Hostname: page-component-7bb8b95d7b-fmk2r Total loading time: 0 Render date: 2024-10-02T17:43:15.125Z Has data issue: false hasContentIssue false

A Fusion Method for the X-Ray Fluorescence Analysis of Portland Cements, Clinker and Raw Materials Utilizing Cerium (IV) Oxide in Lithium Borate Fluxes

Published online by Cambridge University Press:  06 March 2019

Gregory S. Barger*
Affiliation:
Central Process Laboratory Southwestern Portland Cement Ccmpany P. O. Sox 937 Victorville, California 92 392 U.S.A.
Get access

Abstract

This method describes the addition of cerium (IV) oxide to a lithium borate flux. CeO2 provides a non-analytic glass former to the melt production. CeO2 also acts as an interelemental buffer replacing the use of lanthanum oxide for long wavelength absorption. With cerium oxide addition, excellent results are produced, resulting in part from the elimination of recrystallization problems encountered with lanthanum oxide use. Analytical results easily meet the ASTM C-114 qualification requirements for rapid method analysis of hydraulic cements.

Type
Research Article
Copyright
Copyright © International Centre for Diffraction Data 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Moore, C.W., “Spectrochemical Analysis of Portland Cement by Fusion with Lithium Tetraborate using an X-ray Spectrometer” (E-2 SM. 0-26), pp. 911-17, Methods for Emission Spectrochemical Analysis, Seventh Edition, ASTM. Philadelphia, 1982.Google Scholar
2. Anderman, S., “Spectrochemical Analysis of Cement by Lithium Tetraborate-Lanthanum Oxide Fusion Technique Using an X-ray Spectrometer”, (E-2 SM. 0-20), pp. 885-92, Methods for Emission Spectrochemical Analysis. Seventh Edition, ASTM. Philadelphia, 1982.Google Scholar
3. Claisse, F., Instruction Manual for Claisse Fluxer VI. 1979, Corporation Sdentifique Cl ai'sse, Tnc., Quebec, Canada.Google Scholar
4. X-Ray Spectrochemical Accessories. “X-Ray Fusion Fluxes” Section, 1981 Catalog, Chemplex Industries” Inc., Eastchester, N. Y.Google Scholar
5. Sudoh, G.; Asahara, N.; Kitsuda, K.; and Nakayama, T., “Automatic Bead Preparation Techniques for X-ray Fluorescence Analysis”, Seroento Gijutsu Nempo. pp. 28, 80-83, Canent Association of Japan, Tokyo, 1974.Google Scholar
6. Anzelmo, J.A., “X-ray Emission Spectro-Chemical Analysis of Aluminosilicate Raw Materials and Refractories by Lithium Tetraborate-Lanthanum Oxide Fusion Technique” (E-2 SM. 0-33), pp. 358-61, Methods for Emission Spectrochemical Analysis. Seventh Edition, ASTM. Philadelphia, 1982.Google Scholar