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The Determination of Rare Earth Elements in Geological Samples by XRF Using the Proportional Factor Method

Published online by Cambridge University Press:  06 March 2019

Chen Yuanpan*
Affiliation:
Research Institute of Geology for Mineral Resources, China National Nonferrous Metals Industry Corporation, Sanlidian Guilin, China
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Abstract

This paper describes the principle, method and application of the proportional factor method for the determination of rare earth elements (REE) in geological samples by XRF, The analytical results of this method are compared with REE recommended values in geological standards, and good agreement was observed. Five of the REE (Pr, Tb, Ho, Tm and Lu) have also been determined by interpolation from chondrite-normalized plots, and more satisfactory results were obtained.

Type
III. XRF Mathematical Models and Quantitation
Copyright
Copyright © International Centre for Diffraction Data 1988

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References

(1) Kogarko, L.N., et al. , Geokhimia 5 639651 (1984)Google Scholar
(2) Zhao Zhenhua, et al. , Geochimica 1 26-35 (1981)Google Scholar
(3) Qizhong, Wen, Suhua, Yu, Xiongfei, Gu and Jianquan, Lei, Geochimica 2 151161 (1981)Google Scholar
(4) Turanskaya, N.V., Method for determination and analysis of rare elements Moscow 143144 (1961)Google Scholar
(5) Vainstein, E.E., Methods for Quantitative X-Ray Spectroscopic Analysis Moscow 176177 (1956)Google Scholar
(6) Bellary, V.P., Deshpande, S.S., Dixitand, R.M. and sankaran, A.V., F.Z. Anal. Chem. 309 380382 (1981)Google Scholar
(7) Roellandts, I., Anal. Chem. 54(4) 676680 (1981)Google Scholar
(8) Sial, A.N., H, M.C.. Figueiredo and Long, L.E., Chem. Gool. 31(3) 271283 (1981)Google Scholar
(9) Mitrapoulos, P., Chem. Geol. 35(3/4) 265280 (1982)Google Scholar
(10) Lianyuan, Feng, et al. , Geoehimica 1 35-46 (1982)Google Scholar
(11) Qingxiang, An, Acta Ptrologica Minerallogica et Analytica 3(2) 162-165 (1984)Google Scholar
(12) Yuanpan, Chen, Analytical Chemistry (in China) 1 61-64 (1981)Google Scholar
(13) Pinhui, Sun and Yuanpan, Chen, Spectroscopy and Spectral Analysis 5(4) 4752 (1985)Google Scholar
(14) Nakamura, N., Geochim. Cosmochim. Acta 38(5) 757775 (1974)Google Scholar
(15) Potts, P.J., Thorpe, O.W. and Watson, J.S., Chem. Geol. 34(3/4) 331352 (1981)Google Scholar
(16) Gladney, E.S. and Burns, C.E., Geostandards Newsletter 7 (1) 11-12 (1983)Google Scholar
(17) Xie, Xuejing, Van, Mingcai, Lianzhong Li and Huijun Shen, Geostandards Newsletter Vol. IX No. l 83159 (1985)Google Scholar