Ænigmatite occurs as a trace constituent of the Ægirine-Riebeckite Granite of the Liruei Complex, Younger Granite Province of Nigeria. It is enriched in Ti and Mg and depleted in Si, Al, and Ca relative to many other ænigmatites. Relative to coexisting ægirine and arfvedsonitic riebeckite it is enriched in Ti and depleted in Fe3+. Conditions required for formation of the mineral appear to have been high Ti concentration in a peralkaline magma of low T and fo2. The composition of the Nigerian ænigmatite confirms that there is only limited miscibility between rhönite and aenigmatite although in certain circumstances the two may have a paragenetic relationship.

Phase relations at atmospheric pressure in the pseudobinary join KAlSi2O6 (Lc)-NaAlSi3O8(Ab) and in the pseudoternary join Lc-Ab-CaAl2Si2O8(An) indicate that leucite is in-compatible with Na-feldspar. In the former join leucite can exist with an alkali feldspar of maximum albite content Ab54. In the Lc-Ab-An join, leucite only coexists with ternary feldspars with high An contents (approximately An50). Under PH2O conditions leucites may only coexist with alkali feldspars even poorer in Ab than those found at atmospheric pressure. Rare occurrences of coexisting leucite and Na-feldspar in nature have probably not crystallized directly from a melt but may have formed by a process of alkali ion exchange; or they may be unstable assemblages. No support can be found for the suggestions based on thermochemical calculations that albite and leucite are compatible at high temperatures.

Minute crystals of pure Mg-sapphirine approximating (Mg3.23Al4.74)vi(Al4.69Si1.31)ivO20, and thus having more aluminous compositions than the hitherto accepted 7:9:3 end member, were formed together with Mg-cordierite and corundum along narrow zones of the schist through reaction of the pre-existing high-pressure assemblages kyanite-gedrite and kyanite-talc. These sapphirines are considered to be metastable intermediate products growing under the influence of the structurally similar host mineral kyanite. Under equilibrium conditions they continued to react with kyanite to form the stable assemblage cordierite-corundum. Peraluminous sapphirines including those most recently synthesized may be metastable phases under all conditions of crystallization.

Aluminous Ca-rich clinopyroxenes (5.95-7.63 wt % Al2O3) are next in abundance to leucite in the basic alkaline potassic lavas from Monte Somma and Vesuvius, Italy, and occur as phenocrysts (1 to 7 mm), micropbenocrysts (< 1 mm), and groundmass granules. Zoning of various types is a conspicuous feature in these pyroxenes. Optical and chemical data are presented and a comparison is made between these pyroxenes and similar ones from alkali basalts. It is known from published data that Al2O3 fluctuates strongly in the oscillatory zones of Vesuvian pyroxenes. This can be explained as due to temperature variation in the magma, to magma variation in silica content due to contamination, to oscillations in leucite precipitation, or to a combination of these factors. Of these three factors, oscillations in leucite precipitation, as it appears, would be more effective than the others since it would have a greater control over Si/A1 availability in the magma.

Four new chemical analyses are reported for riebeckites of the hypersolvus granites of Massachusetts and Rhode Island. Riebeckites of southern New England are enriched in Li+, which appears to substitute for Fe2+, with additional Na+ coming in to compensate for the charge imbalance.

Microprobe analyses of eight ilmenites, a titaniferous magnetite, and a rutile are presented. They were synthesized at pressures from 5 to 26 kb and temperatures between 1075 and 1225°C in the anhydrous melting interval of a tholeiitic andesite from the Snake River Plain, Idaho, U.S.A. Both the Fe/Ti distribution between coexisting ilmenite and titanomagnetite at 11 kb/1075°C and the low calculated Fe3+ contents of the other ilmenites confirm previous suggestions that the fo2 in these experiments was buffered by graphite capsules to values near those generated by the wüstitemagnetite assemblage. Mn in the ilmenites (0·30-0·51% MnO) shows moderate negative correlations with both the pressures and temperatures of their formation, whilst Al (0·41-1·06 % Al2O3) shows poor positive correlations with these parameters. In contrast, the only significant trend shown by Mg in the ilmenites (2·09-5·26 % MgO) is with the position of each experimental run in the melting interval of the lava. Mg/(Mg + Fe2+) of the ilmenite decreases during equilibrium crystallization at a given pressure and appears to be controlled solely by Mg/Fe2+ distribution amongst the coexisting ferromagnesian minerals and interstitial liquid (glass).

Lodran is a unique meteorite consisting of roughly equal amounts of metal, olivine, and pyroxene with minor amounts of sulphide, chromite, phosphide, chrome-diopside, and a new phase with a composition close to (K,Na)AlSi5O12. Zähringer reported planetary-type rare gases in both the metal and silicates, suggesting a primitive nature. The pyroxene composition is Fs13.8 with little variation. Olivine composition averages Fa12.6, but varies at least ±20 % both among grains and zoned within single grains; only the Fe-rich olivine is in equilibrium with the pyroxene. The metal probably cooled rapidly (700 K/Myr) at high temperatures and slower (30 K/Myr) at lower temperatures. Two compositional populations of chromite are found.

A model for the formation of Lodran includes three steps: Formation of large olivine, pyroxene, and metal grains, with the trapping of small olivine inclusions in pyroxene and pyroxene in olivine. Equilibration and recrystallization of olivine, pyroxene, and metal, loss of alkalis and Ca; this probably occurred in a parent-body setting. And incorporation of reducing materials and mild reheating sufficient to produce the zoning in the olivine but not enough to re-equilibrate the pyroxene.

Phase compositions and rare-gas concentrations in ureilites are similar to those in Lodran. In some respects Lodran appears to be a metal-rich ureilite, but the higher Fe/(Fe+Mg) ratios in the latter (Fa 21 olivine) suggest origin on separate parent bodies.

The Harvard University meteorite is a mesosiderite and not closely related to Lodran.

Phosphates introduced into the et-Tabun cave as a result of human habitation, mainly as bone material, were partly dissolved by slightly acid solutions (organic acids derived from human or other animal activity). From these solutions, dahllite precipitated when the solutions came into contact with calcite. In the more weathered parts of the section, where little or no calcite occurs, the phosphate minerals formed are montgomeryite and crandallite.

In addition to the normal type of chromite alteration, an antipathetic form of alteration has been observed in the ultramafic zone of the Panton Sill, Western Australia. The chromites display margins of lower reflectivity related to a marked enrichment in MgO and Al2O3 and depletion in Cr2O3, Fe2O3, and FeO, such that a spinellid of composition lying between the end members MgAl2O4 and FeAlaO4 is formed. The alteration is related to the formation of secondary spinel in the ground-mass during the hornblendization of primary silicates under metasomatic conditions accompanied by low oxygen activity.

Apjohnite, MnAl2(SO4)4·22H2O, is monoclinic, space group P21/c, a 6·198 (2), b 24·347 (4), c 21·266 (4) Å, β 100·28 (3)° and Z = 4. The crystal structure was determined by means of direct methods applied to X-ray data collected with a single-crystal diffractometer. At the end of the refinement, performed with least-squares method, the R index was 0·039.

The SO4 tetrahedra, Al(H2O)5 octahedra, and MnO(H2O)5 octahedra are connected by a hydrogen bonding system; the only direct connection between polyhedra is by sharing of an oxygen between S(4) and Mn. In the asymmetric unit there are twenty-two water molecules, five of which lie in channels of the structure and are not linked to the cations but only to ligand water oxygens by means of hydrogen bonds.

Powder data indicate a close structural relationship between apjohnite, halotrichite, and pickeringite.

A flinty, spherulitic dyke of peralkaiine trachyte in a Precambrian dyke-swarm consists mainly of albite and aegirine. Within this, euhedral crystals of narsarsukite, Na2(Ti,Fe)Si4O10(F), occur as short prisms elongate parallel to c. This distinguishes them from all previously described narsarsukites, which have tabular habits. Minor phases present include micas, apatite, quartz, pectolite, nordite, and a thorium silicate. Probe analyses are presented for narsarsukite, aegirine, aibite, biotite, apatite, pectolite, nordite, and the thorium silicate.

On mineralogical and geochemical grounds it is unlikely that the narsarsukite-bearing dyke is a differentiate of supposedly mantle-derived basalt-trachyte-comendite magmas in the region. The dyke is colinear with a comendite dyke exposed at lower altitude and it is suggested that the narsarsukite- bearing dyke developed as a rhcomorphic fenite generated by reaction between quartz diorite basement and fugitive alkaline solutions from the subjacent comendite.

The Kangerdlugssuaq late dike swarm, which strikes at a high angle to the well-known East Greenland coastal swarm, is described and chemical analyses presented. The basic members are characterized by a high potassium content. A variety of kaersutite-bearing gabbroic inclusions in one member of this swarm is described in detail and microprobe analyses of clinopyroxenes, amphiboles, plagioclases, sheet silicates, and spinel minerals are presented. On the basis of this evidence it is deduced that these inclusions derive from a cumulate sequence formed at depths of between 5 and 10 km beneath the Lower Tertiary land surface. It is likely that fractionation of such assemblages causes a transition, at relatively low pressure, from undersaturated to oversaturated compositions, but the products appear to be quantitatively minor.

It is proposed that mitridatite and englishite contain octahedral sheets of the alunite type and that their formulae are [Ca6(H2O)3(PO4)2][Fe3(OH)6(PO4)(PO3OH)]3 and [K2Na(H2O)4Ca4·5 (PO3OH)3][Al3(OH)6(PO4)(PO3OH)]3 respectively.

Chemical analyses of eleven garnets from orthogneisses and related pegmatites, belonging to the Upper Swat Hornblendic Group, Pakistan, are presented along with the petrographic descriptions of the host rocks. The garnets show dominant almandine content, followed by grossular pyrope, spessartine, and andradite, in order of relative abundance. One garnet sample is different from the rest in having higher andradite and spessartine contents and higher refractive index, and is also different in habit. This is the first detailed study of garnets from Pakistan.

Concretionary siderite horizons are quite common in massive clay sequences. One such horizon, from the Westphalian of Yorkshire, has been studied in detail. Two iron-rich carbonate minerals occur together although they cannot be distinguished in thin section on account of very fine grain size. One is much richer in magnesium (pistomesite) than the other (siderite). The latter is rela-tively rich in manganese and the heavier stable carbon isotope 13C whereas the former carbonate is richer in calcium and 12C. The most important iron source is thought to have been hydrated iron oxides originating in soils. Much of the carbonate carbon started as organic molecules. The siderite appears to have formed earlier than the pistomesite. The stratiform character of these deposits appears to reflect siltier horizons in the mudstones, which presumably channelled pore water migration during compaction. This is probably why such carbonate horizons were formerly believed to be of simple sedimentary rather than diagenetic origin.

A wide range of volcanic sublimates and alteration products from the Johnston-Lavis collection has been analysed for major elements plus copper, lead, and zinc. 'Aphthitalite' and 'natrikalite' from Mount Vesuvius and an 'alum' from the island of Vulcano all proved to be enriched in copper and selected analyses are tabulated. The process leading to copper and lead enrichment of the Vesuvian material may be vapour phase transport as chloride followed by sulphation on sublimation. It is suggested that the source of the copper found in the alum sample from Vulcano could be of interest to economic geologists.

Differential thermal analysis of a rapidly reversible transition in carnegieite to 7 kbar shows the transition temperature increases from ⪝ 707°C (on heating) at I bar with initial slope ≈ 8·0 deg kbar−1 and anomalous curvature (d2T/dp2 > o), with hysteresis between heating and cooling signals that decreases with pressure. DTA of rapidly reversible transitions in nepheline shows the very subtle transition near 185°C (on heating) at 1 bar decreases with pressure to ≈ 170°C near 2-3 kbar and hardly varies in temperature up to 6 kbar; and the higher temperature transition increases from ≈ 872°C (on heating) at 1 bar with slope ≈ 25 deg kbar−1, to 5 kbar, with the hysteretic interval remaining essentially unchanged in the investigated range.

Seven chemical analyses of pink or green tourmalines belonging to the elbalte-schorl series, along with their physical, optical, and X-ray data are presented. Linear variation diagrams showing the relationship between composition and refractive indices, specific gravities, and cell parameters are constructed. Relationship between colour and chemical composition is also discussed.

Plagioclase crystal fragments and a block of anorthosite occur in small basaltic dykes on the Jos Plateau. The anorthosite is unusual, for the feldspar is labradoritic, but the interstitial mineralogy is granitic rather than basic, displaying granophyric intergrowths in places. The anorthosite is probably not an intermediate stage in fractionation from a basic parent magma towards granite, since over 95 % of this large province is granitic and the volume of basic magma required would be prohibitively large. Nor did it develop as an intermediate stage in fractionation from a salic parent magma, e.g. syenite, because the plagioclase is too calcic to have crystallized from a syenitic melt. Basic to intermediate dykes are numerous though volumetrically insignificant in the Younger Granite province. The anorthosite may be related to the evolution of small volumes of basaltic magma, which had little to do with Younger Granite magmatism.

A new analysis of the violet amphibole from the original locality where winchite came from agrees with another recent analysis in differing substantially from the original winchite composition and is (K0·17Na2·10Ca0·23)(Al0·19Ti0·00Fe31·27Fe20·01Mn0·07Mg3·34)Si8·01O22·05(OH)1·95. It is essentially a magnesio-arfvedsonite. Although it is possible that the original analysis was unreliable, evidence is given to support the alternative view that there is a wide range of blue alkali and soda calcic amphibole compositions at Kajlidongri and the name winchite should be restricted to compositions between ferri-winchite CaNaMg5Fe3+Si8O22(OH,F,Cl)2 and alumino-winchite CaNaMg5Al Si8O22(OH,F,Cl)2. X-ray, density, and optical data on the analysed mineral are given.