Raman spectra (532 nm diode laser) of gypsum, syngenite and görgeyite powders were studied from 273 to 83 K every −10 K. Although it was found that not all the Raman peaks are temperature-sensitive, the effect of temperature on the Raman signal of some bands was modelled. It was observed that the main bands of the three sulfates shift toward higher wavenumbers as temperature decreases. The strengthening of the bonds causes an increase in energy and, consequently, higher wavenumbers. However, –OH bands shift depending on the crystal structure they acquire as the temperature decreases, so not all –OH bands behave in the same way. Finally, the gypsum –OH bands change to more ordered crystalline structures with decreasing temperature, so their bandwidths become narrower and sharper.

Deciphering the localisation of solid and dissolved impurities on the micron-scale in glacial ice remains a challenge, but is critical to understand the integrity of ice core records and internal deformation. Here we report on the state-of-the-art in microstructural impurity research by highlighting recent progress in bringing together cryo-Raman spectroscopy and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). We show the potential of both methods and discuss possibilities to improve inter-method approaches aiming for a more holistic understanding of the evolution of impurity localisation throughout the ice column, including post-depositional processes. In this framework, we elaborate on future research priorities such as LA-ICP-MS imaging on firn samples and integrating a large cryo-cell with imaging capabilities.

Cryospheric change occurs in unequal spaces. Societies living near ice are divided by race, class, gender, geography, politics and other factors. Consequently, impacts of ice loss are not shared equally, and everyone experiences cryospheric changes differently. Responsibility for recent ice loss is also driven by a relatively small portion of humanity: those who emit the most greenhouse gases. Additionally, people who study the cryosphere come from institutions and societies where inequality is often systemic, making research on ice and snow a symptom of and contributor to social inequality. To better understand unequal effects of cryospheric change within and across diverse communities, including research communities, this paper focuses on three areas, drawing primarily from glacier-related work: (1) the social context of cryospheric changes; (2) attribution and responsibility for cryospheric changes and (3) imbalances in knowledge about the cryosphere. Addressing these dimensions of ice loss requires transdisciplinary approaches that connect research to societies and link glaciology and other cryospheric sciences with social sciences and humanities. These concepts, cases and suggestions to help address inequalities also reveal that no singular conceptualization of sustainability exists. Different societies, residents and researchers possess distinct understandings of and goals for ‘ice in a sustainable society’.

Snow ice (SI) forms from freezing wet snow, known as slush, and contributes to the thickness of level and brash ice. However, the mechanism of snow-slush-snow ice transformation has not been extensively investigated to date, despite the difference in the freezing rate of slush in comparison with water is important for estimating the ice thickness. In this study, we examined the growth of initial congelation ice (CI) and snow ice (SI) in a fresh water tank exposed to outdoor weather conditions in Luleå, northern Sweden. The tank of size 1.8 × 0.65 × 1.2 m in length, width and height was divided into two compartments to facilitate the simultaneous growth of CI and SI. A total of 12 experiments were conducted in the years 2021 and 2022. The transformation from slush to snow ice was achieved by submerging various amounts of snow in the compartments. It was observed that approximately 35% of the initial snow transformed into SI. Snow ice grew 4 mm°C−0.5 d−0.5 faster than congelation ice. The CI growth under SI was 1 mm°C−0.5 d−0.5 slower than the CI growth under CI. This study provides valuable insights for modelling snow-slush-snow ice transformation and designing future laboratory-scale experiments.

Upper Palaeolithic archaeological sites in the Basque Country have been excavated for over a century. They have yielded a rich palaeoenvironmental record with zoological and botanical remains that have been obtained in stratigraphic series dated precisely by radiocarbon. This information reveals cyclical environmental changes from climates similar to today to drier and extremely cold conditions, when species in current boreal biomes and others now extinct but with similar ecological preferences were present in the region. Moreover, the archaeological sites have provided high-resolution information about the resilience mechanisms of the communities of our own human species. This information allows us to increase the corpus of palaeoclimate data regarding the Marine Isotopic Stage (MIS) 2 and MIS 3 for a critical region within the human population of Eurasia. The aim of this paper is to show how an extraordinary capacity for adaptation to drastic climate changes Upper Palaeolithic hunter–gatherer societies displayed, even though their subsistence depended on biotic resources that alter rapidly.

Monte Perdido Glacier, located in the central Pyrenees, is one of the southernmost glaciers in Europe. Due to climate change, this glacier is suffering an accelerated mass loss, especially in the last decades. If the current trends persist, this glacier is expected to disappear in the next 50 years. As part of the efforts of the scientific community to increase the knowledge about this glacier, this research presents the first microstructural characterization of the Monte Perdido Glacier, focused on a high-impurity concentration segment that belongs to an ice core drilled in 2017. The results reveal the ice has a layering defined by air bubbles and non-soluble impurities. The bubble-defined layering exhibits features of both a primary (sedimentary) and a secondary (strain-induced) origin. We found a clear inverse correspondence between the particle concentration and the grains' size and roundness index. A preliminary micro-Raman characterization of the particles shows the occurrence of atacamite, anatase (likely related to ancient mining activities in the vicinity of the glacier) and quartz. The latter could be an indicator of mineral dust, probably suggesting the arrival of dust-laden air masses from the north of the African continent.

The Antarctic Peninsula Ice Sheet (APIS) has become a significant contributor to sea-level rise over recent decades. Accurately estimating the ice discharge from the outlet glaciers of the APIS is crucial to quantify the mass balance of the Antarctic Peninsula. We here compute the ice discharge from the outlet glaciers of the APIS north of 70${^\circ }$S for the five most widely used ice-thickness reconstructions, using a common surface velocity field and a common set of flux gates, so the differences in ice discharge can be solely attributed to the differences in ice thickness at the flux gates. The total volumetric ice discharge for 2015–2017 ranges within 45–141 km3 a−1, depending on the ice-thickness model, with a mean of 87 ± 44 km3 a−1. The substantial differences between the ice-discharge results, and a multi-model normalized root-mean-squared deviation of 0.91 for the whole data set, reveal large differences and inconsistencies between the ice-thickness models, giving an indication of the large uncertainty in the current ice-discharge estimates for the APIS. This manifests a fundamental problem of the region: the scarcity of appropriate ice-thickness measurements and the difficulty of the current models to reconstruct the ice-thickness distribution in this complex region.

Perennial ice can be studied for many purposes, including paleoclimate records or rheological properties. For most of those purposes, the ice microstructure must be studied, often through optical microscopy. The aim of this work is to assess the viability of immersion microscopy for the study of ice microstructures. It consists of using an oil between the objective lens and the specimen, to increase image resolution. Immersion microscopy is a technique well-developed for the investigation of diverse materials, but it has so far not been explored for ice research. Here we investigate the challenges and advantages of that technique. The main challenge is related to the selection of the immersion oil itself, which must satisfy a number of criteria, ranging from refractive index and viscosity to toxicity and reactivity. We identify pure silicone oil (dimethicone) as a simple and safe option for immersion microscopy of inner ice structures. Among its advantages, it provides higher resolution (compared to standard ‘dry’ microscopy) and it can be simultaneously used as a long-term coating to prevent undesired sublimation of the ice-sample surfaces. For the observation of surface structures, however, another type of oil with higher refractive index should be used.

The analysis of Martian meteorites is a key research to understand the mineralogical composition of Mars. However, they suffer different types of alteration due to the environment where they fall on Earth. These differences should be identified in order to characterize correctly the original Martian compounds. Most of the meteorites found on Earth are collected in Antarctica where the environmental conditions are such that, in general and based on many previous investigations, produce fewer alterations compared with other terrestrial environments such as hot deserts. In this study, the weathering alterations of minerals from the MIL 090030 Martian Nakhlite found in Antarctica were analyzed to determine which minerals are formed by Antarctic environmental conditions. It was confirmed that the south-polar region environment can contaminate Martian meteorites and, in this study, several minerals like halite, nitratine and niter, were detected as weathering alteration products that have not been referenced in the literature before.