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Particle Size Effects in Geological Analyses by X-Ray Fluorescence

Published online by Cambridge University Press:  06 March 2019

K.K. Nielson
Affiliation:
Rogers and Associates Engineering Corporation Sait Lake City, Utah 84110
V.C. Rogers
Affiliation:
Rogers and Associates Engineering Corporation Sait Lake City, Utah 84110
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Abstract

Particle-size effects can cause significant errors in x-ray fluorescence (XRF) analysis of particulate materials. The effects are usually removed when samples are fused or dissolved to standardize the matrix for quantitative analysis. Recent improvements in numerical matrix corrections reduce the need to standardize the sample matrix via fusion or dissolution, particularly when the CEMAS method is used to estimate unmeasured light-element components of undefined materials for matrix calculations. A new method to correct for particle-size effects has therefore been examined to potentially avoid the need for destructive preparation of homogeneous samples.

Type
Research Article
Copyright
Copyright © International Centre for Diffraction Data 1985

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References

1. Nielson, K.K. and Rogers, V.C., “Comparison of X-Ray Backscatter Parameters for Complete Sample Matrix Definition”, Advances in X. ray Analysis. 449457, 1984.Google Scholar
2. Kielson, K.K. and Rogers, V.C., “Accurate X-Ray Fluorescence Analysis of Environmental Materials without Standards”, Trans, Am. Nucl. Soc., 49, 146147, 1985.Google Scholar
3. Berry, P.F., Furuta, T. and Rhodes, J.R., “ Particle Size Effects in Radio - Isotope X- ray Spectrometry”, Advances in X. ray Analysis, 12, 612632, 1969.Google Scholar
4. Nielson, K.K., “Matrix Corrections for X-Ray Fluore scence Analysis of Environmental Samples with Coherent/ Incoherent Scattered X- rays”, Analytical Chemistry, 49, 641648, 1977.Google Scholar
5. Li, J.C.R., StatisticalInference, Ann Arbor; EdwardsBros., 1964.Google Scholar