Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-27T11:21:52.559Z Has data issue: false hasContentIssue false
  • English
  • Français

The Geometrical Representation of Ternary Alloys and its Applications to X-Ray Fluorescence and Microprobe Analysis

Published online by Cambridge University Press:  06 March 2019

A. Taylor ,
Brenda J. Kagle  and
E. W. Beiter
A. Taylor
Affiliation:
Westinghouse Research Laboratories, Pittsburgh, Pennsylvania
Brenda J. Kagle
Affiliation:
Westinghouse Research Laboratories, Pittsburgh, Pennsylvania
E. W. Beiter
Affiliation:
Westinghouse Research Laboratories, Pittsburgh, Pennsylvania
Get access

Abstract

A simple and accurate graphical method is described for converting the composition of ternary alloys from weight per cent to atomic per cent, and vice versa. By making certain simplifying assumptions, the principles of the method are extended to the approximate determination of ternary alloy compositions from the count fractions obtained from fluorescence X-ray spectra. An example is given for the not-so-favorable system bismuth-germanium-tellurium. On account of the simpler excitation conditions, the same procedures may also be applied to X-ray microprobe analysis.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 5: Tenth Annual Conference on Applications of X-ray Analysis, August 7-9, 1961 , 1961 , pp. 355 - 369
Copyright
Copyright © International Centre for Diffraction Data 1961

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Noakes, G. E., “Symposium on Fluorescent X -Ray Specorographic Analysis,” Am. Soc. Testing Materials, Special Tech. Pub., Vol. 157, 1954.Google Scholar
2. Hamos, L.v., Arkiv fur Matematik, Astronomie och Fysik, Vol. 31A, 1945, p. 1.Google Scholar
3. Koh, P. K. and Caugherty, E., J. Appl. Phys., Vol. 23, 1952, p. 427.Google Scholar
4. Beatty, H. J. and Brissie, R. M., Anal. Chem., Vol. 26, 1954, p. 980.Google Scholar
5. Tiller, W. H., Unpublished work. We are indebted to Dr. Tiller for the samples.Google Scholar
6. Gibbs, Willard J., Collected Works, Vol. I, Longmans, Green and Co., New York, 1928.Google Scholar
7. Stokes, C. G., Proc. Roy. Soc. (London), Vol. 49A, 1891, p. 174.Google Scholar
8. Roozeboom, H. W., Z. Physik. Chem., Vol. 15, 1894, p. 147.Google Scholar
9. Darken, L. S. and Gurry, R. W., Physical Chemistry of Metals, McGraw-Hill Book Company Inc., 1953, p. 236.Google Scholar
10. Taylor, A., Kagle, B. J., and Beiter, E. W., Anal. Chem. (in press).Google Scholar
11. Korzhinskii, S., Physlco-Chemical Basis of the Paragenesis of Minerals (Translation from the Russian), Consultants Bureau, New York, 1959.Google Scholar