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An X-Ray Amorphous Scattering Investigation of the Corrosion of a Potassium Silicate Glass K2O-3Si02

Published online by Cambridge University Press:  06 March 2019

R. W. Gould  and
M. S. Hill
R. W. Gould
Affiliation:
University of Florida, Gainesville, Florida 32611
M. S. Hill
Affiliation:
University of Florida, Gainesville, Florida 32611
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Abstract

Structural modifications occurring in corroded potassium silicate glasses were studied using x-ray amorphous scattering techniques. Pair function distribution curves are compared and the differential method is used to follow the structural changes. The structure appears to approach that of vitreous silica after long leaching times.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 17: Twenty-Second Annual Conference on Applications of X-ray Analysis, August 22-24, 1973 , 1973 , pp. 384 - 394
Copyright
Copyright © International Centre for Diffraction Data 1973

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References

1. Zernike, F and Prins, J. A., “Die Beugung von Röntgenstrahlen in Flüssigkeiten als Effekt der Molenkülanordnung,” in Zeitschrift für Physik, 41, 184 (1927).Google Scholar
2. Debye, P and Menke, H., “Bestimmung der inneren Struktur von Flüssigkeiten mit Röntgenstrahlen,” in Physikalische Zeitshrift, 31, 797 (1930).Google Scholar
3. Warren, B. E., Krutter, H and Morningstar, O., “Fourier Analysis of X-ray Patterns of Vitreous SiO2 and B2O3,” in Journal of American Ceramic Society, 19, 202 (1936).Google Scholar
4. Mozzi, R. L. and Warren, B. E., “The Structure of Vitreous Silica,” in Journal of Applied Crystallography, 2, 164 (1969).Google Scholar
5. Valenkov, N and Forai-Koshits, E., “X-ray Investigation of the Glassy State,” in Zeitschrift für Kristallographie, 95, 195 (1936).Google Scholar
6. Hartleif, G., “Beiträge zur Struktur des Kieselglases und der Kalisilikatgläser,” in Zeitschrift für Anorganische Chemie, 233, 353 (1938).Google Scholar
7. Warren, B. E., “Exact Method for an Amorphous Sample With More Than One Kind of Atom,” in X-ray Diffraction, p 135–42, Addison-Wesley Publishing Co., Reading, Mass. (1969).Google Scholar
8. Warren, B. E., “Amorphous Scattering,” Lectures at the University of Florida (Spring 1969).Google Scholar
9. Hill, M. S., “An X-ray Investigation of Interatomic Distances in Potassium Silicate Glasses,” M.S. Thesis, University of Florida (1972).Google Scholar
10. Mash, D. B., “New Technique for Quantitative SiO2 Determinations of Silicate Materials by X-ray Diffraction Analysis of Glass,” in Advances in X-ray Analysis, 7, 209 (1964).Google Scholar
11. Gokularathnam, C. V., “X-ray Diffraction Analysis of Structural Changes in Vitreous Silica,” Ph.D. Dissertation University of Florida (1971).Google Scholar
12. Kaplow, R., S, Strong, L and Averbach, B. L., “Radial Density Functions for Liquid Mercury and Lead,” in Physical Review, 138, A1336 (May 31, 1965).Google Scholar