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X-Ray Studies of Basic Lead Azides

Published online by Cambridge University Press:  06 March 2019

M. Stammler  and
J. E. Abel
M. Stammler
Affiliation:
Picatinny Arsenal, Dover, New Jersey
J. E. Abel
Affiliation:
Picatinny Arsenal, Dover, New Jersey
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Abstract

Basic lead azides are obtained by the slow thermal decomposition of PbN6 at temperatures up to 200°C in oxygen, argon, and air containing varying amounts of moisture. The decomposition diagrams show several stages due to the formation of different phases, two of which have been separated. One phase can be identified as a tetragonal deformed cubic lattice. Further slow decompositions of the basic lead azide at 250°C lead to tetragonal lead oxide. The structure of the other isolated phase Is of lower symmetry and has not yet been classified. The results of this investigation are also compared with the work of previous investigators.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 4: Ninth Annual Conference on Applications of X-ray Analysis, August 10-12, 1960 , 1960 , pp. 130 - 139
Copyright
Copyright © International Centre for Diffraction Data 1960

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References

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