Book contents
- Green Catalysis and Reaction Engineering
- Cambridge Series in Chemical Engineering
- Green Catalysis and Reaction Engineering
- Copyright page
- Dedication
- Contents
- Preface
- Acknowledgments
- 1 Sustainability Challenges of the Chemical Industry
- 2 Multiphase Catalytic Processes and Sustainability Challenges
- 3 Ethylene Production from Diverse Feedstocks and Energy Sources
- 4 Ethylene Epoxidation in Gas-Expanded Liquids with Negligible CO2 Formation as a Byproduct
- 5 Spray Reactor-Based Terephthalic Acid Production as a Greener Alternative to the Mid-Century Process
- 6 Sustainability Assessments of Hydrogen Peroxide-Based and Tertiary Butyl Hydroperoxide-Based Propylene Oxide Technologies
- 7 Separation of Propane/Propylene Mixture by Selective Propylene Hydroformylation in Gas-Expanded Liquids
- 8 A Greener Higher Olefin Hydroformylation Process
- 9 Solid Acid-Catalyzed Olefin/Isoparaffin Alkylation in Supercritical Carbon Dioxide
- 10 Epilogue
- Index
- References
6 - Sustainability Assessments of Hydrogen Peroxide-Based and Tertiary Butyl Hydroperoxide-Based Propylene Oxide Technologies
Published online by Cambridge University Press: 15 September 2022
Book contents
- Green Catalysis and Reaction Engineering
- Cambridge Series in Chemical Engineering
- Green Catalysis and Reaction Engineering
- Copyright page
- Dedication
- Contents
- Preface
- Acknowledgments
- 1 Sustainability Challenges of the Chemical Industry
- 2 Multiphase Catalytic Processes and Sustainability Challenges
- 3 Ethylene Production from Diverse Feedstocks and Energy Sources
- 4 Ethylene Epoxidation in Gas-Expanded Liquids with Negligible CO2 Formation as a Byproduct
- 5 Spray Reactor-Based Terephthalic Acid Production as a Greener Alternative to the Mid-Century Process
- 6 Sustainability Assessments of Hydrogen Peroxide-Based and Tertiary Butyl Hydroperoxide-Based Propylene Oxide Technologies
- 7 Separation of Propane/Propylene Mixture by Selective Propylene Hydroformylation in Gas-Expanded Liquids
- 8 A Greener Higher Olefin Hydroformylation Process
- 9 Solid Acid-Catalyzed Olefin/Isoparaffin Alkylation in Supercritical Carbon Dioxide
- 10 Epilogue
- Index
- References
Summary
Propylene oxide (PO), a commodity chemical used for making antifreeze and plastics, has long been manufactured using technologies that make co-products that influence process economics and environmental footprint. In contrast, the hydrogen peroxide propylene oxide (HPPO) process (commercialized by Dow-BASF) uses titanium silicate as a catalyst and hydrogen peroxide (H2O2) as an oxidant to selectively produce PO without a co-product. Another alternate process (CEBC-PO) uses a homogeneous methyltrioxorhenium (MTO) catalyst and H2O2 to exclusively produce PO. This chapter compares the economics and environmental footprint of three technologies for making PO: HPPO, CEBC-PO and LyondelBasell that makes tertiary butyl alcohol (TBA) as a co-product. While the HPPO and CEBC-PO processes are profitable, the profitability of the LyondellBasell process depends on the demand and value for TBA. Cradle-to-gate LCA reveals that the environmental impacts of all three processes are similar, with most of the adverse impacts caused by using fossil-based sources (natural gas and transportation fuel) for producing the raw materials (isobutane, propylene and hydrogen peroxide).
Keywords
- Type
- Chapter
- Information
- Green Catalysis and Reaction EngineeringAn Integrated Approach with Industrial Case Studies, pp. 123 - 147Publisher: Cambridge University PressPrint publication year: 2022
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