Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-26T07:20:15.492Z Has data issue: false hasContentIssue false

Experimental studies of fine-grained micas

I. Organic contamination on the surface of wet-ground muscovite

Published online by Cambridge University Press:  09 July 2018

P. G. Rouxhet
Affiliation:
Materials Research Laboratory, and Department of Geochemistry and Mineralogy, Pennsylvania State University, University Park, Pennsylvania, U.S.A.
G. W. Brindley
Affiliation:
Materials Research Laboratory, and Department of Geochemistry and Mineralogy, Pennsylvania State University, University Park, Pennsylvania, U.S.A.

Abstract

The surface properties of wet-ground muscovite were studied by thermodynamics of water adsorption. The surface appears to be covered by contaminating material, probably organic, which is strongly held; it was not removed at 350° C and under a vacuum of 10−4 torr. Attention is directed to the difficulty of maintaining freshly made silicate surfaces without contamination and to the importance of surface conditions in the interpretation of silicate properties which involve surface phenomena.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1966

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barshad, I. (1960) Clays and Clay Minerals, Proc. 8th Conf., p. 84. Pergamon Press, Oxford.Google Scholar
Bellamy, L.J. (1958) The Infrared Spectra of Complex Molecules, Chap. II, p. 13. Methuen, London; Wiley, New York.Google Scholar
Bradley, W.F. & Grim, R.E. (1961) The X-ray Identification and Crystal Structures of Clay Minerals (Brown, G., editor), Chap. V, p. 215. Mineralogical Society, London.Google Scholar
Brindley, G.W., Takeshi, H. & Wentworth, S.A. (1963) Annual Report, p. 1. American Petroleum Institute, Project 55.Google Scholar
Brunauer, S. (1945) The Adsorption of Gases and Vapors, Vol. I, p. 82. Princeton University Press.Google Scholar
Every, R.L., Wade, W.H. & Hackerman, N. (1961) J. phys. Chem., Wash. 65, 25.Google Scholar
Fripiat, J.J., Jelli, A., Poncelet, G. & André, J. (1965) J. phys. Chem., Wash. 69, 2185.Google Scholar
Gaines, G.L. (1958) J. phys. Chem., Wash. 62, 1526.CrossRefGoogle Scholar
Gaines, G.L. (1961) Solid Surfaces and the Gas-Solid Interfaces (Gould, R.F., editor), p. 264. Advances in Chemistry Series, No. 33. American Chemical Society, Washington.Google Scholar
Hill, T.L. (1949) J. phys. Chem., Wash. 17, 520.Google Scholar
Livingston, A.K. (1949) J. Colloid Sci. 4, 447.Google Scholar
Martin, R.T. (1960) Clays and Clay Minerals, Proc. Sth Conf., p. 102. Pergamon Press, Oxford.Google Scholar
Mooney, R.W., Keenan, A.G. & Wood, L.A. (1952) J. Am. chem. Soc. 74, 1367.CrossRefGoogle Scholar
Rosenqvist, I.Th. (1963) Clays and Clay Minerals, Proc. 11th Conf., p. 117. Pergamon Press, Oxford.Google Scholar
Rouxhet, P. & Fripiat, J.J. (1966) Bull Grpe fr. Argiles. 17, 81.Google Scholar
Wentworth, S.A. & Brindley, G.W. (1965) Annual Report, p. 1. American Petroleum Institute, Project 55.Google Scholar