Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-16T17:09:01.179Z Has data issue: false hasContentIssue false

The Berthollet-Proust Controversy and Dalton's Chemical Atomic Theory 1800–1820

Published online by Cambridge University Press:  05 January 2009

Kiyohisa Fujii
Affiliation:
Tokyo Institue of Technology, Department of Science Education, 2–12–1 Ookayama, Meguro-ku, Tokyo, Japan.

Extract

The Berthollet-Proust controversy and Dalton's atomic theory are two important historical landmarks which appeared almost simultaneously at the very beginning of the nineteenth century. Therefore it is likely that between the theory of definite proportions—one of the main subjects of the controversy–and Dalton's atomic theory there was an important interrelation, and that they reinforced each other. Kapoor has suggested that Proust could not have been the forerunner of Dalton's law of constant and multiple proportions, because Dalton discovered his law from completely different premises, and does not seem to have got his ideas from Proust. In my opinion, however, his conclusion does not seem to be decisive.

Type
Research Article
Copyright
Copyright © British Society for the History of Science 1986

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

I am most grateful to Dr David M. Knight of Durham University for patiently reading a draft of this paper and giving me valuable suggestions and advice, and also to a anonymous referee of this journal for offering many useful suggestions. I would also like to thank the staff of Durham University Library and the Library of Tokyo Institute of Technology for their assistance in obtaining materials required for the study.

1. The important articles on the controversy are Holmes, F. L.: ‘From Elective Affinities to Chemical Equilibria: Berthollet's Law of Mass Action’. Chymia, (1962), 8, p. 105145CrossRefGoogle Scholar; Kapoor, S. C.: ‘Berthollet, Proust, and Proportions’. Chymia, (1965), 10, p. 53110CrossRefGoogle Scholar; Sadoun-Goupil, M.: Le Chemiste Claude-Louis Berthollet. Paris, 1977, ch. VIII, p. 195208Google Scholar; The older ones are Meldrum, A. N.: ‘The Development of the Atomic Theory: (1) Berthollet's Doctrine of Variable Proportions’. Manchester Memoirs, (1910), liv, No.7, p. 116Google Scholar; Freund, I.: The Study of Chemical Compostion. Cambridge, 1904Google Scholar; reprinted, New York, 1968, chapter V, especially p. 127–143; Partington, J. R.: A History of Chemistry, 5 vols, London, 19611970, iii, ch. XIV, especially p. 644653.Google Scholar

2. Kapoor, ibid., 87n.

3. Berthollet, C. L.: Essai de Statique Chimique. 2 vols, Paris, 1803Google Scholar; reprinted, Bruxelles, 1968, i, p. 339.

4. Proust, J. L.: ‘Recherches sur le bleu de Prusse’.Ann. de. chim. (1797), 23, p. 101.Google Scholar

5. Kapoor, , op. cit. (1), p. 9498.Google Scholar

6. Proust, : ‘Sur les sulfures métalliques’. J. de phys., (1804), 59, p. 261.Google Scholar

7. Proust, : ‘Memoire pour servir a l'histoire de l'antimoine’. J. de phys., (1802)-2 55, p. 335.Google Scholar

8. Mauskopf, S. H.: ‘Crystals and Compounds’. Trans. Am. Phil. Soc. (1967), 66, part III, section I and II, p. 720.Google Scholar

9. Nash, L. K.: ‘The Origin of Dalton's Chemical Atomic Theory’, Isis, (1956), 47, p. 101116CrossRefGoogle Scholar; Guerlac, H.: ‘Some Daltonian Doubts’. Isis, (1961), 52, p. 544554CrossRefGoogle Scholar; Siegfried, R.: ‘Further Daltonian Doubts’, Isis, (1963), 54, p. 480481Google Scholar; Thackray, A. W.: ‘The Emergence of Dalton's Chemical Atomic Theory: 1801–1808’. Br. J. Hist. Sci. (1966), 3, Pt. 1, p. 122CrossRefGoogle Scholar; ‘The Origin of Dalton's Chemical Atomic Theory: Daltonian Doubts Resolved’. Isis, (1966), 57, p. 3555Google Scholar; John Dalton: Critical Assessments of His Life and Science. Massachusetts, 1972Google Scholar; Mauskopf, S. H.: ‘Haüy's model of Chemical Equivalence: Daltonian Doubts Exhumed’. Ambix, (1970), 17, No. 3, p. 182191CrossRefGoogle Scholar; Fleming, R. S.: ‘Newton, Gases, and Daltonian Chemistry: The Foundations of Combination in Definite Proportions’. Ann. Sci. (1974), 31, p. 561574CrossRefGoogle Scholar; Smeaton, W. A.: ‘Berthollet's Essai de statique chimique and its translations: A Biographical Note and a Daltonian Doubt’. Ambix, (1977), 24, No.3, p. 149158CrossRefGoogle Scholar; (1978), 25, No. 3, p. 211; Cole, T. JrDalton, Mixed Gases, and the Origin of the Chemical Atomic Theory’. Ambix, (1978), 25, No.2, p. 117130.CrossRefGoogle Scholar

10. Some historians of chemistry hold that this does not seem to be the case. See, for example, Fleming, ibid. and Cole Jr., ibid

11. Smeaton, , op. cit. (9).Google Scholar

12. Roscoe, H. E. & Harden, A..: A New View of the Origin of Dalton's Atomic Theory. London, 1896; reprinted, New York and London, 1970, p. 79.Google Scholar

13. Meldrum, A. N.: ‘The Development of the Atomic Theory: (2) The Various Accounts of the Origin of Dalton's Theory. Manchester Memoirs, (1910). lv. No. 3, p. 4.Google Scholar

14. Thackray, , op. cit. (9)Google Scholar, ‘The Origin’, p. 53.Google Scholar

15. Dalton, J.: A New System of Chemical Philosophy, 2 vols, Manchester, 18081827; reprinted, London, i, part I, p. 142.Google Scholar

16. Proust, , op. cit. (4), p. 85101Google Scholar; Nicholson's J. (1798), 1, p. 453457.Google Scholar

17. Proust, ibid., Nicholson's J. p. 457.Google Scholar

18. Proust, : ‘Recherches sur l'etain’. Ann. de chim. (1798), 28, p. 213222Google Scholar; Nicholson's J.. (1799), 2, p. 515518.Google Scholar

19. Proust, : ‘Sur Quelques sulfures métalliquesJ. de Phys. (1801), 53, p. 8997Google Scholar; Nicholson's J. (1802), 6, p. 268275.Google Scholar

20. Proust, : ‘Sur les sulfures natifs et artificiels du fer’. J. de phys. (1802), 54, p. 8995Google Scholar; Nicholson's J. (1802), 6, p. 268275.Google Scholar

21. Proust, , op. cit. (6), p. 260265Google Scholar; Phil Mag. (1805), 21, p. 208213.Google Scholar

22. Thomson, T.: A System of Chemistry. 1st edn. 4 vols, Edinburgh, 1802, i, p. 116.Google Scholar

23. Thomson, ibid., i, p. 124.

24. Thomson, ibid., i, p. 169.

25. Thomson, ibid., i, p. 184.

26. Thomson, ibid., i, p. 230.

27. Thomson, ibid., iii, p. 195

28. Thomson, ibid., iii, p. 196–197.

29. Thomson, ibid., iii, p. 197.

30. Thomson, ibid., iii, p. 198.

31. Thomson, ibid., iii, p. 199.

32. Thomson, ibid., iii, p. 199–202.

33. Thomson, ibid., iii, p. 202.

34. Mauskopf, : ‘Thomson before Dalton’. Ann. Sci. (1969), 25, p. 237.CrossRefGoogle Scholar

35. Dalton, : ‘New Theory of the Constitution of Mixed Gases Elucidated’. Phil Mag. (1802), 14, p. 169173CrossRefGoogle Scholar; Nicholson's J. (1802), 3, p. 267271.Google Scholar

36. Henry, W. C.: Memoirs of the Life and Scientific Researches of John Dalton. London, 1854, p. 8485.Google Scholar

37. Thackray, , op. cit. (9)Google Scholar, ‘The Origin’ Greenway, F.: John Dalton and the Atom. New York, 1966, p. 136137, p. 234236Google Scholar; Patterson, E. C.: John Dalton and the Atomic Theory. New York, 1970, p. 197199.Google Scholar

38. Guerlac, , op. cit. (9).Google Scholar

39. Guerlac, ibid., p. 552.

40. Smeaton, , op. cit. (9).Google Scholar

41. Dalton, : ‘Experimental Enquiry into the Proportion of Several Gases or Elastic Fluid, Constituting the Atmosphere’. Manchester Memoirs, (1805), II, 1, p. 244258.Google Scholar

42. Roscoe, & Harden, , op. cit. (12), p. 3738.Google Scholar

43. Dalton, , op. cit. (41), p. 250.Google Scholar This paper was originally read to the Manchester Lit. and Phil. Society on 12 November 1802. But it might have been revised before publication, for Dalton was one of the secretaries of the Society since 1800, and thus he could probably have revised his manuscript before printing.

44. Patterson, , op. cit. (37), p. 99Google Scholar; Guerlac, , op. cit. (9), p. 551Google Scholar; Meldlrum, : ‘The Development of the Atomic Theory: (5) Dalton's Chemical Theory’. Manchester Memoirs, (1911), lv, No. 6. 13Google Scholar; Roscoe, & Harden, , op. cit. (12). p. 33.Google Scholar

45. Proust, , op. cit. (4), p. 85.Google Scholar The English translation appeared in the Nicholson's J.: ‘A great number of facts prove, on the contrary, that iron does not rest indifferently at all the different degrees of oxidation between the two terms above mentioned’, (op. cit. (16), Nicholson's J. p. 453).Google Scholar

46. In 1804 Proust wrote: ‘Si la nature ou l'art ne nous offrent nulle part des rapport intermédiates entre ces terms, nous ne devons done pas nous presser d'admettre sulfuration variable’. (Proust, , op. cit. (6) p. 261Google Scholar; Phil. Mag. (1805), 21, p. 209).Google Scholar

47. Dalton, , op. cit. (41), p. 250Google Scholar

48. Cole, Jr, op. cit. (9).Google Scholar

49. Thomson, : ‘Chemistry’. In: Supplement to the Third Edition of the Encyclopaedia Britannica or A Dictionary of the Arts, Sciences and Miscellaneous Literature. 2 vols, Edinburgh, 1801, i, p. 249.Google Scholar

50. Thomson, ibid., p. 249.

51. Mauskopf, , op. cit. (34), p. 229242.Google Scholar

52. Mauskopf, ibid., p. 230–231.

53. Thomson, , op. cit. (49), p. 343.Google Scholar

54. Thomson, ibid., p. 343.

55. Thomson, : A System of Chemistry. 3rd edn., 5 vols, Edinburgh, 1807, iv, p. 7.Google Scholar

56. Thomson, ibid., iii, p. 424–429. Therefore Thackray has concluded that: ‘The particular development of Dalton, which distinguishes his chemical atomic theory from earlier work, was his devising of an effective system to obtain these relative particle weights from currently available chemical data’, (Thackray, , op. cit. (9) ‘The Origin’, p. 37.Google Scholar

57. Thomson, , ‘On Oxalic Acid’. Phil. Trans. (1808), 6395.Google Scholar

58. Thomson, ibid., p. 87.

59. Thomson, ibid., p. 88.

60. Thomson, : ‘On the Daltonian Theory of Definite Proportions in Chemical Combinations’. Ann. Phil. (1813), 2, p. 3252, 109115, 167171, 293301Google Scholar; (1814), 3, p. 134–140, 375–378; (1814), 4, p. 11–18, 83–89.

61. Thomson, : A System of Chemistry. 5th edn., 4 vols, Edinburgh, 1817, i. p. 19.Google Scholar

62. Thomson, : The History of Chemistry. 2 vols, London, 1831Google Scholar; reprinted. New York, 1975, ii, p. 160.

63. Thomson, ibid., ii, p. 162.

64. Thomson, ibid., ii, p. 163.

65. Kapoor, , op. cit. (1), p. 107108.Google Scholar

66. Davy, H.: ‘On Some Chemical Agencies of Electricity’. Phil. Trans. (1807)Google Scholar; Collected Works, 9 vols London, 18391840Google Scholar, reprinted, New York and London, 1972, v, p. 41.

67. Söderbaum, H. G., ed.: Jac. Berzelius Bref. 6 vols., Stockholm and Uppsala, 19121932, i(ii), p. 22.Google Scholar

68. Davy, H.: ‘On Some New Electro-Chemical Researches, on Various Objects, particularly the Metallic Bodies, from the Alkalies and Earths, and on Some Combinations of Hydrogen’. Phil. Trans. (1810), Works, v, p. 271272.Google Scholar

69. Davy, ibid., p. 272n.

70. Davy, : ‘Researches on the Oxymuriatic Acid, Its Nature and Combinations; and on the Elements of the Muriatic Acid: with Some Experiments on Sulphur and Phosphrous, made in the Laboratory of the Royal Institution’. Phil. Trans. (1810), Works, v, p. 310.Google Scholar

71. Davy, : ‘On Some of the Combinations of Oxymuriatic Gas and Oxygen, and on the Chemical Relations of these Principles, to Inflammable Bodies’. Phil. Trans. (1811), Works, v, p. 328n.Google Scholar

72. Davy, , op. cit. (70), p. 297.Google Scholar

73. Davy, , Elements of Chemical Philosophy. London, 1812, Works, iv, p. 85.CrossRefGoogle Scholar

74. Holmes, , op. cit. (1), p. 118.Google Scholar

75. Davy, , op. cit. (73), p. 8586.Google Scholar

76. Holmes, , op. cit. (1), p. 118.Google Scholar

77. Davy, , op. cit. (73), p. 87.Google Scholar

78. Davy, ibid., p. 89.

79. Davy, ibid., p. 83.

80. Goodman, D. G.: ‘Wollaston and the Atomic Theory of Dalton’. Hist. Stud. Phy. Sci. (1967), 1, p. 3759.Google Scholar

81. Wollaston, W. H.: ‘On Super-acid and Sub-acid Salts’. Phil. Trans. (1808), p. 96102.Google Scholar

82. Wollaston, ibid., p. 101.

83. Wollaston, : ‘On the Elementary Particles of Certain Crystals’. Phil. Trans. (1813), p. 5163.Google Scholar

84. Wollaston, : ‘A Synoptic Scale of Chemical Equivalents’. Phil. Trans. (1814), p. 122.Google Scholar

85. Wollaston, ibid., p. 7.

86. Wollaston, ibid., p. 4.

87. The paper Wollaston referred to is; Berthollet, : ‘Sur les rapports quantité dans les élémens des combinaisons’. Mém. de Phys. et de Chim. de la Soc. d'Arcueil, (1809), 2, p. 470484Google Scholar; reprinted, New York and London, 1967. In fact, Berthollet repeated and extended Wollaston's experiments and concluded the possibility of the formation of intermediate combinations, other than those in simple or multiple proportions.

88. Wollaston, , op. cit. (84), p. 6.Google Scholar

89. Wollaston, : ‘On the Finite Extent of the Atmosphere’. Phil. Trans. (1822), p. 8998.Google Scholar

90. Wollaston, ibid., p. 91.

91. Goodman, , op. cit. (80), p. 58.Google Scholar

92. Thenard, L. J.: ‘Les différenes états de l'oxide d'antimoine, et ses combinaisons avec l'hydrogen sulfuré’. Ann. de chim. (1799), 32, p. 257269.Google Scholar

93. Thenard, : ‘Sur les différentes combinaisons du cobalt avec oxigène, suivie de quelques observations sur plusieurs sels ammoniacométalliques’. Ann. de chim. (1802), 42, p. 210219.Google Scholar

94. Berthollet, , op. cit. (3), ii, p. 372.Google Scholar

95. Thenard, : ‘Considerations sur l'oxidation des métaux en general, et en particulier sur l'oxidation du fer’. Ann. de chim. (1805), 56, p. 62.Google Scholar

96. Thenard, ibid., p. 63.

97. Thenard, : Traité de Chimie Élémentaire, Théorique et Pratique, troisième, éd., Paris, 4 vols, 1821, i, p. 19.Google Scholar

98. Gay-Lussac also referred to Dalton's ideas as part of a ‘system’. He wrote: ‘M. Dalton a été conduit à cette idée par des consideration systématiques, et on voit par son ouvrage New System of Chemical Philosophy, p. 213’. (Gay-Lussac, : ‘Sur la combinaisons des substances gazeuses, les unes avec les autres’. Mém. de Phys. et de Chim. de la Soc. d'Arcueil, (1809), 2, p. 209nGoogle Scholar; reprinted, New York and London, 1967.) According to Crosland, the word ‘system’ reflected the eighteenth century French distrust of the over-ambitious Descartes (Crosland, M.: Gay-Lussac Scientist and Bourgeois. Cambridge, 1978, p. 139).CrossRefGoogle Scholar

99. Thenard, , op. cit. (97), p. 2324.Google Scholar

100. Gay-Lussac, J. L.: ‘Sur les précipitations mutuelles des oxides métalliques’. Ann. de chim. (1804), 49, p. 2135.Google Scholar

101. Gay-Lussac, , op. cit. (98), p. 207234.Google Scholar

102. Gay-Lussac, ibid., p. 218.

103. Crosland, M.: ‘The First Reception of Dalton's Atomic Theory in France’. In: Cardweii, D.S.L., ed,: John Dalton and the Progress of Science. Manchester and New York, 1968, p. 274289, especially p. 227278.Google Scholar

104. Dalton, : ‘Letter to Berzelius’Google Scholar. In: Roscoe, & Herden, , op. cit. (12), p. 159.Google Scholar

105. Crosland, , op. cit. (98), p. 138.Google Scholar

106. Gay-Lussac, : Cours de Chimie. 2 vols, Paris, 1828, i, p. 8.Google Scholar

107. Gay-Lussac, ibid., i, p. 9–10.

108. Gay-Lussac, ibid., i, p. 12.

109. Crosland, , op. cit. (98), p. 138.Google Scholar

110. Hassenfratz, J. H.: ‘Sur l'oxidation du fer’. Ann. de chim. (1808), 67, p. 309319.Google Scholar

111. Hassenfratz, ibid., 311.

112. Hassenfratz, ibid., 319.

113. Hassenfratz, : ‘Observations et discussion sur lex oxides de fer’. Ann. de chim. (1809), 69, p. 113154.Google Scholar

114. Haussmann, J. M.: ‘Extrait d'une lettre de M. Jean-Michel Haussmann, à M. Berthollet’. Ann. de. chim. (1805), 56, p. 514.Google Scholar

115. Scott, E. L.: ‘Dalton and William Henry’Google Scholar. In: Cardwell, D.S.L., ed, op. cit. (103), p. 233.Google Scholar

116. Henry, W.: The Elements of Experimental Chemistry. 6th edn, 2 vols, London, 1810, i, p. 8182.Google Scholar

117. Scott, , op. cit. (115), p. 233.Google Scholar

118. Henry, : The Elements of Experimental Chemistry. 8th edn., 2 vols, London, 1818, i, p. 48.Google Scholar

119. Henry, : The Elements of Experimental Chemistry. 11th edn., 2 vols, London, 1829, i, p. 52.Google Scholar

120. Henry, ibid., p. 65–67.

121. Henry, ibid., p. 67.

122. Ewart, P.: ‘Observations on Mr Dalton's Theory of Chemical Composition’. Ann. Phil. (1815), 6, p. 371378.Google Scholar

123. Ewart, ibid., p. 378.

124. Murray, I.: Elements of Chemistry. 4th edn., 2 vols, Edinburgh. 1817. i. p. 39.Google Scholar

125. Murray, ibid., p. 54–58.

126. Murray, ibid., p. 61–62.

127. Murray, ibid., p. 64.

128. Murray, : ‘Observations on the Relation of the Law of Definite Proportions in Chemical Combination, to the Constitution of the Acids. Alkalis, and the Earths’. Phil. Mag. (1819), 54, p. 90100, 182194.CrossRefGoogle Scholar

129. Holmes, , op. cit. (1), p. 121.Google Scholar

130. Berzelius, J. J.: ‘Sur les proportions déterminées dans lequelles se trouvent réunis les élémens de la nature inorganique’. Ann, de chim. (1811), 78, p. 537. 105132, 217242Google Scholar; 79, p. 113–142; 80, p. 5–37, 225–258; (1812), 81, p. 5–56; 82, p. 5–33. 113–125, 225–272; 83, p. 5–35. 117–131; Phil. Mag. (1813), 41, p. 38, 8190, 197205. 275284, 334346, 401415Google Scholar; 42, p. 40–44, 135–142, 171–182, 265–276, 371–386, 440–463; (1814), 43, p. 42–54. 88–101, 161–175, 245–249.

131. Berzelius, ibid., Ann. de chim. (1812), 83, p. 117Google Scholar; Phil, Mag. (1814). 43, p. 245.Google Scholar

132. Berzelius. ibid., Ann. de chim. (1812), 83, p. 119120Google Scholar; Phil. Mag. (1814), 43, p. 246.Google Scholar

133. Berzelius. ibid., Ann. de chim. (1812), 83, p. 122Google Scholar; Phil. Mag. (1814), 43, p. 247.Google Scholar

134. Berzelius. ibid., Ann. de chim. (1812), 83, p. 125Google Scholar; Phil. Mag. (1814), 43, p. 248.Google Scholar

135. Berzelius, ibid., Ann. de chim. (1812), 83, p. 8Google Scholar; Phil. Mag. (1814), 43, p. 4.Google Scholar

136. Berzelius, : ‘Essay on the Cause of Chemical Proportions, and on Some Circumstances relating to them: together with a Short and Easy Method of Expressing Them’. Ann. Phil. (1813), 2, p. 443454.Google Scholar

137. Holmes, , op. cit. (1), p. 122.Google Scholar

138. Berzelius, ibid., p. 443.

139. Berzelius, ibid., p. 443.

140. Berzelius, ibid., p. 444.

141. Dalton, : ‘Remarks on the Essay of Dr. Berzelius on the Cause of Chemical ProportionsAnn Phil. (1814), 3, p. 174.Google Scholar

142. Berzelius, : Essai sur la Théorie des Proportions Chimiques et sur l'Influence Chimique de l'Électricité Paris. 1819Google Scholar; reprinted. New York and London, 1972. p. 10–11.

143. Berzelius. ibid., p. 10.

144. Holmes, , op. cit. (1) p. 116.Google Scholar

145. Pfaff, C. H.: ‘Expériences et observations relatives au nouveau principe d'action de l'affinité établi par M. Berthollet’. Ann. de chim.. (1811), 77, p. 259287.Google Scholar

146. Berthollet, : ‘Notes’. Ann. de chim. (1811), 77, p. 288296.Google Scholar