Book contents
- Frontmatter
- Contents
- Preface
- Chapter 1 The wave function
- Chapter 2 Schrödinger wave mechanics
- Chapter 3 General principles of quantum theory
- Chapter 4 Harmonic oscillator
- Chapter 5 Angular momentum
- Chapter 6 The hydrogen atom
- Chapter 7 Spin
- Chapter 8 Systems of identical particles
- Chapter 9 Approximation methods
- Chapter 10 Molecular structure
- Appendix A Mathematical formulas
- Appendix B Fourier series and Fourier integral
- Appendix C Dirac delta function
- Appendix D Hermite polynomials
- Appendix E Legendre and associated Legendre polynomials
- Appendix F Laguerre and associated Laguerre polynomials
- Appendix G Series solutions of differential equations
- Appendix H Recurrence relation for hydrogen-atom expectation values
- Appendix I Matrices
- Appendix J Evaluation of the two-electron interaction integral
- Selected bibliography
- Index
- Physical constants
Chapter 1 - The wave function
Published online by Cambridge University Press: 05 June 2012
- Frontmatter
- Contents
- Preface
- Chapter 1 The wave function
- Chapter 2 Schrödinger wave mechanics
- Chapter 3 General principles of quantum theory
- Chapter 4 Harmonic oscillator
- Chapter 5 Angular momentum
- Chapter 6 The hydrogen atom
- Chapter 7 Spin
- Chapter 8 Systems of identical particles
- Chapter 9 Approximation methods
- Chapter 10 Molecular structure
- Appendix A Mathematical formulas
- Appendix B Fourier series and Fourier integral
- Appendix C Dirac delta function
- Appendix D Hermite polynomials
- Appendix E Legendre and associated Legendre polynomials
- Appendix F Laguerre and associated Laguerre polynomials
- Appendix G Series solutions of differential equations
- Appendix H Recurrence relation for hydrogen-atom expectation values
- Appendix I Matrices
- Appendix J Evaluation of the two-electron interaction integral
- Selected bibliography
- Index
- Physical constants
Summary
Quantum mechanics is a theory to explain and predict the behavior of particles such as electrons, protons, neutrons, atomic nuclei, atoms, and molecules, as well as the photon–the particle associated with electromagnetic radiation or light. From quantum theory we obtain the laws of chemistry as well as explanations for the properties of materials, such as crystals, semiconductors, superconductors, and superfluids. Applications of quantum behavior give us transistors, computer chips, lasers, and masers. The relatively new field of molecular biology, which leads to our better understanding of biological structures and life processes, derives from quantum considerations. Thus, quantum behavior encompasses a large fraction of modern science and technology.
Quantum theory was developed during the first half of the twentieth century through the efforts of many scientists. In 1926, E. Schrödinger interjected wave mechanics into the array of ideas, equations, explanations, and theories that were prevalent at the time to explain the growing accumulation of observations of quantum phenomena. His theory introduced the wave function and the differential wave equation that it obeys. Schrödinger's wave mechanics is now the backbone of our current conceptional understanding and our mathematical procedures for the study of quantum phenomena.
Our presentation of the basic principles of quantum mechanics is contained in the first three chapters. Chapter 1 begins with a treatment of plane waves and wave packets, which serves as background material for the subsequent discussion of the wave function for a free particle.
- Type
- Chapter
- Information
- Principles of Quantum MechanicsAs Applied to Chemistry and Chemical Physics, pp. 1 - 35Publisher: Cambridge University PressPrint publication year: 1999