The explicit solitary Rossby wave solutions found by Larichev, Reznik and Berestov are shown to be unique for the model equations considered, in the sense that there are no other antisymmetric wave solutions which are not of these forms. This is done by adapting arguments used by Amick and Fraenkel to show the uniqueness of the Hill's vortex solution. It is based on the maximum principle and the domain folding method of Gidas, Ni and Nirenberg, and involves showing that the function ψ/y is radially symmetric, where ψ is the streamfunction of a solitary wave and y the horizontal cartesian coordinate perpendicular to the x-axis, along which the waves move at steady positive speed. This argument is also used to show the uniqueness of the well-known explicit solutions for cylindrical vortices. The result does not apply directly to rider solutions of Flierl et al., which are not antisymmetric, but it does restrict the possible rider solutions that can form because of their association with particular antisymmetric solutions.