Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-27T05:45:16.808Z Has data issue: false hasContentIssue false
  • English
  • Français

Preliminary Studies on the Characterization of Solution-Grown ADP Crystals

Published online by Cambridge University Press:  06 March 2019

Richard D. Deslattes ,
John L. Torgesen ,
Boris Paretzkin  and
Avery T. Horton
Richard D. Deslattes
Affiliation:
National Bureau of Standards Washington, D.C.
John L. Torgesen
Affiliation:
National Bureau of Standards Washington, D.C.
Boris Paretzkin
Affiliation:
National Bureau of Standards Washington, D.C.
Avery T. Horton
Affiliation:
National Bureau of Standards Washington, D.C.
Get access

Abstract

Large single crystals of ammonium dihydrogen phosphate (ADP) have been grown from solutions of reagent grade materials by means of precisely controlled temperature programs. We have studied the perfection of these crystals by means of double-crystal rocking curves and diffraction topographs. In the course of this study, effects associated with various techniques of sectioning and polishing specimens from these crystals were examined. A combination of string sawing and chemical polishing procedures produced specimens exhibiting the best diffraction characteristics. Results obtained from surfaces so prepared are tentatively taken as being characteristic of the bulk crystal and may be interpreted in terms of longrange strain fields and imaging of both emergent and nonemergent dislocations. In some specimens, regions of 1 cm2 or more have been found to be free of defect images and to have uniform reflectance.

The perfection of some specimen pairs and the intrinsic properties of certain reflections suggest their possible application to spectroscopic problems. Some crystal pairs cut parallel to (101) planes have exhibited physical resolving powers of 104 at 8.3 Å; others cut for the 600 reflection have given 4 x 105 at 1,5 Å, These crystals deteriorate on exposure to moist laboratory air and preservation techniques had to be employed.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 8: Thirteenth Annual Conference on Applications of X-ray Analysis, August 12-14, 1964 , 1964 , pp. 315 - 324
Copyright
Copyright © International Centre for Diffraction Data 1964

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Robinson, A. E., “The Growth of Large Crystals of Ammonium Dihydrogen. Phosphate and Lithium Sulfate,” Discussions Faraday Soc. 1949(5):315-319; A. C. Walker, “Growing Piezoelectric Crystals,” J. Franklin Inst. 250(6) :481-524, 1950; A. C. Walker and G. T. Kbhman, “Growing Crystals of Ethylene Diamine Tartrate,” Trans, Am. Inst, Elec. Engr. 67:565-570, 1948; P. H. Egli and L. R. Johnson, in: The Art and Science of Growing Crystals, J. J. Gilman (ed.), John Wiley & Sons, New York, 1963, p. 194.Google Scholar
2. Newkirk, J. B., “Growth of Cadmium Iodide Crystals,” Acta Met. 3:121–125, 1955.Google Scholar
3. Torgesen, J. L., Horton, A. T., and Saylor, C. P., “Equipment for S ingle-Crystal Growth from Aqueous Solution,” J. Res. Natl. Bur. Std. C67:25–32, 1963.Google Scholar
4. Tipson, R. S., in: Techniques of Organic Chemistry, Vol. III, Part I, Interscience Publishers, Inc., New York, 1956, p. 485.Google Scholar
5. Young, F. W. and Wilson, T. R., “Acid Cutting and Acid Polishing of Copper Crystals,” Rev. Sci. Instr. 32:559–562, 1961.Google Scholar
6. Dyer, L. D., “Design and Use of an Acid Polishing Machine,” Rev. Sci. Instr. 34:1114–1116, 1963.Google Scholar
7. Bonse, U., “Determination of the Type of Individual Dislocations in1 Single Crystals by X-Rays,” Z. Physik 153:278–296, 1958.Google Scholar
8. Kardonskii, V. M., “The X-Ray Topography of Crystals,” Kristalbgrafiya 7:313-315, 1962; Soviet Phys.-Cryst. (English transi.) 7: 244, 1962.Google Scholar
9. Renninger, M., Z. Naturforsch. 16a:1110, 1361; K. Kohra, M, Yoshimatsu, and I. Shumzu, in: Direct Observation of Imperfections in Crystals, J. B. Newkirk and J. H. Wernick (eds.), Interscience Publishers, Inc., New York, 1962, p. 461.Google Scholar
10. Compton, A. H. and Allison, S. K., X-Rays in Theory and Experiment, second edition, D. Van Nostrand Co., Inc., New York, 1954, p. 717.Google Scholar
11. Webb, W. W., in: Direct Observation of Imperfections in Crystals, J. B. Newkirk and J. H. Wernick (eds.), Interscienoe Publishers, Inc., New York, 1962, pp. 67–72.Google Scholar
12. Ross, P. A., “A Double Crystal X-Ray Spectrometer and Spectrograph,” Phys, Rev. 39: 550, 1932.Google Scholar
13. Kokosaka, G., private communication.Google Scholar
14. Jackson, R. W., unpublished results.Google Scholar