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A Theoretical Derivation of the Composition of Mixable Specimens from Fluorescent X-Ray Intensities

Published online by Cambridge University Press:  06 March 2019

Jacob Sherman
Jacob Sherman*
Affiliation:
Philadelphia Naval Shipyard, Philadelphia, Pennsylvania
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Abstract

A rigorous solution is developed for the correlation of the composition of mixable specimens and the fluorescent X-radiation emitted by the elements in the specimen. The instrumental modifications and treatment of the specimens are derived from the fundamental fluorescence equation.

The resultant dilution formula contains measurable quantities only. No calibration curve is required.

The theory is illustrated by some experimental data confirming the equations.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 1: Sixth Annual Conference on Industrial Applications of X-ray Analysis, August 7-9, 1957 , 1957 , pp. 231 - 252
Copyright
Copyright © International Centre for Diffraction Data 1957

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References

1.ITL Research and Development Report 6001-1 (NS-013-007) “Correlation of Fluorescent X-ray Intensities and Chemical Composition” by Jacob Sherman, February 1955; or ”The Theoretical Derivation of Fluorescent X-ray Intensities from Mixtures”, J. Sherman; Spectrochimica Acta (7), 1955.Google Scholar