Book contents
- Frontmatter
- Contents
- Preface
- Physical constants and other numerical data
- Prefixes to Units
- 1 Structure, energy, mechanism
- 2 Atoms, molecules and their structures
- 3 Determination of structure
- 4 Energy and energetics
- 5 States of matter: gases and liquids
- 6 States of matter: solids
- 7 Phase rule and properties of solutions
- 8 Chemical equilibrium
- 9 Electrochemistry
- 10 Chemical kinetics and mechanisms of chemical reactions
- Appendix 1 Problem-solving with personal computers
- Appendix 2 Stereoviewing
- Appendix 3 Average classical thermal energies
- Appendix 4 Reduced mass
- Appendix 5 Spherical polar coordinates
- Appendix 6 Gamma function
- Appendix 7 Slater's rules
- Appendix 8 Linear least squares and the propagation of errors
- Appendix 9 Determinants and cofactors
- Appendix 10 Solution of a second-order differential equation
- Appendix 11 Separation of variables
- Appendix 12 Overlap integrals
- Appendix 13 Partial derivatives
- Appendix 14 Numerical integration
- Appendix 15 Fermi-Dirac statistics
- Appendix 16 Calculation of Madelung constants
- Appendix 17 The hypsometric formula: an example of the Boltzmann distribution
- Appendix 18 Tables of physical data
- Bibliography
- Answers to numerical problems
- Index
- Frontmatter
- Contents
- Preface
- Physical constants and other numerical data
- Prefixes to Units
- 1 Structure, energy, mechanism
- 2 Atoms, molecules and their structures
- 3 Determination of structure
- 4 Energy and energetics
- 5 States of matter: gases and liquids
- 6 States of matter: solids
- 7 Phase rule and properties of solutions
- 8 Chemical equilibrium
- 9 Electrochemistry
- 10 Chemical kinetics and mechanisms of chemical reactions
- Appendix 1 Problem-solving with personal computers
- Appendix 2 Stereoviewing
- Appendix 3 Average classical thermal energies
- Appendix 4 Reduced mass
- Appendix 5 Spherical polar coordinates
- Appendix 6 Gamma function
- Appendix 7 Slater's rules
- Appendix 8 Linear least squares and the propagation of errors
- Appendix 9 Determinants and cofactors
- Appendix 10 Solution of a second-order differential equation
- Appendix 11 Separation of variables
- Appendix 12 Overlap integrals
- Appendix 13 Partial derivatives
- Appendix 14 Numerical integration
- Appendix 15 Fermi-Dirac statistics
- Appendix 16 Calculation of Madelung constants
- Appendix 17 The hypsometric formula: an example of the Boltzmann distribution
- Appendix 18 Tables of physical data
- Bibliography
- Answers to numerical problems
- Index
Summary
This book is a complete revision of an earlier work of the same title by the author and his late colleague, Dr W H Lee. It is intended to meet the requirements of students in their first and second years of a degree course in chemistry, or in those sciences for which chemistry forms a significant part, and so to prepare the ground for more advanced final-year studies in this subject.
The mathematical arguments that have been employed in the book should lie within the scope of any chemistry degree student, who will have studied mathematics to A-level, or its equivalent, at least. Physical chemistry is not a nonmathematical subject: any attempt to make it appear so will probably detract from the elegance that attends those approaches that have served this subject well. Some less familiar mathematical topics are discussed in appendices.
Each chapter has been provided with a set of problems designed to enhance the reader's appreciation of the subject matter and its application to new situations. A suggested scheme for solving problems has been given in Appendix 1. The ready availability of computers means that much more extensive data sets can be handled than would be reasonable with hand calculators.
To this end, a number of computer programs has been written, as outlined in Appendix 1. They have been made available on the Worldwide Web internet and may be accessed at web site www.cup.cam.ac.uk; the set of programs, with notes, may be obtained also from the author.
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- Information
- Introduction to Physical Chemistry , pp. xvi - xviiPublisher: Cambridge University PressPrint publication year: 1998