Introduction

In a pioneering study on the electron impact excitation of atomic oxygen, Seaton (1953) formulated the now well known close-coupling approximation of atomic collision theory, which he termed the “continuum state Hartree-Fock method”, reflecting the physical picture that the new method was an extension of the bound state method to the continuum region that encompassed electron-ion scattering and photoionization phenomena. For nearly three decades, the close coupling approximation has been widely employed to calculate the most accurate low-energy cross sections for excitation and photoionization, and radiative transition probabilities. Large computational packages were developed, mainly at University College London and the Queen's University of Belfast, to carry out the enormous task of fulfilling the needs of astrophysicists and plasma physicists. In particular, the R-matrix method developed by Burke and associates (Burke et al. 1971) has proved to be computationally very efficient for large-scale calculations.

A huge amount of radiative atomic data was produced, during last 10 years or so, under the auspices of an international collaboration of atomic physicists and astrophysicists, called the Opacity Project, led by Seaton (Seaton et al. 1994).