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The Effect of Chemical Combination on Some Soft X-Ray K and L Emission Spectra*

Published online by Cambridge University Press:  06 March 2019

David W. Fischer  and
William L. Baun
David W. Fischer
Affiliation:
Air Force Materials Laboratory, Wright-Patterson Air Force Base, Ohio
William L. Baun
Affiliation:
Air Force Materials Laboratory, Wright-Patterson Air Force Base, Ohio
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Abstract

X-ray spectrochemical analysis is a versatile technique that can be used to determine considerably more than just the elemental composition of a sample. X-ray lines and bands are, in many cases, influenced by the state of chemical combination of the element whose spectrum is being investigated. Significant effects due to changes in bonding are seen in the K and L spectra of the low atomic number elements which fall in the 20 to 90 Å region. Results using primary excitation, a stearate crystal, and a flow proportional counter are shown for the K spectra of boron, carbon, and nitrogen. Chlorine and sulfur L spectra from some simple metal compounds of these elements are also shown.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 9: Fourteenth Annual Conference on Applications of X-ray Analysis, August 25-27, 1965 , 1965 , pp. 329 - 343
Copyright
Copyright © International Centre for Diffraction Data 1965

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Footnotes

*

All rights reserved by the U.S. Air Force Materials Laboratory.

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