We introduce a family of stationary random measures in the Euclidean space generated by so-called germ-grain models. The germ-grain model is defined as the union of i.i.d. compact random sets (grains) shifted by points (germs) of a point process. This model gives rise to random measures defined by the sum of contributions of non-overlapping parts of the individual grains. The corresponding moment measures are calculated and an ergodic theorem is presented. The main result is the central limit theorem for the introduced random measures, which is valid for rather general independently marked germ-grain models, including those with non-Poisson distribution of germs and non-convex grains. The technique is based on a central limit theorem for β-mixing random fields. It is shown that this construction of random measures includes those random measures obtained by the so-called positive extensions of intrinsic volumes. In the Poisson case it is possible to prove a central limit theorem under weaker assumptions by using approximations by m-dependent random fields. Applications to statistics of the Boolean model are also discussed. They include a standard way to derive limit theorems for estimators of the model parameters.