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Adsorption capacity of sodic- and dendrimers-modified stevensite

Published online by Cambridge University Press:  22 August 2018

Mohamed Hajjaji ,
Abdellah Beraa ,
Yannick Coppel ,
Régis Laurent  and
Anne-Marie Caminade
Mohamed Hajjaji*
Affiliation:
Laboratoire de Physico-chimie des Matériaux et Environnement, Unité Associée au CNRST (URAC 20), Faculté des Sciences Semlalia, Université Cadi Ayyad, B.P. 2390, Av. Pce My Abdellah, 40001, Marrakech, Morocco
Abdellah Beraa
Affiliation:
Laboratoire de Physico-chimie des Matériaux et Environnement, Unité Associée au CNRST (URAC 20), Faculté des Sciences Semlalia, Université Cadi Ayyad, B.P. 2390, Av. Pce My Abdellah, 40001, Marrakech, Morocco CNRS, LCC (Laboratoire de Chimie de Coordination du CNRS), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
Yannick Coppel
Affiliation:
CNRS, LCC (Laboratoire de Chimie de Coordination du CNRS), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
Régis Laurent
Affiliation:
CNRS, LCC (Laboratoire de Chimie de Coordination du CNRS), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
Anne-Marie Caminade
Affiliation:
CNRS, LCC (Laboratoire de Chimie de Coordination du CNRS), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France
*
*E-mail: [email protected]
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Abstract

The adsorption capacities of nano-sized organoclays composed of a stevensite-rich clay (R), phosphorus dendrimers (GC1 and GC2) and Na+-saturated clay were evaluated for their capacity to adsorb chromate and methylene blue (MB) in the range of 298–318 K. The adsorption kinetics and the isotherms were analysed based on kinetic equations and isotherm models and by adopting a non-linear regression procedure. In addition, the organoclays and the Na+-saturated clays were characterized principally by solid-state nuclear magnetic resonance spectroscopy. The pseudo-second-order rate equation described kinetics data well, and the adsorption rates were not limited by the intraparticle diffusion or by the liquid film diffusion. Both chemical species were adsorbed spontaneously (–31 < ΔG°T< –10 kJ/mol), but the adsorbents had a high affinity for MB species. The adsorption isotherms of chromate were fitted better by the Freundlich model, while those of MB followed the Langmuir model. Chromate adsorption took place at the edges and the free surfaces of stevensite, particularly at the protonated aluminols. MB was adsorbed as MBH2+ and MB+. The MB protonation occurred at the clay surfaces, and MB+ ions were located at the planar surfaces of stevensite as well as at the external surfaces of aggregates. Moreover, the tetrahedral sheet of stevensite involved in the formation of GC1-based organoclays was the subject of a partial chemical modification.

Keywords

stevensitedendrimerschromatemethylene blueadsorptioncharacterization
Type
Article
Information
Clay Minerals , Volume 53 , Issue 3 , September 2018 , pp. 525 - 544
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Associate Editor: Laurent Michot

References

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