Every network has a corresponding matrix representation. This is powerful. We can leverage tools from linear algebra within network science, and doing so brings great insights. The branch of graph theory concerned with such connections is called spectral graph theory. This chapter will introduce some of its central principles as we explore tools and techniques that use matrices and spectral analysis to work with network data. Many matrices appear in different cases when studying networks, including the modularity matrix, nonbacktracking matrix, and the precision matrix. But one matrix stands out—the graph Laplacian. Not only does it capture dynamical processes unfolding over a networks structure, its spectral properties have deep connections to that structure. We show many relationships between the Laplacians eigendecomposition and network problems, such as graph bisection and optimal partitioning tasks. Combining the dynamical information and the connections with partitioning also motivates spectral clustering, a powerful and successful way to find groups of data in general. This kind of technique is now at the heart of machine learning, which well explore soon.