One-photon sources are important elements in quantum optics. The archetypal example is an atom raised to an excited state at time t = 0, then de-exciting with emission of a single photon. The development of this kind of source depends on progress with experimental techniques, e.g. the possibility of isolating a single atom, molecule or quantum well. In this complement, we present the formalism for describing the corresponding radiation, and use it to discuss some spectacular experiments which bring out properties quite incompatible with a classical description of the electromagnetic field. We begin in Section 5B.2 by describing the anti-correlation between detections on either side of a semi-reflecting mirror, establishing the quantitative difference with a classical field. Section 5B.3 discusses a quantum optical effect that was only demonstrated at the beginning of the twenty-first century, namely the quantum coalescence of two one-photon wave packets on a semi-reflecting mirror, which occurs even when the two photons were emitted by independent atoms. An analogous effect, the Hong–Hou–Mandel effect, is discussed in Chapter 7. These effects exemplify quantum interference involving two photons. Finally, Section 5B.4 is concerned with quantum calculations involving quasi-classical states. As we now know, this leads to results that are identical to the predictions of semi-classical theory.