Hostname: page-component-745bb68f8f-f46jp Total loading time: 0 Render date: 2025-02-04T17:43:52.433Z Has data issue: false hasContentIssue false
  • English
  • Français

The oxides and hydroxides of iron and their structural inter-relationships

Published online by Cambridge University Press:  14 March 2018

J. D. Bernal ,
D. R. Dasgupta  and
A. L. Mackay
J. D. Bernal
Affiliation:
Birkbeck College, 21 Torrington Square, LondonW.C.I.
D. R. Dasgupta
Affiliation:
Birkbeck College, 21 Torrington Square, LondonW.C.I.
A. L. Mackay
Affiliation:
Birkbeck College, 21 Torrington Square, LondonW.C.I.
Get access

Abstract

The transformations in the iron oxide-hydroxide system have been interpreted in a rational crystallochemical manner, some being characterized as topotactic and some as non-topotactic. Crystallographic measurements have been made on the more reactive or metastable phases, particularly on the “green rusts.” The oxyhydroxides β-FeOOH and δ-FeOOH have been examined more fully, but data on all the phases have been checked. New data on transformations, such as FeCO3 → FeO and Fe(OH)2 → FeO are reported.

Type
Research Article
Information
Clay Minerals Bulletin , Volume 4 , Issue 21 , August 1959 , pp. 15 - 30
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1959

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Abe, R., 1951. J. phys. Soc., Japan, 6, 345.Google Scholar
Bernal, J D , Dasgupta, O. R. and Mackay, A. L., 1957. Nature, Lond., 180, 645.CrossRefGoogle Scholar
Byström, A. and Byström, A. M., 1950. Acta cryst., 3, 146.CrossRefGoogle Scholar
Braun, P. B., 1952. Nature, Lond., 170, 1123.CrossRefGoogle Scholar
Clark, L. M., Hedley, A. G. M. and ROBINSON, J. G., 1944. J. Soc. chem. Ind., Lond., 63, 208.Google Scholar
Collongues, R., 1954. Thesis, Paris.Google Scholar
Feitknecht, W. and Bucher, H., 1943. Helv. chim. acta, 26, 2177.CrossRefGoogle Scholar
Francombe, M. H. and Rooksby, H. P., 1959. Clay Min. Bull., 4, 1.CrossRefGoogle Scholar
Glemser, O. and Gwinner, E., 1939. Z. anorg. Chem., 240, 163.Google Scholar
Goldsztaub, S., 1931. C. R. .4cad. Sci., Paris, 193, 533.Google Scholar
Goodman, J. F., 1958. Proc. Roy. Soc., A247, 346.Google Scholar
Keller, G., 1948. Thesis, Bern. See also Feitknecht, W. and. Keller, G., 1950. Z. anorg. Chem., 262, 61.Google Scholar
Kratky, O. and Nowotny, H., 1938. Z. Kristallogr. A100, 356.Google Scholar
Natta, G. and Casazza, A., 1928. Gazz. chim. ital., 58, 344.Google Scholar
van Oosterhout, G. W. and Rooumans, C. J. M., 1958. Nature, Lond., 181, 44.CrossRefGoogle Scholar
Sn∼wick, N. V., 1950. The Chemical Elements and their Compounds. Oxford Univ. Press.Google Scholar
Wetser, H. B. and Milligan, W. O., 1935. d. phys. Chem., 39, 25.Google Scholar
Wells, A. F., 1949. Acta cryst., 2, 175.CrossRefGoogle Scholar
Yosmoka, H., 1948. Kagaku, 18, No. 9, 413 Google Scholar