrated hydrotalcites. Journal of Porous Materials, 7, 469–473.CrossRefGoogle Scholar
Gastuche, M.C., Brown, G. & Mortland, M.M. (1967) Mixed magnesium–aluminium hydroxides. I. Preparation and characterization of compounds formed in dialysed systems. Clay Minerals, 7, 177–192.CrossRefGoogle Scholar
Gupta, P., Behera, B., Chhibber, V.K. & Ray, S.S. (2018) Microwave assisted synthesis of glycerol carbonate over zinc incorporated mesoporous hydrotalcite catalyst. Current Microwave Chemistry, 5, 13–22.CrossRefGoogle Scholar
Haley, S.M., Tappin, A.D., Bond, P.R. & Fitzsimons, M.F. (2006) A comparison of SEM-EDS with ICP-AES for the quantitative elemental determination of estuarine particles. Environmental Chemistry Letters, 4, 235–238.CrossRefGoogle Scholar
Inayat, A., Klumpp, M. & Schwieger, W. (2011) The urea method for the direct synthesis of ZnAl layered double hydroxides with nitrate as the interlayer anion. Applied Clay Science, 51, 452–459.CrossRefGoogle Scholar
Iyi, N., Matsumoto, T., Kaneko, Y. & Kitamura, K. (2004) Deintercalation of carbonate ions from a hydrotalcite-like compound: enhanced decarbonation using acid-salt mixed solution. Chemistry of Materials, 16, 2926–2932.CrossRefGoogle Scholar
Lennerová, D., Kovanda, F. & Brožek, J. (2015) Preparation of Mg–Al layered double hydroxide/polyamide 6 nanocomposites using Mg–Al-taurate LDH as nanofiller. Applied Clay Science, 114, 265–272.CrossRefGoogle Scholar
Li, Q. & Kirkpatrick, R.J. (2007) Organic anions in layered double hydroxides: an experimental investigation of citrate hydrotalcite. American Mineralogist, 92, 397–402.CrossRefGoogle Scholar
Lobo-Sánchez, M., Nájera-Meléndez, G., Luna, G., Segura-Pérez, V., Rivera, J.A. & Fetter, G. (2018) ZnAl layered double hydroxides impregnated with eucalyptus oil as efficient hybrid materials against multi-resistant bacteria. Applied Clay Science, 153, 61–69.CrossRefGoogle Scholar
Mantilla, A., Tzompantzi, F., Fernández, J.L., Díaz Góngora, J.A.I. & Gómez, R. (2010) Photodegradation of phenol and cresol in aqueous medium by using Zn/Al + Fe mixed oxides obtained from layered double hydroxides materials. Catalysis Today, 150, 353–357.CrossRefGoogle Scholar
Olszówka, J.E., Karcz, R., Bielańska, E., Kryściak-Czerwenka, J., Napruszewska, B.D., Sulikowski, B., Socha, R.P., Gaweł, A., Bahranowski, K., Olejniczak, Z. & Serwicka, E.M. (2018) New insight into the preferred valency of interlayer anions in hydrotalcite-like compounds: the effect of Mg/Al ratio. Applied Clay Science, 155, 84–94.CrossRefGoogle Scholar
Paredes-Carrera, S.P., Valencia-Martínez, R.F., Valenzuela-Zapata, M.A., Sánchez-Ochoa, J.C. & Castro-Sotelo, L. V. (2015) Study of hexavalent chromium sorption by hydrotalcites synthesized using ultrasound vs microwawe irradiation. Revista Mexicana de Ingeniería Química, 14, 429–436.Google Scholar
Pérez, E., Ayele, L., Getachew, G., Fetter, G., Bosch, P., Mayoral, A. & Díaz, I. (2015) Removal of chromium (VI) using nano-hydrotalcite/SiO2 composite. Journal of Environmental Chemical Engineering, 3, 1555–1561.CrossRefGoogle Scholar
Rivera, J.A., Fetter, G. & Bosch, P. (2006) Microwave power effect on hydrotalcite synthesis. Microporous and Mesoporous Materials, 89, 306–314.CrossRefGoogle Scholar
Rives, V., del Arco, M. & Martín, C. (2014) Intercalation of drugs in layered double hydroxides and their controlled release: a review. Applied Clay Science, 88–89, 239–269.CrossRefGoogle Scholar
Rocha Oliveira, G., Dias do Amaral, L.J., Giovanela, M., da Silva Crespo, J., Fetter, G., Rivera, J.A., Sampieri, A. & Bosch, P. (2015) Bactericidal performance of chlorophyllin–copper hydrotalcite compounds. Water, Air, & Soil Pollution, 226, 226–316.CrossRefGoogle Scholar
Sommer, A., Fetter, G., Bosch, P. & Lara, V.H. (2010) New template effect in hydrotalcite synthesis. nodular vs layered morphologies. Clays and Clay Minerals, 58, 340–350.CrossRefGoogle Scholar
Tran, H.N., Lin, C.C., Woo, S.H. & Chao, H.P. (2018) Efficient removal of copper and lead by Mg/Al layered double hydroxides intercalated with organic acid anions: adsorption kinetics, isotherms, and thermodynamics. Applied Clay Science, 154, 17–27.CrossRefGoogle Scholar
Velázquez-Herrera, F.D., Fetter, G., Rosato, V., Pereyra, A.M. & Basaldella, E.I. (2018) Effect of structure, morphology and chemical composition of Zn–Al, Mg/Zn–Al and Cu/Zn–Al hydrotalcites on their antifungal activity against A. niger. Journal of Environmental Chemical Engineering, 6, 3376–3383.CrossRefGoogle Scholar
Wang, Q. & O'Hare, D. (2012) Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets. Chemical Reviews, 112, 4124–4155.CrossRefGoogle ScholarPubMed
Xie, X., Ren, X., Li, J., Hu, X. & Wang, Z. (2006) Preparation of small particle sized ZnAl-hydrotalcite-like compounds by ultrasonic crystallization. Journal of Natural Gas Chemistry, 15, 100–104.CrossRefGoogle Scholar
Xu, Z.P. & Zeng, H.C. (2001) Abrupt structural transformation in hydrotalcite-like compounds Mg1-xAlx(OH)2(NO3−)x⋅nH2O as a continuous function of nitrate anions. Journal of Physical Chemistry B, 105, 1743–1749.CrossRefGoogle Scholar
Zhu, R., Wang, T., Ge, F., Chen, W. & You, Z. (2009) Intercalation of both CTMAB and Al13 into montmorillonite. Journal of Colloid and Interface Science, 335, 77–83.CrossRefGoogle ScholarPubMed