Book contents
- Frontmatter
- Contents
- Preface
- 1 A polaron theory of high-temperature superconductors
- 2 On the possibility of non-BCS superconductivity
- 3 A bipolaron Bose liquid in high-Tc superconductors
- 4 Spin polarons in high-Tc superconductors
- 5 The polaron scenario for high-Tc superconductors
- 6 Formation, phase separation and superconductivity of large bipolarons
- 7 Polarons and bipolarons in WO3−x and YBa2Cu3O7
- 8 Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
- 9 Electron–phonon interaction of non-equilibrium carriers in the photoinduced state of YBa2Cu3O7−δ
- 10 Experimental evidence of local lattice distortion in superconducting oxides
- 11 The Hall effect due to small polarons and conduction in narrow energy bands
- 12 Static and dynamic conductivity of untwinned Y1Ba2Cu4O8: gaps or condensation?
- 13 The near infrared and optical absorption of high- Tc superconductors using powders
- 14 Polaronic theory of mid-infrared conductivity: a numerical cluster study
- 15 Electromagnetic properties of local pair superconductors
- 16 Electron–hole asymmetric polarons
- 17 On the nature of the superconducting state in high-Tc cuprates
- 18 High- Tc superconductivity with polarons and bipolarons: an approach from the insulating states
- 19 Coexistence of small-polaron and Anderson localization in high- Tc superconducting materials
- 20 Concentration and temperature-dependence of magnetic polaron spectra in the t–J model
- 21 Mass enhancement without band-narrowing in t–t′–J and related models: predictions for Fermi-surface and optical conductivity
- 22 Polarons in Peierls–Hubbard models
- 23 Exact estimates of inter-polaron coupling constants resulting in bipolaron formation
- 24 Coulomb interaction and the criteria for bipolaron formation
- 25 Large bipolarons and high-Tc materials
- 26 Collective excitations in the ground state of a two-dimensional attractive Fermi gas
- 27 Strong two-band electron self-trapping, state hybridization effects and related pressure-induced phenomena in semiconductors
- 28 Bismuth disproportionation in super- and semiconducting barium bismuthates
- 29 Magnetic polarons in concentrated and diluted magnetic semiconductors
- 30 Energy scales of exotic superconductors
- Index
28 - Bismuth disproportionation in super- and semiconducting barium bismuthates
Published online by Cambridge University Press: 24 November 2009
- Frontmatter
- Contents
- Preface
- 1 A polaron theory of high-temperature superconductors
- 2 On the possibility of non-BCS superconductivity
- 3 A bipolaron Bose liquid in high-Tc superconductors
- 4 Spin polarons in high-Tc superconductors
- 5 The polaron scenario for high-Tc superconductors
- 6 Formation, phase separation and superconductivity of large bipolarons
- 7 Polarons and bipolarons in WO3−x and YBa2Cu3O7
- 8 Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
- 9 Electron–phonon interaction of non-equilibrium carriers in the photoinduced state of YBa2Cu3O7−δ
- 10 Experimental evidence of local lattice distortion in superconducting oxides
- 11 The Hall effect due to small polarons and conduction in narrow energy bands
- 12 Static and dynamic conductivity of untwinned Y1Ba2Cu4O8: gaps or condensation?
- 13 The near infrared and optical absorption of high- Tc superconductors using powders
- 14 Polaronic theory of mid-infrared conductivity: a numerical cluster study
- 15 Electromagnetic properties of local pair superconductors
- 16 Electron–hole asymmetric polarons
- 17 On the nature of the superconducting state in high-Tc cuprates
- 18 High- Tc superconductivity with polarons and bipolarons: an approach from the insulating states
- 19 Coexistence of small-polaron and Anderson localization in high- Tc superconducting materials
- 20 Concentration and temperature-dependence of magnetic polaron spectra in the t–J model
- 21 Mass enhancement without band-narrowing in t–t′–J and related models: predictions for Fermi-surface and optical conductivity
- 22 Polarons in Peierls–Hubbard models
- 23 Exact estimates of inter-polaron coupling constants resulting in bipolaron formation
- 24 Coulomb interaction and the criteria for bipolaron formation
- 25 Large bipolarons and high-Tc materials
- 26 Collective excitations in the ground state of a two-dimensional attractive Fermi gas
- 27 Strong two-band electron self-trapping, state hybridization effects and related pressure-induced phenomena in semiconductors
- 28 Bismuth disproportionation in super- and semiconducting barium bismuthates
- 29 Magnetic polarons in concentrated and diluted magnetic semiconductors
- 30 Energy scales of exotic superconductors
- Index
Summary
Abstract
It is explained why, despite the strong exothermicity of the reaction generating two Bi4+ ions from one Bi3+ and one Bi5+ ion in the gas phase, solid barium bismuthate (Ba2BivBiIIIO6) contains bismuth in two different oxidation states and has a structure distorted from that of a perfect cubic perovskite by displacements of the oxide ions towards the Biv species. The predicted difference between the energy of this and that of an undistorted undisproportionated cubic perovskite (BaBiO3) containing only Biiv is in good agreement with the activation energy measured for conductivity by thermal hopping. It is also shown why, for x≳O.3, all materials of stoichiometry KxBa1-xBiO3 contain only one type of bismuth (BiIV) in a perovskite structure without the distorting oxide displacements of the undoped material. The distorted disproportionated structure is predicted to be degenerate with the undistorted undisproportionated structure when x = 0.34. A possible connection between this degeneracy and high-temperature superconductivity is discussed.
Observations for explanation
The primary object of this paper is to explain two related experimental observations concerning the structure of the semi-conductor barium bismuthate and the materials that result from its doping with K+ ions. We then comment on possible connections with the high-temperature superconductivity (HTS) exhibited by the latter materials at sufficiently high levels of doping.
The first observation requiring an explanation is that there are two different types of bismuth site in the undoped material of stoichiometric formula BaBiO3[l–7]. This compound thus has the formula Ba2BvBiIIIO6[l–7], where the superscript denotes formal oxidation state.
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- Publisher: Cambridge University PressPrint publication year: 1995