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Adsorption-desorption processes of azo dye on natural bentonite: batch experiments and modelling

Published online by Cambridge University Press:  27 February 2018

A. Berez ,
F. Ayari ,
N. Abidi ,
G. Schäfer  and
M. Trabelsi-Ayadi
A. Berez
Affiliation:
Laboratoire d’Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement (LACReSNE)- UR 05- ES 09 Université de Carthage, Faculté des Sciences de Bizerte, Zarzouna, 7021 Bizerte, Tunisia Laboratoire d’Hydrologie et de Géochimie de Strasbourg (LHyGeS) - UMR 7517 Centre National de Recherche Scientifique, Université de Strasbourg, ENGEES, 1 rue Blessig, 67084 Strasbourg Cedex, France
F. Ayari
Affiliation:
Laboratoire d’Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement (LACReSNE)- UR 05- ES 09 Université de Carthage, Faculté des Sciences de Bizerte, Zarzouna, 7021 Bizerte, Tunisia
N. Abidi
Affiliation:
Laboratoire d’Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement (LACReSNE)- UR 05- ES 09 Université de Carthage, Faculté des Sciences de Bizerte, Zarzouna, 7021 Bizerte, Tunisia Laboratoire d’Hydrologie et de Géochimie de Strasbourg (LHyGeS) - UMR 7517 Centre National de Recherche Scientifique, Université de Strasbourg, ENGEES, 1 rue Blessig, 67084 Strasbourg Cedex, France
G. Schäfer*
Affiliation:
Laboratoire d’Hydrologie et de Géochimie de Strasbourg (LHyGeS) - UMR 7517 Centre National de Recherche Scientifique, Université de Strasbourg, ENGEES, 1 rue Blessig, 67084 Strasbourg Cedex, France
M. Trabelsi-Ayadi
Affiliation:
Laboratoire d’Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement (LACReSNE)- UR 05- ES 09 Université de Carthage, Faculté des Sciences de Bizerte, Zarzouna, 7021 Bizerte, Tunisia
*
*E-mail: [email protected]
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Abstract

The purpose of this study was to determine whether a bentonite from the Gafsa deposit (western Tunisia) could be used to remove the Foron Blue 291 (FB) azo dye from wastewater. Batch adsorption and desorption experiments were conducted using untreated and purified bentonite and the influence of contact time, pH, adsorbent mass and temperature of the dye solution on the adsorption of FB was evaluated. Kinetic and isotherm data were fitted using two non-linear kinetic and two non-linear isotherm equations. In addition, the fits were evaluated using the coefficient of determination (R2) and the RMSE. The percentage of dye removal increased with increasing amount of adsorbent until total discolouration was achieved. The adsorption isotherms followed the Langmuir model, with the purified bentonite having a higher adsorption capacity than the raw material due to its higher specific surface area. In addition, the FB molecules were removed from the liquid medium by physical adsorption. Batch desorption experiments were conducted to study the desorption kinetics and the characteristics of the desorption isotherms as well as to quantify the portion of the FB (by mass) that was irreversibly fixed on the solid. Overall, the desorption kinetics were similar to the adsorption kinetics, which indicated that the adsorption-desorption process of azo dye is non-singular; irreversibility occurred that was underlined by an observed thermodynamic index of irreversibility (TII) of 0.69–0.94. The desorption isotherms of the FB depended on the mass of the FB that was initially adsorbed on the bentonite sample, suggesting hysteresis. The amount of irreversibly retained FB was between 46 and 68% of the initial adsorbed mass.

Keywords

adsorption isothermsdesorptionirreversibilitybentoniteazo dyekinetics
Type
Research Article
Information
Clay Minerals , Volume 49 , Issue 5 , December 2014 , pp. 747 - 763
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2014

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References

Abdullah, A.R., Sinnakkannu, S. & Tahir, N.M. (2001) Adsorption, desorption, and mobility of metsulfuron methyl in Malaysian agricultural soils. Bulletin of Environmental Contamination and Toxicology, 71, 655–661.Google Scholar
Al-Qodah, Z. (2000) Adsorption of dyes using shale oil ash. Water Research, 34, 4295–4303.Google Scholar
Atun, G. & Sismanoglu, T. (1996) Adsorption of 4,4%- isopropylidenediphenol and diphenylolpropane 4,4%-dioxyacetic acid from aqueous solution on kaolinite. Journal of Environmental Science and Health, Part A, 31, 2055–69.Google Scholar
Auta, M. & Hameed, B.H. (2012) Modified mesoporous bentonite adsorbent for adsorption isotherm and kinetics of methylene blue. Chemical Engineering Journal, 198-199, 219–227.Google Scholar
Auta, M. & Hameed, B.H. (2013) Coalesced chitosan activated carbon composite for batch and fixed-bed adsorption of cationic and anionic dyes. Colloids and Surfaces B. Biointerfaces, 105, 199–206.CrossRefGoogle ScholarPubMed
Auta, M. & Hameed, B.H. (2014) Chitosan-bentonite composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue. Chemical Engineering Journal, 237, 352–361.Google Scholar
Benguella, B. & Yacouta-Nour, A. (2009) Elimination des colorants acides en solution aqueuse par la bentonite et le kaolin. Comptes Rendue Chimie, 12, 762–771.Google Scholar
Bergaya, F. & Vayer, M. (1997) CEC of clay; Measurement by adsorption of a copper ethylene diamine complexem. Applied Clay Science, 12, 275–280.Google Scholar
Bes-Piá, A., Mendoza-Roca, J.A., Roig-Alcover, L., Iborra-Clar, A. & Alcaina-Miranda, M.I. (2003) Comparison between nanofiltration and ozonation of biologically treated textile wastewater for its reuse in the industry. Desalination, 157, 81–86.Google Scholar
Bouna, L., Rhouta, B., Maury, F., Jada, A., Senocq, F. & Lafont, M. C. (2014) Photocatalytic activity of T.O. / stevensite nanocomposites for the removal of Orange G from aqueous solutions. Bentonite Minerals, 49, 417–428.Google Scholar
Bouras, O. (2003) Propriétés adsorbantes d’argiles pontées organophiles: synthe`se et caractérisation. PhD Thesis, Université de Limoges, France.Google Scholar
Bujdák, J., Iyi, N. & Fujita, T. (2002) The aggregation of methylene blue in montmorillonite dispersions. Clay Minerals, 37, 121–133.Google Scholar
Caille`re, S., Hénin, S. & Rautureau, M. (1982) Minéralogie des argiles: Structure et propriétés physico chimiques, Tome, I., p 184. Edition Masson. Paris.Google Scholar
Das, S.K. & Chatterjee, M.K. (1993) Specific surfaces and heat of adsorption of some Indian bentonites by dye-adsorption technique. Bulletin of Materials Science, 16, 205–211.Google Scholar
Dincer, A.R., Gunes, Y., & Karakaya, N. (2007) Coalbased bottom ash (CBBA) waste material as adsorbent for removal of textile dyes tuffs from aqueous solution. Journal of Hazardous Material, 141, 529–535.Google Scholar
Dogan, M., Alkan, M., & Onganer. Y. (2000) Adsorption of methylene blue from aqueous solution onto perlite. Water, Air, and Soil Pollution, 120, 229–248.Google Scholar
Edelin, F. (1998) L’épuration physico-chimique des eaux. Edition Cebedoc, Lie`geGoogle Scholar
El Kbir, L., Ouali, M.S. & El Maleh, S. (1998) Epuration physico-chimique des rejets liquides de l’industrie textile (Zone industrielle d’El Jadida - Maroc). L’eau, l’industrie, les nuisances, 214, 54–60.Google Scholar
Eren, E. & Afsin, B. (2007) Investigation of a basic dye adsorption from aqueous solution onto raw and pretreated sepiolite surfaces. Dyes and Pigments, 73, 162–167.Google Scholar
Errais, E., Duplay, J., Elhabirib, M., Khodjac, M., Ocampod, R., Baltenweck-Guyote, R. & Darragi, F. (2012) Anionic RR120 dye adsorption onto raw bentonite: Surface properties and adsorption mechanism. Colloids and Surfaces A. Physicochemical and Engineering Aspects, 403, 69–78.Google Scholar
Eslinger, E. & Peaver, D. (1988) Bentonite Minerals for Petroleum Geologists and Engineers. SEPM Short course 22. Society of Economic Paleontologists and Mineralogists, Tulsa, USA.Google Scholar
Fernadez, N.A., Chacin, E., Gutierrez, E., Alastre, N., Llamoza, B. & Forster, C.F. (1995) Adsorption of lauryl benzyl sulfonate on algae. Bioresource Technology, 54, 111–115.Google Scholar
Gebremariam, Y.S., Beutel, W.M., Flury, M., Ames Harsh, B.J. & Avid Yonge, R.D. (2012) Nonsingular adsorption/desorption of chlorpyrifos in soils and sediments: Experimental results and modeling. Environmental Science and Technology, 46, 869–875.Google Scholar
Gerçel, O. ., Gerçel, H.F., Koparal, A.S. & ÖgÜtveren, U. .B. (2008) Removal of disperse dye from aqueous solution by novel adsorbent prepared from biomass plant material. Journal of Hazardous Materials, 160, 668–674.Google Scholar
Ghorbel-Abid, I. & Trabelsi-Ayadi, M. (2011) Competitive adsorption of heavy metals on local landfill clay. Arabian Journal of Chemistry, doi:10.1016/j.arabjc.2011.02.030.Google Scholar
Gunay, A., Ersoy, B., Dikmen, S. & Evcin, A. (2013) Investigation of equilibrium, kinetic, thermodynamic and mechanism of Basic Blue 16 adsorption by montmorillonitic bentonite. Adsorption, 19, 757–768.Google Scholar
GÜrses, A., Dogar, C., Yalcin, M., Acikyildiz, M., Bayrak, R. & Karaca, S. (2006) The adsorption kinetics of the cationic dye, methylene blue, onto bentonite. Journal of Hazardous Material, 13, 217–228.Google Scholar
Hamdaouia, O. & Naffrechoux, E. (2007) Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon . Part II. Models with more than two parameters. Journal of Hazardous Materials, 147, 401–411.Google Scholar
Ho, Y.S. & McKay, G. (1999) Pseudo-second order model for sorption processes. Process Biochemistry, 34, 451–465.Google Scholar
Ho, Y.S. & McKay, G. (2000) The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Research, 34, 735–742.Google Scholar
Huang, G., Li, Q. & Zhang, X. (2003) Adsorption and desorption of trazine by tree soils. Bulletin of Environmental Contamination and Toxicology, 71, 655–661.Google Scholar
Jain A., K., Gupta, V.K., Bhatnagar, A. & Suhas (2003) Utilization of industrial waste products as adsorbents for the removal of dyes. Journal of Hazardous Material, 101, 31–42.Google Scholar
Jovic-Jovicic, N., Milutinovic-Nikolic, A., Grzetic, I. & Jovanovic, D. (2008) Organobentonite as efficient textile dye sorbent. Chemical Engineering and Technology, 31, 567–574 Google Scholar
Kadrivelu, K., Kavipriya, M., Karthika, C., Radhika, M., Vennilamani, N. & Pattabhi, S. (2003) Utilization of various agricultural wastes for actived carbon preparation and application for the removal of dyes metal ions from aqueous solutions. Bioresource Technology, 87, 129–132.Google Scholar
Kaur, M. & Datta, M. (2011) Adsorption characteristics of acid orange 10 from aqueous solutions onto montmorillonite bentonite. Adsorption Science and Technology, 29, 301–318.Google Scholar
Kim, C.Y., Choi, H.M. & Cho, H.T. (1997) Effect of deacetylation on sorption of dyes and chromium on chitin. Journal of Applied Polymer Science, 63, 725–736.Google Scholar
Kołodynska, D., Wnetrzak Leahy, R.J.J., Hayes, M.H.B., Kwapinski, W. & Hubicki, Z. (2012) Kinetic and adsorptive characterization of biochar in metal ions removal. Chemical Engineering Journal, 197 295–305.Google Scholar
Lagergren, S. (1898) About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1–39.Google Scholar
Langmuir, I. (1916) The constitution and fundamental properties of solid sand liquids. Journal of American Chemical Society, 38, 2221–2295.Google Scholar
Langmuir, I. (1918) The adsorption of gases on plan surfaces of glass, mica and platinum. Journal of American Chemical Society, 40, 1361–1403.Google Scholar
Li, Z., Chang, P.H., Jiang, W.T., Jean, J.S. & Hong, H. (2011) Mechanism of methylene blue removal from water by swelling bentonites. Chemical Engineering Journal, 168, 1193–1200.Google Scholar
Leyva-Ramos, R., Fuentes-Rubio, L., Guerrero-Coronado, R.M. & Mendoza-Barron, J. (1995) Adsorption of trivalent chromium from aqueous solutions onto activated carbon. Journal of Chemical Technology and Biotechnology, 62, 64–67.Google Scholar
Madrigal-Monarrez, I. (2004) Rétention de pesticides dans les sols des dispositifs tampon enherbés et boisés; roˆle des matie`res organiques. PhD Thesis, Institut National Agronomique Paris-Grignon, Paris, France.Google Scholar
McKay, G., Otterburn, M.S. & Aga, J.A. (1985) Fuller’s earth and fired bentonite as absorbents for dyestuffs external mass transport processes during adsorption. Water, Air, and Soil Pollution, 26, 149–161.Google Scholar
Mhamdi, M., Gasmi, N., Elaloui, E., Kbir-Ariguib, N. & Trabelsi-Ayadi, M. (2010) Purification and characterization of smectite bentonite taken from Gafsa, Tunisia : Progressive elimination of carbonate. IOP Conference series - Material Science and Engineering, 13, 12–27.CrossRefGoogle Scholar
Morris, C., Mooney, S.J. & Young, S.D. (2008) Sorption and desorption characteristics of the dye tracer, Brilliant Blue F.F. in sandy and bentonite soils. Geoderma, 146, 434–438.Google Scholar
Namayam, C. & Kanchana, N. (1992) Waste banana pith as adsorbent for color removal from wastewaters. Chemosphere, 25, 1691–1705.Google Scholar
Namasivayam, C. & Yamuna, R.T. (1992) Removal of Congo Red from aqueous solution by biogas waste slurry. Journal of Chemical Technology and Biotechnology, 53, 153–157.Google Scholar
Ozdemir, E., Duranoglu, D., Beker, U. & Avci, A.O. (2011) Process optimization for Cr(VI) adsorption onto activated carbons by experimental design. Chemical Engineering Journal, 172, 207–218 Google Scholar
Pannuzo, S., & Rovel, J.M. (2000) Traiter l’eau et les effluents industriels par les techniques membranaires et d’autres techniques couplées. L’eau, l’industrie, les nuisances, 235, 123–128.Google Scholar
Periasamy, K. & Namasivayam, C. (1994) Process development for removal and recovery of cadmium from wastewater by a low cost adsorbent: adsorption rates and equilibrium studies. Industrial and Engineering Chemistry Research, 33, 317–320.Google Scholar
Qadeer, R. (2007) Adsorption behavior of ruthenium ions on activated charcoal from nirtic acid medium. Journal of C. lloids and Surface s A. Physicochemical and Engineering Aspects, 293, 217–223.Google Scholar
Rahman, A., Urabe, T. & Kishimoto, N. (2013) Color removal of reactive procion dyes by clay adsorbents. Procedia Environmental Sciences, 17, 270–278.Google Scholar
Safa, Y. & Bhatti, H.N. (2011) Kinetic and thermodynamic modeling for the removal of Direct Red-31 and Direct Orange-26 dyes from aqueous solutions by rice husk. Desalination, 272, 313–322.Google Scholar
Sander, M., Lu, Y. & Pignatello, J.J. (2005) A thermodynamically based method to quantify true sorption hysteresis. Journal of Environmental Quality, 34, 1062–1072.Google Scholar
Senthilkumaar, S., Kalaamani, P. & Subburaam, C.V. (2006) Liquid phase adsorption of crystal violet onto activated carbons derived from male flowers of coconut tree. Journal of Hazardous Materials, 136, 800–808.Google Scholar
Sharma, D.C. & Forster, C.F. (1996) Removal of hexavalent chromium from aqueous solutions by granular activated carbon. Water SA, 22, 153–160.Google Scholar
Sørensen, T. (1996) Textilkemi 3. Farvning og Trykning, April 1996.Google Scholar
Souabi, S. (1996) Study on removal of the dyes from textile industry rejections. Techniques Sciences Methods, 3, 181–185.Google Scholar
Srinivasan, A. & Viraraghavan, T. (2010) Decolorization of dye wastewaters by biosorbents: a review. Journal of Environmental Management, 91, 1915–1929.CrossRefGoogle ScholarPubMed
Van Olphen, H. (1963) An Introduction to Bentonite Colloid Chemistry. Interscience Publishers, NY London.Google Scholar
Wang, Y., Wang, W. & Wanga, A. (2013) Efficient adsorption of methylene blue on an alginate-based nanocomposite hydrogel enhanced by organo-illite/ smectite bentonite. Chemical Engineering Journal, 228, 132–139.Google Scholar
Wehrhan, A., Streck, T., Groeneweg, J., Vereecken, H. & Kasteel, R. (2010) Long-term sorption and desorption of sulfadiazine in soil: Experiments and modeling. Journal of Environmental Quality, 39, 654–666.Google Scholar
Worrall, F., Parker, A., Rae, J.E. & Johnson. A.C. (1997) A study of the adsorption kinetics of isoproturon on soil and subsoil. Chemosphere, 34, 71–86.Google Scholar
Yaneva, Z. & Koumanova, B. (2006) Comparative modelling of mono- and dinitrophenols sorption on yellow bentonite from aqueous solutions. Journal of Colloid and Interface Science, 293, 303–311.Google Scholar
Yin, Y.J., Allen, H.E., Huang, C.P., Sparks, D.L. & Sanders, P.F. (1997) Kinetics of mercury (II) adsorption and desorption on soil. Environmental Science and Technology, 31, 496–503.Google Scholar
Zhou, Q. & Wang, M. (2010) Adsorption-desorption characteristics and pollution behavior of reactive X. 3B red dye in four Chinese typical soils. Journal of Soil Sediments, 10, 1324–1334.Google Scholar
Zollinger, H. (1987) Color Chemistry: Synthesis, Properties and Application of Organic Dyes and Pigments. VCH Publishers, New York.Google Scholar