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11 - Concluding chapter

Published online by Cambridge University Press:  05 March 2012

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Summary

Perhaps the two most blatant omissions from the preceding chapters on μSR are background theory and solid-state applications. Justification for the dearth of theoretical derivations of the equations used in the text is offered on the grounds that each facet of μSR theory, from quantum electrodynamics to free radical hyperfine tensors, has already been dealt with elsewhere, better than could be accomplished here. Particularly commendable from the chemists' point of view are the treatments of Hughes (1966), Ivanter & Smilga (1968), Brewer, Crowe, Gygax & Schenck (1975), Schenck (1976), Percival & Fischer (1976), Brewer & Crowe (1978), Fleming et al. (1979), Garner (1979) and Roduner & Fischer (1981).

On the second major omission, it must be acknowledged that solid-state physics constitutes at least three-quarters of the total μSR research effort (Brewer & Crowe, 1978). This reflects the great value of the muon's unique magnetic moment, and its spin polarization, as a probe of structure and dynamics. The solid state encompasses more diversification than one should try to enumerate. Chemical compositions range from pure elements, through compounds and complex minerals, to an inexhaustible selection of ‘doped’ materials. Their magnetic properties include diamagnetics, paramagnetics, ferromagnetics and antiferromagnetics; electrical properties range from metals through semi-conductors to insulators; structures embrace ionic crystals, molecular crystals, amorphous phases and glassy media; and many of these properties change drastically with temperature, which is readily altered from several hundred degrees to almost zero. Mu and μ+ (and μ) probe the local magnetic, nuclear and electronic structures, and they can mimic H and p+ as inter st it ials.

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Publisher: Cambridge University Press
Print publication year: 1983

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  • Concluding chapter
  • D. C. Walker
  • Book: Muon and Muonium Chemistry
  • Online publication: 05 March 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511721717.014
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  • Concluding chapter
  • D. C. Walker
  • Book: Muon and Muonium Chemistry
  • Online publication: 05 March 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511721717.014
Available formats
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Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Concluding chapter
  • D. C. Walker
  • Book: Muon and Muonium Chemistry
  • Online publication: 05 March 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511721717.014
Available formats
×