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The Analysis of the Light Elements in Ferrotitanium Ores and Residues of Widely Varying Composition by X-Ray Spectrography

Published online by Cambridge University Press:  06 March 2019

Benjamin S. Sanderson  and
James A. Yeck
Benjamin S. Sanderson
Affiliation:
National Lead Company South Amboy, New Jersey
James A. Yeck
Affiliation:
National Lead Company South Amboy, New Jersey
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Abstract

Ferrotitanium ores and residues may vary widely in composition. Because of this, interelemerxt effects are very large. An X-ray spectrographic method will be described for the analysis of the light elements in these ores and residues. The method uses a standard helium path Norelco spectrograph with a tungsten target tube. A KAP analyzing crystal is used for all the elements investigated. Appropriate emission lines of the elements magnesium, aluminum, silicon, calcium, titanium, and iron are measured and the results are calculated on a small computer using the empirical corrections for interelernent effects of Lucas-Tooth and Pyne. The FORTRAN program for these calculations will be given.

The problems of sample preparation, standardization, interferences and instrumental variables will be discussed. A comparison of X-ray results with chemical analysis is made.

The method is especially adaptable to automated analysis and some of the systems needed will be outlined. The method may also be modified to analyze light elements in other matrices.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 10: Fifteenth Annual Conference on Applications of X-ray Analysis, August 10-12, 1966 , 1966 , pp. 474 - 488
Copyright
Copyright © International Centre for Diffraction Data 1966

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References

1. Dunne, J. A., “Components for X-Ray Fluorescence Spectroscopy in the 5-65 Å Wavelength Region,” Norelco Reporter 11: 109–112, 1964.Google Scholar
2. Gunn, E. L., “Fluorescent X-Ray Spectral Analysis of Powdered Solids by Matrix Dilution,” Anal. Chem. 29: 184–189, 1957.Google Scholar
3. Lewis, G. J. Jr. and Goldberg, E. D., “X-Ray Fluorescence Determination of Barium, Titanium and Zinc in Sediments,” Anal. Chem. 28: 1282–1285, 1956.Google Scholar
4. Claisse, F., “Sample Preparation Techniques for X-Ray Fluorescence Analysis,” Quebec Dept. Mines Prelim. Report No. 402, 1960.Google Scholar
5. Lucus-Tooth, J. and Pyne, L., “The Accurate Determination of Major Constituents by X-Ray Fluorescence Analysis in the Presence of Large Interelement Effects,” Advances in X-Ray Analysis, Vol. 7, Plenum Press, New York, 1964, pp. 526-54.Google Scholar
6. Houseknecht, T. M. and Patterson, W., “Sample Preparation for X-Ray Analysis,” Speetrographers News Letter 17: 2, 1964.Google Scholar