Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-19T02:34:21.025Z Has data issue: false hasContentIssue false

Characterization of spectral and geochemical variability within the Ferrar Dolerite of the McMurdo Dry Valleys, Antarctica: weathering, alteration, and magmatic processes

Published online by Cambridge University Press:  09 May 2013

M.R. Salvatore*
Affiliation:
Department of Geological Sciences, Brown University, 324 Brook Street, Box 1846, Providence, RI 02912, USA
J.F. Mustard
Affiliation:
Department of Geological Sciences, Brown University, 324 Brook Street, Box 1846, Providence, RI 02912, USA
J.W. Head III
Affiliation:
Department of Geological Sciences, Brown University, 324 Brook Street, Box 1846, Providence, RI 02912, USA
D.R. Marchant
Affiliation:
Department of Earth Sciences, Boston University, 685 Commonwealth Avenue, Boston, MA 02215, USA
M.B. Wyatt
Affiliation:
Department of Geological Sciences, Brown University, 324 Brook Street, Box 1846, Providence, RI 02912, USA

Abstract

Orbital spectroscopy and laboratory analyses are utilized to identify major geochemical variations throughout the Ferrar Dolerite exposed in the McMurdo Dry Valleys (MDV) of Antarctica. Our laboratory results highlight the range of primary and secondary chemical and spectral variations observed throughout the dolerite, and provide the necessary calibration for detailed orbital investigations. Pure dolerite units are identified and analysed throughout the MDV using Advanced Land Imager (ALI) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) orbital datasets. In conjunction with our laboratory analyses, orbital analyses indicate that the dolerite sills are dominated by MgO concentrations of c. 6–7 wt% except where influenced by orthopyroxene-laden magmatic injections, where MgO concentrations can reach as high as 32.5 wt%. ASTER analyses also indicate that spectrally significant alteration is limited primarily to surfaces dominated by fine-grained dolerites, which form and preserve well developed alteration rinds due to their resistance to physical erosion. The archetype of these secondary signatures is Beacon Valley, where a combination of cold, dry, and stable environmental conditions and the presence of fine-grained dolerites results in strong alteration signatures. This work provides unprecedented spatial coverage of meso- and macro-scale geochemical features that, until now, have only been identified in field and laboratory investigations.

Type
Earth Sciences
Copyright
Copyright © Antarctic Science Ltd 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Adams, J.B. 1974. Visible and near-infrared diffuse reflectance spectra of pyroxenes as applied to remote sensing of solid objects in the solar system. Journal of Geophysical Research, 79, 48294836.CrossRefGoogle Scholar
Adams, J.B. McCord, T.B. 1971. Optical properties of mineral separates, glass, and anorthositic fragments from Apollo mare samples. Proceedings of the Lunar and Planetary Science Conference, 3, 21832195.Google Scholar
Allen, C.C. Conca, J.L. 1991. Weathering of basaltic rocks under cold, arid conditions: Antarctica and Mars. Proceedings of the Lunar and Planetary Science Conference, 21, 711717.Google Scholar
Bédard, J.H.J., Marsh, B.D., Hersum, T.G., Naslund, H.R. Mukasa, S.B. 2007. Large-scale mechanical redistribution of orthopyroxene and plagioclase in the Basement Sill, Ferrar Dolerites, McMurdo Dry Valleys, Antarctica: petrological, mineral-chemical and field evidence for channelized movement of crystals and melt. Journal of Petrology, 48, 22892326.Google Scholar
Chander, G., Markham, B.L. Helder, D.L. 2009. Summary of current radiometric calibration coefficients for Landsat MSS, TM, ETM+, and EO-1 ALI sensors. Remote Sensing of Environment, 113, 893903.CrossRefGoogle Scholar
Chavez, P.S. Jr 1996. Image-based atmospheric corrections - revisited and improved. Photogrammetric Engineering & Remote Sensing, 62, 10251036.Google Scholar
Christensen, P.R., Bandfield, J.L., Hamilton, V.E., Howard, D.A., Lane, M.D., Piatek, J.L., Ruff, S.W. Stefanov, W.L. 2000. A thermal emission spectral library of rock-forming minerals. Journal of Geophysical Research, 105, 97359739.Google Scholar
Cooper, R.F., Fanselow, J.B. Poker, D.B. 1996. The mechanism of oxidation of a basaltic glass: chemical diffusion of network-modifying cations. Geochimica et Cosmochimica Acta, 60, 32533265.Google Scholar
Cord, A.M., Pinet, P.C., Daydou, D. Chevrel, S.D. 2005. Experimental determination of the surface photometric contribution in the spectral reflectance deconvolution processes for a simulated Martian crater-like regolith target. Icarus, 175, 7891.CrossRefGoogle Scholar
Domingue, D. Vilas, F. 2007. Local topographic effects on photometry and reflectance spectra of planetary surfaces: an example based on lunar photometry. Meteoritics & Planetary Science, 42, 18011816.CrossRefGoogle Scholar
Doran, P.T., McKay, C.P., Clow, G.D., Dana, G.L., Fountain, A.G., Nylen, T. Lyons, W.B. 2002. Climate observations from the McMurdo Dry Valleys, Antarctica, 1986–2000. Journal of Geophysical Research, 10.1029/2001JD002045.CrossRefGoogle Scholar
Ehlmann, B.L., Mustard, J.F., Swayze, G.A., Clark, R.N., Bishop, J.L., Poulet, F., Des Marais, D.J., Roach, L.H., Milliken, R.E., Wray, J.J., Barnouin-Jha, O. Murchie, S.L. 2009. Identification of hydrated silicate minerals on Mars using MRO-CRISM: geologic context near Nili Fossae and implications for aqueous alteration. Journal of Geophysical Research, 10.1029/2009JE003339.CrossRefGoogle Scholar
Elliot, D.H. Fleming, T.H. 2004. Occurrences and dispersal of magmas in the Jurassic Ferrar large igneous province, Antarctica. Gondwana Research, 7, 223237.CrossRefGoogle Scholar
ERSDAC (Earth Remote Sensing Data Analysis Center). 2005. ASTER user's guide, Part 1. General, version 4. 103 pp. http://www.science.aster.ersdac.jspacesystems.or.jp/en/documnts/users_guide/part1/pdf/Part1_4E.pdf, accessed 12 June 2012.Google Scholar
Farmer, V.C. 1974. The infrared spectra of minerals. London: Mineralogical Society, 539 pp.Google Scholar
Fitzgerald, P.G., Baldwin, S.L., Webb, L.E. O'Sullivan, P.B. 2006. Interpretation of (U-Th)/He single grain ages from slowly cooled crustal terranes: a case study from the Transantarctic Mountains of southern Victoria Land. Chemical Geology, 255, 91120.Google Scholar
Fleming, T.H., Foland, K.A. Elliot, D.H. 1995. Isotopic and chemical constraints on the crustal evolution and source signature of Ferrar magmas, north Victoria Land, Antarctica. Contributions to Mineralogy & Petrology, 121, 217236.CrossRefGoogle Scholar
Fleming, T.H., Heimann, A., Foland, K.A. Elliot, D.H. 1997. 40Ar/39Ar geochronology of Ferrar Dolerite sills from the Transantarctic Mountains, Antarctica: implications for the age and origin of the Ferrar magmatic province. Geological Society of America Bulletin, 109, 533546.2.3.CO;2>CrossRefGoogle Scholar
Fountain, A.G., Nylen, T.H., Monaghan, A., Basagic, H.J. Bromwich, D. 2009. Snow in the McMurdo Dry Valleys. International Journal of Climatology, 10.1002/joc.1933.Google Scholar
Gillespie, A., Rokugawa, S., Matsunaga, T., Cothern, S., Hook, S. Kahle, A.B. 1998. A temperature and emissivity separation algorithm for Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) images. Institute of Electrical & Electronics Engineers Transactions on Geoscience & Remote Sensing, 36, 11131126.Google Scholar
Glasby, G.P., McPherson, J.G., Kohn, B.P., Johnston, J.H., Freeman, A.G. Tricker, M.J. 1981. Desert varnish in Southern Victoria Land, Antarctica. New Zealand Journal of Geology & Geophysics, 24, 389397.Google Scholar
Hapke, B. 1981. Bidirectional reflectance spectroscopy 1: theory. Journal of Geophysical Research, 86, 30393054.CrossRefGoogle Scholar
Head, J.W., Kreslavsky, M.A. Marchant, D.R. 2011. Pitted rock surfaces on Mars: a mechanism of formation by transient melting of snow and ice. Journal of Geophysical Research, 10.1029/2011JE003826.Google Scholar
Heyn, J., Marsh, B. Wheelock, M. 1995. Crystal size and cooling time in the Peneplain sill, dry valley region, Antarctica. Antarctic Journal of the United States, 30 (5), 5051.Google Scholar
Isaac, M.J., Chinn, T.J., Edbrooke, S.W., Forsyth, P.J. 1995. Geology of the Olympus Range area, southern Victoria Land, Antarctica. 1:50 000. Lower Hutt, New Zealand: New Zealand Institute of Geological and Nuclear Sciences, Geological map 20, 1 sheet + 60 pp.Google Scholar
Klima, R.L., Pieters, C.M. Dyar, M.D. 2008. Characterization of the 1.2 μm M1 pyroxene band: extracting cooling history from near-IR spectra of pyroxenes and pyroxene-dominated rocks. Meteoritics & Planetary Science, 43, 15911604.CrossRefGoogle Scholar
Lasaga, A.C. 1984. Chemical kinetics of water-rock interactions. Journal of Geophysical Research, 89, 40094025.CrossRefGoogle Scholar
Lewis, A.R., Marchant, D.R., Kowalewski, D.E., Baldwin, S.L. Webb, L.E. 2006. The age and origin of the Labyrinth, western Dry Valleys, Antarctica: evidence for extensive middle Miocene subglacial floods and freshwater discharge to the Southern Ocean. Geology, 34, 513516.Google Scholar
Lu, D., Mausel, P., Brondizio, E. Moran, E. 2002. Assessment of atmospheric correction methods for Landsat TM data applicable to Amazon basin LBA research. International Journal of Remote Sensing, 23, 26512671.Google Scholar
Marchant, D.R. Head III, J.W. 2007. Antarctic dry valleys: microclimate zonation, variable geomorphic processes, and implications for assessing climate change on Mars. Icarus, 192, 187222.CrossRefGoogle Scholar
Marchant, D.R., MacKay, S., Lamp, J.L., Hayden, A.T. Head, J.W. In press. A review of geomorphic processes and landforms in the Dry Valleys of southern Victoria Land: implications for evaluating climate change and ice sheet stability. In Hambrey, M.J., Barker, P.F., Barrett, P.J., Bowman, V., Davies, B., Smellie, J.L. & Tranter, M., eds. Antarctic palaeoenvironments and earth-surface processes. Geological Society Special Publication, No. 381. http://dx.doi.org/10.1144/SP381.10.CrossRefGoogle Scholar
Marsh, B. 2004. A magmatic mush column Rosetta Stone: the McMurdo Dry Valleys of Antarctica. Eos Transactions of the American Geophysical Union, 85, 497508.CrossRefGoogle Scholar
Marsh, B.D. Wheelock, M.K. 1994. The vertical variation of composition in the Peneplain and Basement Sills of the McMurdo Dry Valleys: the null hypothesis. Antarctic Journal of the United States, 29 (5), 2425.Google Scholar
Mendenhall, J.A., Bernotas, L.A., Bicknell, W.E., Cerrati, V.J., Digenis, C.J., Evans, J.B., Forman, S.E., Hearn, D.R., Hoffeld, R.H., Lencioni, D.E., Nathanson, D.M. Parker, A.C. 2000. Earth Observing-1 Advanced Land Imager: instrument and flight operations overview. Massachusetts Institute of Technology & Lincoln Laboratory Project Report EO-1-1, 121 pp.Google Scholar
Murray, R.W., Miller, D.J. Kryc, K.A. 2000. Analysis of major and trace elements in rocks, sediments, and interstitial waters by Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES). Texas A&M University, Ocean Drilling Program Technical Note No. 29, 21 pp.Google Scholar
Mustard, J.F. Pieters, C.M. 1989. Photometric phase functions of common geologic minerals and applications to quantitative analysis of mineral mixture reflectance spectra. Journal of Geophysical Research, 94, 1361913634.Google Scholar
Pieters, C.M. 1983. Strength of mineral absorption features in the transmitted component of near-infrared reflected light: first results from RELAB. Journal of Geophysical Research, 88, 95349544.CrossRefGoogle Scholar
Ramsey, M.S. Christensen, P.R. 1998. Mineral abundance determination: quantitative deconvolution of thermal emission spectra. Journal of Geophysical Research, 103, 577596.Google Scholar
Salvatore, M.R., Mustard, J.F., Head, J.W., Cooper, R.F., Marchant, D.R. Wyatt, M.B. In press. Development of alteration rinds by oxidative weathering processes in Beacon Valley, Antarctica, and implications for Mars. Geochimica et Cosmochimica Acta, http://dx.doi.org/10.1016/j.gca.2013.04.002.Google Scholar
Schenk, T., Csatho, B., Ahn, Y., Yoon, T., Shin, S.W. Huh, K.I. 2004. DEM generation from the Antarctic LIDAR data: site report. http://usarc.usgs.gov/lidar/lidar_pdfs/Site_reports_v5.pdf, 49 pp.Google Scholar
Schwerdtfeger, W. 1984. Weather and climate of the Antarctic. Amsterdam: Elsevier, 327 pp.Google Scholar
Sugden, D.E., Denton, G.H. Marchant, D.R. 1995. Landscape evolution of the Dry Valleys, Transantarctic Mountains: tectonic implications. Journal of Geophysical Research, 100, 99499967.Google Scholar
Zavala, K., Leitch, A.M. Fisher, G.W. 2011. Silicic segregations of the Ferrar Dolerite sills, Antarctica. Journal of Petrology, 52, 19271964.Google Scholar