The lower Palaeozoic marine succession of NE Vietnam accumulated on the South China plate. Despite historical works dating to French colonial times, the stratigraphy and palaeontology of the succession is poorly constrained. Chief amongst the lower Palaeozoic lithostratigraphical divisions is the Than Sa Formation, a c. 1200 m thick succession of clastic rocks of Cambrian and early Ordovician age. Newly collected graptolites (including Rhabdinopora? sp. and Tetragraptus approximatus) from the upper part of the formation identify strata assignable to the Tremadocian and Floian stages of the Lower Ordovician. The same succession also probably records the Cambrian–Ordovician boundary. Our analysis identifies one or more intervals of graptolite-bearing laminated mudstones in the upper part of the Than Sa Formation that may be widespread in NE Vietnam during the early Tremadocian.

Subduction initiation is a cornerstone in the edifice of plate tectonics. It marks the turning point of the Earth's Wilson cycles and ultimately the supercycles as well. In this paper, we explore the consequences of subduction zone invasion in the Atlantic Ocean, following recent discoveries at the SW Iberia margin. We discuss a buoyancy argument based on the premise that old oceanic lithosphere is unstable for supporting large basins, implying that it must be removed in subduction zones. As a consequence, we propose a new conceptual model in which both the Pacific and the Atlantic oceans close simultaneously, leading to the termination of the present Earth's supercycle and to the formation of a new supercontinent, which we name Aurica. Our new conceptual model also provides insights into supercontinent formation and destruction (supercycles) proposed for past geological times (e.g. Pangaea, Rodinia, Columbia, Kenorland).

We develop a two-dimensional thermo-mechanical numerical model in which the formation of oceanic crust and serpentinite due to the hydration of the uprising mantle peridotite has been implemented, with the aim of discussing the behaviour of the lithosphere of the Alps and Northern Apennines during the transition from continental rifting to ocean spreading of the Alpine Tethys. The predictions of the model are compared with natural data related to the Permian–Triassic high-temperature – low-pressure (HT-LP) metamorphism affecting the continental lithosphere and data from the Jurassic P–T evolution of the oceanic lithosphere from the Alps and the Northern Apennines. Our analysis indicates that a thinned continental crust, an ocean–continent transition zone and an oceanic lithosphere characterize the final structure of the system in a poor magma rift pre-Alpine configuration. We also find that mantle serpentinization starts before crustal break-up and that denudation occurs before ocean spreading. The mantle denudation starts several million years before the gabbros/basalt formation, generating an ocean–continent transition zone from the passive continental margin to the oceanic lithosphere of size 160–280 km. The comparative analysis shows that the extension of a hot and weak lithosphere, which promotes the development of hyperextended Alpine margins, better agrees with the natural data. Finally, our comparative analysis supports the hypothesis that the lithospheric extension preceding the opening of the Alpine Tethys did not start in a stable continental lithosphere, but developed by recycling part of the old Variscan collisional suture.

The Jurassic Linglong granites, intrusive into the North China Craton (NCC) in eastern China, provide a critical record of the first major episode of lithospheric-scale extension and magmatism in NE China during Mesozoic time. Our U–Pb zircon dating reveals that the Linglong granites were emplaced during 161–158 Ma, shortly after the inception of a shallow subduction of the Palaeo-Pacific plate beneath East Asia during Middle Jurassic time. These granites have high alkali contents (K2O + Na2O = 8–9 wt%), low MgO and Mg no. values and variable Cr–Ni abundances. Their relatively high Ba and Sr concentrations, relatively low heavy rare Earth element (HREE) and strongly fractionated REE patterns characterize them as high Ba–Sr granites. The negative whole-rock εNd(t) values ranging from −22.4 to −10.9 and wide-ranging zircon εHf(t) values of −39.1 to −1.5 suggest that magmas of the Linglong granites were produced by partial melting of a garnet-amphibolite-bearing lower crust of the Jiaobei Terrane and by re-melting of the Triassic ultrahigh-pressure (UHP) metamorphic rocks and alkaline suites of the Sulu Terrane. The occurrence in the granitic rocks of inherited zircons of the Neoarchaean, Palaeoproterozoic, Neoproterozoic, Palaeozoic and Triassic ages suggests that magmas of the Linglong granites interacted with the ancient crust in these terranes during their ascent. Asthenospheric upwelling, induced by the steepening and rapid rollback of the Palaeo-Pacific slab during Late Jurassic time, provided the heat source for the inferred lower crustal melting. Trench migration and thermal weakening of the crust caused extensional deformation and thinning in the eastern part of the NCC.

Palaeoproterozic metasedimentary rocks, also referred to as khondalites, characterized by Al-rich minerals, are extensively exposed in the nucleus of the Yangtze craton, South China block. Samples of garnet–sillimanite gneiss in the khondalite suite were collected from the Kongling complex for Nd isotopic and elemental geochemical study. These rocks are characterized by variable SiO2 contents ranging from 35.71 to 58.07 wt%, and have low CaO (0.45–0.84 wt%) but high Al2O3 (18.56–29.04 wt%), Cr (174–334 ppm) and Ni (42.5–153 ppm) contents. They have high CIW (Chemical Index of Weathering) values (90.4–94.7), indicating intense chemical weathering of the source material. The samples display light rare earth elements (LREE) enrichment with negative Eu anomalies (Eu/Eu*=0.40–0.68), and have flat heavy rare earth elements (HREE) patterns. The high contents of transition elements (e.g. Cr, Ni, Sc, V) and moderately radiogenic Nd isotopic compositions suggest that the paragneisses might be those of first-cycle erosion products of predominantly mafic rocks mixing with small amounts of felsic moderately evolved Archaean crustal source. Geochemical and Nd isotopic compositions reveal that at least some of the protoliths of Kongling khondalite were sourced from local pre-existing mafic igneous rocks in a continental arc tectonic setting. Combined with documented zircon U–Pb geochronological data, we propose that the Palaeoproterozoic high-pressure granulite-facies metamorphism, rapid weathering, erosion and deposition of the khondalites in the interior of the Yangtze craton might be related to a Palaeoproterozoic collisional orogenic event during 2.1–1.9 Ga, consistent with the worldwide contemporary orogeny, implying that the Yangtze craton may have been an important component of the Palaeoprotorozoic Columbia supercontinent.

The Shackleton Range is a truncated Pan-African Orogen situated at the Weddell Sea margin of East Antarctica. It almost exclusively consists of basement rocks exposed at an elevated, escarpment-bound palaeosurface and is covered locally by patchy remnants of Ordovician, Permian and, controversially, Jurassic terrestrial deposits. This inventory does not match the geological record of any other place in Antarctica. Here we reconstruct the Phanerozoic evolution of the Shackleton Range by means of a multi-disciplinary approach combining petrological, geochemical and geochronological data with thermal history models of zircon and apatite fission track (ZFT, AFT) and (U–Th–Sm)/He (AHe) data. Petrographic, geochemical and 40Ar/39Ar analyses of a sedimentary cover sequence identify volcaniclastic rocks related to the Ferrar/Karoo magmatic event. Thermal history modelling of ZFT ages of 160–215 Ma, AFT ages of 124–225 Ma, AHe ages of 95–169 Ma and kinematic proxies in combination with geological information indicates a complex thermal history comprising at least three cooling episodes interrupted by reheating pulses. Thermal history refers to inversion of part of the Carboniferous–Triassic Transantarctic Basin prior to the 180 Ma Ferrar/Karoo Event and formation of an up to 3.4 km deep extensional Jurassic – Early Cretaceous basin due to Weddell Sea rifting. Basin depth was diminished by regional middle Cretaceous stress field changes. Final basin inversion and surface uplift were likely triggered by far-field tectonics and climatic influence. This history represents a typical example for the transition from an active to passive margin setting along the outer rim of Gondwana.

Field-based mapping, sandstone petrology, palaeocurrent measurements and zircon cathodoluminescence images, as well as detrital zircon U–Pb geochronology were integrated to investigate the provenance of the Upper Carboniferous – Upper Triassic sedimentary rocks from the northern Bogda Mountains, and further to constrain their tectonic evolution. Variations in sandstone composition suggest that the Upper Carboniferous – Lower Triassic sediments displayed less sedimentary recycling than the Middle–Upper Triassic sediments. U–Pb isotopic dating using the LA-ICP-MS method on zircons from 12 sandstones exhibited similar zircon U–Pb age distribution patterns with major age groups at 360–320 Ma and 320–300 Ma, and with some grains giving ages of > 541 Ma, 541–360 Ma, 300–250 Ma and 250–200 Ma. Coupled with the compiled palaeocurrent data, the predominant sources were the Late Carboniferous volcanic rocks of the North Tianshan and Palaeozoic magmatic rocks of the Yili–Central Tianshan. There was also input from the Bogda Mountains in Middle–Late Triassic time. The comprehensive geological evidence indicates that the Upper Carboniferous – Lower Permian strata were probably deposited in an extensional context which was related to a rift or post-collision rather than arc-related setting. Conspicuously, the large range of U–Pb ages of the detrital zircons, increased sedimentary lithic fragments, fluvial deposits and contemporaneous Triassic zircon ages argue for a Middle–Late Triassic orogenic movement, which was considered to be the initial uplift of the Bogda Mountains.

In this study, the petrology, zircon U–Pb ages, Lu–Hf isotopic compositions, whole-rock geochemistry and Sr–Nd isotopes for newly recognized low-Mg and high-Mg adakitic rocks from the North Altun orogenic belt were determined. The results will provide important insights for understanding the continuities of the North Qilian and North Altun orogenic belts during early Palaeozoic time. The low-Mg adakitic granitoids (445 to 439 Ma) are characterized by high SiO2 (69–70 wt %), low Mg no. (43–48) and low Cr and Ni contents. In contrast, the high-Mg adakitic granitoids (425 to 422 Ma) have relatively lower SiO2 (65–67 wt %), higher Mg no. (60–62) and higher Cr and Ni contents. The low-Mg adakitic rocks have high initial 87Sr/86Sr ratios (0.7073–0.7084), negative εNd(t) (−1.9 to −4.0) and εHf(t) values (−6.8 to −2.0), and old zircon Hf model ages (1.4–1.7 Ga). In contrast, the high-Mg adakitic rocks show lower initial 87Sr/86Sr ratios (0.7044–0.7057), higher εNd(t) (−0.7 to 3.1) and positive εHf(t) values (2.0 to 6.9), with younger zircon Hf model ages (0.9–1.2 Ga). These results suggest that the low-Mg adakitic rocks were probably generated by the partial melting of thickened crust, whereas the high-Mg adakitic rocks were derived from the anatexis of delaminated lower crust, which subsequently interacted with mantle magma upon ascent. The data obtained in this study provide significant information about the geological and tectonic processes after the closure of the Altun Ocean. The continent–continent collision and thickening probably occurred during 450–440 Ma with the formation of low-Mg adakitic rocks, and the transition of the tectonic regime from compression to extension probably occurred at 425–422 Ma with the formation of high-Mg adakitic rocks. The geochemical, geochronological and petrogenetic similarities between the North Altun and North Qilian adakitic rocks suggest that these two orogenic belts were subjected to similar tectonomagmatic processes during early Palaeozoic times.

The Amdeh Formation is a 3.4 km stack of sparsely fossiliferous quartzites and shales which crops out in the Al Hajar mountains near Muscat. Here we describe the uppermost member (Am5) that can be dated biostratigraphically as Darriwilian and which is the outcrop equivalent, and probably the seaward continuation, of the Saih Nihayda Formation in the Ghaba Salt Basin of northern Oman. The outcrops at Wadi Daiqa and Hayl al Quwasim consist of 690 m of quartzitic sandstones, shales and bivalve-rich shell beds. Trace fossils referable to the Cruziana and Skolithos ichnofacies abound. The member comprises storm-dominated shelf, shoreface and delta deposits. A number of new discoveries have been made in the outcrops: fragments of the arandaspid fish Sacabambaspis, ossicles and moulds of the early disparid crinoid Iocrinus, two new genera of conodont, an occurrence of the rare trinucleid trilobite Yinpanolithus, and palynological and sedimentological evidence of more continuous Floian–Darriwilian deposition than is usual in the region. Sea levels during Middle Ordovician time are estimated to have been 50–200 m above present levels and a wide, low-gradient shelf covered much of Arabia. Similar trace fossils and storm-dominated, micro-tidal, sedimentary rocks occur throughout the region. Small changes of sea level, possibly caused by the growth and melting of polar ice sheets, could lead to substantial seaward or landward shifts of facies belts. The Am5 deposits are thick compared to most equivalents in Arabia implying active subsidence and a ready supply of sediment.

Lawsonite eclogites are rare rocks and have been described from only a few localities in the world. Lawsonite-bearing assemblages are highly unstable and physico-chemical processes linked to exhumation may destroy them; only aggregates interpreted as pseudomorphs after lawsonite could be often recognized. In this paper, we present a detailed structural and petrological study of an area in the northwestern sector of the metaophiolitic high-pressure Voltri Massif (Ligurian Western Alps, Italy). The study area is characterized by a lawsonite-bearing eclogitic metagabbro associated with carbonated serpentinites and glaucophanic metasediments. The metagabbro body reached eclogitic metamorphic peak conditions at T = 465–477°C and P = 20.9–24.4 kbar, with H2O continuously supplied to the system. H2O under-saturated conditions, with the occurrence of both lawsonite and epidote, characterized the exhumation path. Both the low temperature recorded by the body and the occurrence of variously carbonated serpentinites led us to interpret this area as a portion of the top of the subducted slab, coupled with a ‘cool’ mantle wedge, where both aqueous fluids and carbonate-rich fluids were present. The occurrence of rocks belonging to different paleogeographic domains (e.g. continent versus ocean) and the multiple deformations recorded by the metagabbro suggest that this area was nearby the slab–mantle interface. This sector was thus affected by a shear regime that acted in a low-viscosity serpentinite channel, bringing these high-pressure rocks back to the surface.

The Maestrat basin was one of the most subsident basins of the Mesozoic Iberian Rift system, developed by a normal fault system which divided it into sub-basins. Its Cenozoic inversion generated the N-verging Portalrubio–Vandellòs fold-and-thrust belt in its northern margin, detached in the Triassic evaporites. In the hinterland, a 40 km wide uplifted area, in the N–S direction, developed, bounded to the N by the E–W-trending, N-verging Calders monocline. This monocline is interpreted as a fault-bend fold over the ramp to flat transition of the E–W-trending, N-verging Maestrat Basement Thrust, and also indicates the transition from a thick-skinned (S) to a thin-skinned (N) style of deformation. This paper presents a kinematic evolutionary model for the northern margin of the basin and a reconstruction of the Maestrat Basement Thrust geometry, generated by the inversion of the Mesozoic normal fault system. It contains a low-dip ramp (9°) extended southwards more than 40 km, attaining a depth of 7.5 km. As this thrust reached the Mesozoic cover to the foreland, it propagated across the Middle Muschelkalk evaporitic detachment, generating a nearly horizontal thrust which transported northwards the supra-salt cover, and the normal fault segments within it, for c. 11–13 km. The displacement of the basement in the hanging-wall of the low-dip basement ramp generated the 40 km wide uplifted area, while the superficial shortening was accumulated in the northern margin of the basin – which contains the thinnest Mesozoic cover – developing the Portalrubio–Vandellòs fold-and-thrust belt.

A reconnaissance survey of part of western Cambodia has found quarries in and near the town of Pailin containing chert, basalt, volcaniclastic rocks, gabbro and serpentinite. Abandoned quarries contain chert and basalt clasts in a volcaniclastic matrix and may constitute a mélange. A new, recently active, quarry contains these rock units in close and coherent contact but they lack the serpentinitic matrix of the Thung Kabin Mélange of eastern Thailand. The rock units are in close contact and may best be described collectively as a dismembered ophiolite. The mélange–ophiolite association constitutes a 3 km wide, 20 km long E–W belt separating a northern 200 km2 block of the mainly amphibolitic Pailin Crystalline Complex from a southern area of Triassic submarine fan siliciclastic rocks. The cherts yield the first documented radiolarian fauna from Cambodia and include a moderately well-preserved Asselian–Sakmarian age fauna consisting of Pseudoalbaillella sakmarensis, Pseudoalbaillella scalprata morphotype scalprata, Pseudoalbaillella sp. cf. P. simplex, Pseudoalbaillella u-forma morphotype II, Pseudoalbaillella sp. cf. P. elegans, Pseudoalbaillella sp. cf. P. lomentaria, Albaillella sp., Pseudoalbaillella spp., Trilonche? sp., Latentifistularia gen. et sp. indet. and Entactinaria gen. et sp. indet. The Pailin ophiolitic rocks, mélange and volcanic rocks occur within a generally E–W-trending belt, which suggests that the Sa Kaeo Suture does not extend southeastwards paralleling the Thai–Cambodian border, nor extend under the Cardamom Mountains but, rather, extends eastwards into Cambodia and possibly then turns southwards along the strike of the Pursat–Kampot Fold Belt.

Although the brittle material in analogue models is characterized by a linear Navier-Coulomb behaviour and rate-independent deformation, the geometry and style of deformation in accretionary wedges is sensitive to shortening velocity. In this study we have constructed a series of analogue models with various shortening velocities in order to study the influence of shortening velocity on the geometry and kinematics of accretionary wedges. Model results illustrate how shortening velocity has an important influence on the geometry and kinematics of the resulting wedge. In general, for models having similar bulk shortening, the accretionary wedges with higher velocities of shortening are roughly steeper, higher and longer, as well as having larger critical wedge angles and height. It accommodates a number of foreland-vergent thrusts, larger fault spacing and displacement rates than those of low- to medium-velocity shortening, which indicates a weak velocity-dependence in geometry of the wedge. Moreover, models with a high velocity of shortening undergo larger amounts of volumetric strain and total layer-parallel shortening than models with low- to medium-velocity shortening. The former accommodate a greater development of back thrusts and asymmetric structures; a backwards-to-forwards style of wedge growth therefore occurs in the frontal zone under high-velocity shortening.

The Vera Basin is one of a series of interconnected Neogene–Quaternary-age basins located within the Betic Cordillera in SE Spain. The initial marine phase in the basin is represented by the sedimentary succession of the Abad Member (Tortonian–Messinian) and comprises mainly marls with varying amounts of intercalated siliciclastic–calcareous turbidites. The succession contains a rich ichnofauna comprising 12 ichnogenera (21 ichnospecies), which can be subdivided into a number of distinct ichnoassemblages. Detailed analysis of the distribution of these ichnoassemblages reveals that deposition occurred within the Nereites ichnofacies, more specifically, the Paleodictyon sub-ichnofacies, presumably in a lobe-type setting, and at epi- to mesobathyal depths (i.e. 200–1000 m). Changes within the ichnofacies suggest that there is a clear deep-through-to-shallow trend within the succession extending from the older (i.e. Almocáizar Corridor) to the younger (i.e. centre of the Vera Basin) parts of the succession. These changes coincide with the onset of the Messinian Salinity Crisis (MSC) across the region, and correlate well with the pre-MSC through to Lago Mare deposits.

Diverse skeletal assemblage has been discovered in the Ediacaran/Cambrian strata of the Codos locality in NE Spain (Aragón, Cadenas Ibéricas). This assemblage includes at least seven genera, only three of which can be ascribed to known taxa. All the fossils are preserved in phosphate but their original microstructures are traceable by both elementary composition and microstructural features that are indicative for primary aragonite and high-magnesium calcite biomineralogies. Already these early skeletal fossils show sophisticated microstructures represented by heterogeneous multilayered composites to satisfy the requirements for better protection against both chemical dissolution and mechanical predator deterioration. The most common and best-preserved fossil, which is tubicolous Codositubulus grioensis gen. et sp. nov., is described here. The composition of the fossil assemblage and its stratigraphic position are indicative for the lowermost Terreneuvian (lower Cambrian) or even pre-Terreneuvian age of this fauna.

Globally, the Series 2 – Series 3 boundary of the Cambrian System coincides with a major carbon isotope excursion, sea-level changes and trilobite extinctions. Here we examine the sedimentology, sequence stratigraphy and carbon isotope record of this interval in the Cambrian strata (Durness Group) of NW Scotland. Carbonate carbon isotope data from the lower part of the Durness Group (Ghrudaidh Formation) show that the shallow-marine, Laurentian margin carbonates record two linked sea-level and carbon isotopic events. Whilst the carbon isotope excursions are not as pronounced as those expressed elsewhere, correlation with global records (Sauk I – Sauk II boundary and Olenellus biostratigraphic constraint) identifies them as representing the local expression of the ROECE and DICE. The upper part of the ROECE is recorded in the basal Ghrudaidh Formation whilst the DICE is seen around 30m above the base of this unit. Both carbon isotope excursions co-occur with surfaces interpreted to record regressive–transgressive events that produced amalgamated sequence boundaries and ravinement/flooding surfaces overlain by conglomerates of reworked intraclasts. The ROECE has been linked with redlichiid and olenellid trilobite extinctions, but in NW Scotland, Olenellus is found after the negative peak of the carbon isotope excursion but before sequence boundary formation.

A mafic amphibole-bearing granulite with porphyroblastic garnet was investigated to evaluate: (1) the rare earth element (REE) partition among garnet, zircon, orthopyroxene and amphibole during the metamorphic evolution; (2) the significance of the REE distribution along lobes and bights of reabsorbed garnet rim; and (3) REE distribution coefficient values (DREE) suggestive of chemical equilibrium, assuming garnet as a reference. The results have been compared with those deriving from an intermediate granulite containing porphyroblastic garnet, without amphibole. Porphyroblastic garnet from both samples is rimmed by a continuous corona formed during post-peak decompression characterized by REE-enriched lobes and REE-poor bights. The amphiboles from corona have various REE abundances, reflecting a different dissolution rate of original garnet rim. The initial slow rate of garnet dissolution caused high REE concentration in the new garnet rim due to intra-crystalline diffusion, leading to the formation of REE-poorer amphiboles in corona. Subsequently, under an increasing geothermal gradient and fluid-present conditions, the faster dissolution of garnet determined the formation of bights and the transfer of REEs towards the corona. The timing of garnet growth and its dissolution were checked by U–Pb zircon ages. The zircons dated from 339 Ma to 303 Ma in two rock types combined with the garnet domains (core, outer core, rim) show similar distribution of patterns relative to heavy rare earth elements for zircon and garnet (DHREEzrn/grt), suggesting chemical equilibrium. Zircons dated at c. 300 Ma do not appear in equilibrium with REE-rich garnet lobes, and younger zircons (278 Ma) show a new equilibrium with REE-poor garnet bights. On this basis, the DHREEamph/grt values obtained in specific textural sites might be interpreted as suggestive of equilibrium under granulite conditions.

The Early to Late Triassic development of a carbonate ramp system in the subtropical belt of the NW Tethys was controlled by the interplay of several global and regional factors: geotectonic setting (slow continuous subsidence on a passive continental margin), antecedent topography (low-gradient relief inherited from preceding depositional regime), climate and oceanography (warm and dry climatic conditions, storm influence), relative sea-level changes (Olenekian to Anisian eustatic rise, middle Anisian to early Carnian sea-level fall), lack of frame-builders (favouring the maintenance of ramp morphology), and carbonate production (abundant formation of lime mud, non-skeletal grains and marine cements, development of diverse biota controlled by biological evolution and environmental conditions). Elevated palaeorelief affected the ramp initialization on a local scale, while autogenic processes largely controlled the formation of peritidal cyclicity during the early stage of ramp retrogradation. Probably fault-driven differential subsidence caused a local distal steepening of the ramp profile in middle–late Anisian time. The generally favourable conditions promoted long-term maintenance of homoclinal ramp morphology and accumulation of carbonate sediments having great maximum thickness (~500 m). Shutdown of the carbonate factory and demise of the ramp system in the early Carnian resulted from relative sea-level fall and subsequent emergence. After a period of subaerial exposure with minor karstification, the deposition of continental quartz arenites suggests the possible effect of the Carnian Pluvial Episode.

The Los Sombreros Formation represents the western continental margin slope deposits of the Argentine Precordillera, a sub-terrane accreted to Gondwana as part of the Cuyania Terrane in early Palaeozoic times. The age of these gravity-driven deposits is controversial and, therefore, a precise biostratigraphic scheme is essential to reveal the evolution of the continental margin. New conodont samplings along with sedimentological and structural analysis carried out in the Los Sombreros Formation in the La Invernada Range provide clues to its depositional framework. The sedimentary succession is made up of dominantly calciturbidites, carbonate breccias and conglomerates, along with mudstones that represent the pelagic/hemipelagic background sedimentation. It displays hectometric to outcrop-scale slump folds with variable hinge-line orientations and pinch-and-swell structures, evidencing soft-sediment deformation, consistent with a slope to base-of-slope setting. Three limestone samples from this succession include conodonts referable to the pandemic Hirsutodontus simplex Subzone of the Cordylodus intermedius Zone (upper Furongian, Cambrian) and from the Macerodus dianae Zone (upper Tremadocian, Ordovician), implying that a slope connected the shallow-water shelf with a deep-water (oceanic) basin at least since late Cambrian times. The conodont faunas show affinities to coeval assemblages from outer shelf and slope environments around Laurentia yet they are not conclusive to postulate a geographic origin for the Precordillera. The thermal alteration of the conodonts is consistent with sedimentary burial and nappe stacking in this sector of the Precordillera.

The Zermatt-Saas Zone was part of the Middle to Late Jurassic Tethyan lithosphere that underwent oceanic metamorphism during Mesozoic time and subduction during Eocene time (HP to UHP metamorphism). In upper Valtournanche, serpentinite, metarodingite and eclogite record a dominant S2 foliation that developed under 2.5±0.3 GPa and 600±20°C during Alpine subduction. Serpentinites contain clinopyroxene and rare zircon porphyroclasts. Clinopyroxene porphyroclasts show fringes within S2 with similar compositions to that of grains defining S2. Zircon cores show zoning typical of magmatic growth and thin fringes parallel to the S2 foliation. These features indicate crystallization of clinopyroxene and zircon fringes during HP syn-D2 metamorphism, related to the Alpine subduction. The U–Pb zircon dates for cores and fringes reveal crystallization at 165±3.2 Ma and 65.5±5.6 Ma, respectively. The Middle Jurassic dates are in agreement with the known ages for the oceanic accretion of the Tethyan lithosphere. The Late Cretaceaous - Paleocene dates suggest that the Zermatt-Saas Zone experienced high-pressure to ultra-high-pressure (HP–UHP) metamorphism at c. 16 Ma earlier than previously reported. This result is in agreement with the evidence that in the Western Alps the continental Sesia-Lanzo Zone reached the subduction climax at least from 70 Ma and was exhumed during ongoing oceanic subduction. Our results are further evidence that the Zermatt-Saas ophiolites diachronically recorded heterogeneous HP–UHP metamorphism.