A dark layer (∼1 cm thick, 93.41 m deep) was identified in an ice core (116 m deep, covering the period -1350-1995) drilled at Styx Glacier plateau, northern Victoria Land, Antarctica. The ice-core section was dated around AD 1500 ± 20 by a firn-densification model. A chemical characterisation was performed on ten subsamples (resolution 3 cm) located around the dark layer by ion chromatography. The concentration/depth profiles of anions (Cl-, Br-, NC3-, H2PO4-, SO42-), cations (Na+, NH4+, K+, Mg*+, Ga2^) and some organic anions (acetate, formate, propionate and methanesulphonate (MSA)) indicate very high concentration peaks for all the components. However, non-sea-salt sulphate (nssSo/-) and F- show the greatest increase with respect to background values (370 and 860 times, respectively). A crustal contribution is attributed to Ga2+ and MSA. The profiles of gas-phase emitted substances (HF, HBr, HNOs and carboxylic acid) suggest gas emission just before the volcanic eruption. Chloride depletion is evident in the dark layer with respect to Na+/Cl- sea-water ratio. At present, it is not possible to attribute an unambiguous source to the volcanic event, but several pieces of evidence lead us to believe that this may be a time-limited local event.

Careful mineral and structural analyses have revealed the characteristics of volcanic ash in the nine horizons of an 80.2 m ice core from Collins Ice Cap, King George Island, Antarctica.

Under the assumption of steady state, the Dansgaard-Johnsen flow model was employed to date the core. The volcanic eruptive sequence established for the South Shetland Islands region since AD 1650 shows seven volcanic eruptive cycles during the past 340 years covered by the ice core. It seems that during the period 1875-1925 there was frequent volcanic activity, with perhaps many eruptions at Deception Island. The years 1650-1800 appear to have been a quiet period, followed by a more turbulent century. The past century is basically a tranquil era except for two turbulent epochs at the beginning of the century and in the 1950s-70s.

Many of the volcanic eruptions in the ice-core sequence are found in the previously reported records for this region. The few that are not in the records should be further investigated. The absence of any 1967-70 eruption trace in the core suggests that this period may represent a minimum in volcanic activity.

A deep ice core drilled to 2503 m depth at Dome Fuji, Antarctica, contains 25 visible tephra layers during the past 340 ka. The thickness of tephra layers is in the range 1-24 mm. The thickness and duration at deposition, determined by a simple ice-flow model, suggests that a violent volcanic eruption caused ash to fall onto the Antarctic ice sheet for ~5 years and to form a ~100 mm thick tephra layer at 117 ka BE Two tephra layers at depths of 573 and 2202 m probably originated from volcanoes in the South Sandwich Islands, Southern Ocean, given the size of tephra shards, >20μm in diameter, and their major chemical composition. Only eight of the 25 tephra layers can also be recognized in the Vostok (Antarctica) ice core, but all correspond to the Vostok tephras if we consider cloudy bands to be volcanic.

Knowledge of permafrost characteristics and distribution in Antarctica and their relationships with present and past climates is still poor. This paper reports investigations on permafrost in an area located between Nansen Ice Sheet to the south and Mount Melbourne (2732 m a.s.l.) to the north. Investigation methods included geomorphological surveys and geoelectrical soundings as well as crystallography, chemical and isotopic analyses of the ground ice. Geomorphological surveys helped to explain the relationships between periglacial landforms (e.g. rock glaciers and patterned ground) and the glacial history of the area. Geoelectrical soundings allowed us to define different ground-ice units in the ice-free areas. Each unit was characterised by a different type of permafrost (dry or ice-poor permafrost, marine or continental massive buried ice and sub-sea permafrost). To identify the nature of ground ice, trenches were dug and some shallow boreholes were drilled to a maximum depth of-3.6 m in massive buried ice. Samples of both ice-poor permafrost and massive ice were collected and analyzed. Chemical, isotopic δ18O and crystal analyses were also carried out. The relationships between climate and thermal regimes of the active layer and the upper part of permafrost were determined using a monitoring station for ground temperatures at Boulder Clay Glacier, near the Italian Antarctic station. During winter, there were several significant thermal-inversion events in the ground, which cannot be explained only by air-temperature changes, suggesting a possible influence of winter snowfall, even if these events are usually considered very rare.

A 36C1 peak has been found at about 37 ka BP in the Guliya ice core, drilled from the Qinghai-Tibetan Plateau. This peak is indicative of enhanced cosmogenic isotope production in the atmosphere, rather than a change in accumulation rate. Comparison with the records of 10Be and 36C1 in ice cores from Antarctica and Greenland indicates that peaks of the cosmogenic isotopes are global, and that they can be used as time markers for dating ice cores. Interestingly, the 37 ka BP global event coincided with a cold period.

Firn temperatures at the Dome Summit South drill site, East Antarctica, are simulated by driving a thermal model of the ice sheet with observed instrumental records over the period 1960-96. The model incorporates firn density and thermal properties to reproduce measured borehole temperatures as shallow as 5 m below the surface, where the seasonal temperature wave is readily apparent. The study shows that ice-sheet temperatures are approximately 0.8°C cooler than mean 4 m air temperatures. It also finds that non-conductive processes such as ventilation and radiation can be simulated at this site by assuming perfect thermal contact between the top ∼1 m of firn and the atmosphere on monthly time-scales.

The temperature profile in the 1200 m deep Dome Summit South (DSS) borehole near the summit of Law Dome, Antarctica, was measured in 1996, 3 years after the termination of the deep drilling.

The temperature profile contains information on past surface temperature over the last 4ka. This temperature history is determined by the use of a Monte Carlo inverse method in which no constraints are placed on the unknown temperature history and no solution is assumed to be unique. The temperature history is obtained from a selection of equally well-fitting solutions by a statistical treatment.

The results show that solutions covering the last 4ka have a well-developed central value, a most likely temperature history. The temperature record has two well-developed minima at AD 1250 and 1850. From 1850 to the present, temperatures have gradually increased by 0.7 K. The reconstructed temperatures are compared with the stable oxygen isotope (δ18O) from the DSS ice core.

An apparatus is described for measuring the thermal conductivity of ice by the transient hot-wire method. Thermal conductivity A, is determined by tracking the thermal pulse induced in the sample by a heating source consisting of a platinum resistor. A central segment of the same platinum heating resistor acts also as a thermal sensor. A heat pulse transferred to the ice for a period of 40s gives a maximum temperature increment of about 7-14°C. In good experimental conditions, the expected reproducibility of the measurements is within ±3%. The accuracy of the method depends on whether the instrument has been calibrated by reliable standard samples, certified by absolute methods.

An automatic ice-fabric analyzer has been developed, which can determine individual ,-axis orientations by image-analysis techniques. The analyzer consists of four major components: a sample stage, a pair of crossed polaroids, a charge coupled device (CCD) camera and a light source. Both the sample stage and the crossed polaroids can be rotated independently of each other by the stepping motors controlled by a personal computer (PC). Measurements are conducted as follows. An ice thin section is set on the sample stage and then the crossed polaroids are rotated. Thin-section images are recorded by the PC at intervals of 2° of rotation. From the image-intensity (gray value) dataset of each crystal in the thin section the extinction angles of individual crystals can be determined. Similarly, eight other extinction angles of individual crystals are obtained from eight other CCD camera positions with respect to the thin section: Finally, the .-axis orientation of individual crystals is calculated by using these extinction angles. With this technique, all crystals within the view of the CCD camera can be analyzed at the same time. In addition, with image-processing techniques the individual crystals are recognized automatically and other parameters, such as grain-size and grain shape, can be measured simultaneously. Textural studies of Dome Fuji (Antarctica) ice cores have been conducted with this analyzer.

A comprehensive study of ice-crystal fabrics and textures was conducted on the Dome F (Antarctica) ice core. Crystal ,-axis orientations, crystal sizes and crystal shape were measured on thin sections with an automatic ice-fabric analyzer. The general feature of textural and fabric development through a 2500 m long core was obtained by a 20 m interval study. Crystal size steadily increases with depth except for depths of about 500,1800, 2000, 2200 and 2300 m, at which depths crystal size decreases suddenly. There is a clear correlation between crystal-size and ´18O values. Crystals tend to elongate horizontally with depth, and the aspect ratio (long axis vs short axis of a grain) increases twofold at 1600 m depth and fluctuates below that depth. The .-axis orientation fabrics gradually change with depth from a random orientation pattern near the surface to a strong vertical single maximum at 2500 m. These are very similar to those from the GRIP (Greenland) core The observations of crystal shape and the fabric measurements indicate that nucleation-recrystallization does not take place at Dome F.

Crystal growth in firn and shallow ice is studied by examining crystal size and ,c-axis orientation fabrics in two ice cores drilled at sites Dome Summit South and DE08, near the summit of Law Dome, East Antarctica. The snow-accumulation rates at the core sites are particularly high (640 and 1160 kg m−2 a−1, respectively) compared to other Antarctic sites. Crystal-growth rates above the firn/ice transition depth (at 70-80 m) are found to be in agreement with the generally used growth-rate-temperature relation (Stephenson, 1967; Gow, 1969), sometimes referred to as "normal grain growth". In the shallow ice layers below this depth and down to about 300 m, the observed crystal-growth rates are enhanced compared to normal grain growth. Also in this shallow ice, crystal ,c-axis orientation measurements show development of anisotropic fabrics indicative of ice flow at strains well above 1%.

In earlier work, Jacka and Li (1994) described the development in clean ice of steady-state ice-crystal size (inversely proportional to the stress and largely independent of temperature) during the onset of flow-related crystal anisotropy, i.e. dynamic recrystallisation. It is concluded here that as a consequence of the high accumulation rates, relatively high deformation rates are generated in the shallow ice. The deformation rates are sufficiently high that "dynamic recrystallisation" takes over from "normal crystal growth" as the dominant crystal-growth mechanism. This leads to a rapid increase in crystal size from the slow-growing small firn crystals towards the larger size appropriate to the stress.

The Antarctic ice sheet preserves paleoclimate information in the form of physical and chemical stratigraphy. A deep ice core down to 2503 m depth was drilled at Dome Fuji station, East Antarctica, during the 1993-96 Japanese Antarctic Research Expedition inland operations. Oxygen isotope measurements were conducted on 50 cm long samples selected from the entire core length. A palco-temperature profile was obtained for the past 340 ka by assuming the same conversion factors for the past relation as exist today between isotope ratio and both surface temperature and accumulation rate, in the inland region of Dronning Maud Land. The environmental-index profiles such as major chemical and dust contents coincide quite well withVostok ice-core data in general but not in detail. Detailed analysis of these climatic and environmental signals is in progress.

Uniaxial compression tests were performed on samples of the Greenland Ice Gore Project (GRIP) deep ice core, both in the field and later in a cold-room laboratory, in order to understand the ice-flow behavior of large ice sheets. Experiments were conducted under conditions of constant strain rate (type A) and constant load (type B). Fifty-four uniaxial-compression test specimens from 1327-2922 m were selected. Each test specimen (25 mm x 25 mm x 90 mm) was prepared with its uniaxial stress axis inclined 45° from the core axis in order to examine the flow behavior of strong single-maximum ice-core samples with basal planes parallel to the horizontal plane of the ice sheet. The ice-flow enhancement factors show a gradual increase with depth down to approximately 2000 m. These results can be interpreted in terms of an increase in the fourth-order Schmid factor. Below 2000 m depth, the flow-enhancement factor increases to about 20-30 with a relatively high variability When the Schmid factor was > 0.46, the enhancement factor obtained was higher than expected from the .-axis concentrations measured. The higher values of flow-enhancement factor were obtained from specimens with a cloudy band structure. It was revealed that cloudy bands affect ice-deformation processes, but the details remain unclear.

A model for ice flow in a polar ice sheet is presented. It is based on laboratory measurements of ice rheology, and includes the effect of anisotropic-flow enhancement in tertiary creep as the ice progresses through a range of stress regimes as it passes through the ice sheet. This flow model is applied to the transect from the summit of Law Dome, East Antarctica, to Gape Folger. In the upper layers of the ice sheet good agreement is found between the shear strain-rate profiles from the model and borehole-inclination measurements. Modifications of the simple model predictions for high shear strain rates in the lower layers of the ice cap are required in order to match the observed surface velocities. In these lower regions reductions in both the enhancement of shear flow and shear stress appear to be required, and this suggests that more attention needs to be given to the dynaimcs deep within ice sheets.

A recently developed theory of post-nucleation conversion of an air bubble to air-hydrate crystal in ice is applied to simulate two different types of air-hydrate formation in polar ice sheets. The work is focused on interpretation of the Vostok (Antarctica) ice-core data. The hydrostatic compression of bubbles is the rate-limiting step of the phase transformation which is additionally influenced by selective diffusion of the gas components from neighboring air bubbles. The latter process leads to the gas fractionation resulting in lower (higher) N2/O2 ratios in air hydrates (coexisting bubbles) with respect to atmospheric air. The typical time of the post-nucleation conversion decreases at Vostok from 1300-200 a at the beginning to 50-3 a at the end of the transition zone. The model of the diffusive transport of the air constituents from air bubbles to hydrate crystals is constrained by the data of Raman spectra measurements. The oxygen and nitrogen self-diffusion (permeation) coefficients in ice are determined at 220 K as 4.5 × 10−8 and 9.5 × 10−8 mm2 a−1, respectively while the activation energy is estimated to be about 50 kJ mol−1. The gas-fractionation time-scale at Vostok, τF ∼300 a, appears to be two orders of magnitude less than the typical time of the air-hydrate nucleation, τz ∼30-35 ka, and thus the condition for the extreme gas fractionation, τF ≪ τz is satisfied. Application of the theory to the GRIP and GISP2 ice cores shows that on average, a significant gas fractionation cannot be expected for air hydrates in central Greenland. However, a noticeable (statistically valid) nitrogen enrichment might be observed in the last air bubbles at the end of the transition.

The results of ground-based radio-echo sounding collected in 1995 and 1996-97 in the drainage basin of Lange Glacier, a tidewater outlet glacier on King George Island, Antarctica, are presented and discussed. Ice-thickness and bedrock-elevation maps, constructed for the upper non-crevassed part of the glacier, show a close relation between its surface and subglacial topography and indicate the main directions of ice runoff from this area where the ice thickness reaches 308 m. A retreat of the glacier front by 1 km since 1956 occurred against a background of climate warming by 1.4°C on the South Shetland Islands during the last five decades, while a neighboring unnamed glacier advanced by 0.6 km and the northern ice-cap margin on King George Island was approximately stationary. To understand the reasons for the different responses of these ice masses to current climate warming in this region of West Antarctica, further studies including mass-balance and ice-velocity observations and numerical modeling are needed.

Air bubbles trapped near the surface of an ice sheet are transformed into air hydrates below a certain depth Their volume and number varies partly with environment and climate. Air bubbles and hydrates at 120-2200 m depth in the Dome Fuji (Dome F) ice core were examined with a microscope. This depth range covers the Holocene/Last Glacial/Last Interglacial/Previous Glacial periods. No air bubbles were seen below about 1100 m depth, and air hydrates began to appear from about 600 m. The observed number of air bubbles and hydrates was similar to that found in the Vostok ice core. For the ice covering the Last Glacial Maximum period, however the hydrate concentration in the Dome F core is about half that of the Vostok core. Reference to snow metamorphism and packing does not explain this finding.

An X-ray transmission method has been developed to obtain a continuous profile of bulk densities of ice cores. Intensities of X-rays transmitted through an ice-core sample were continuously measured by an X-ray detector during translation of the sample across the X-ray beam. A thick section of an ice core with a constant thickness was prepared by band-sawing followed by microtome planing. The X-ray intensity profile obtained was converted to a density profile using a calibration curve for X-ray absorption vs ice thickness. Using this method, spatial resolution of the density profile was down to 1 mm. X-ray radiographs were also taken on a two-dimensional detector imaging plate, in order to observe layer structures of the ice cores.

The method was applied to Dome Fuji (Antarctica) ice cores from the surface to 110 m depth. From the density profile obtained we calculated the power spectrum of the density variation by the discrete Fourier transform, and obtained several peaks at different frequencies. The center period in the spectrum was close to the annual accumulation thickness at the drill site.

A 181 m long ice core was drilled at 79°36’51"S, 45°43’28" W, near the summit of Berkner Island, Antarctica (886 m a.s.L). Berkner Island is located between the Filchner and Ronne Ice Shelves, and the ice near the summit shows little lateral flow. The density of the ice core was measured every 3 mm along its length, using attenuation of a gamma-ray beam, which gave an absolute accuracy of 2%. As expected, there is a general density increase with depth, the maximum densities of > 900 kg m−3 being reached just above 100 m depth. Comparison with the electrical conductivity method (ECM) shows density variations with the same wavelength as the annual signals, which can be seen in the ECM log (higher acidity during summer). In the shallowest part of the core, the density of winter layers is higher than that of summer layers, a relationship which is reversed at greater depth. We assume that the densification rates for the two types of firn are different. Similar density phenomena were observed on ice cores from Greenland, showing that such phenomena are not a local effect.

A Système probatoire pour l’observation de la terre (SPOT) mosaic of King George Island, the largest (1250 Km2) of the South Shetland Islands, West Antarctica, shows its major morphological features. Three main ice domes and 70 glacier drainage basins, covering 92.7% of the King George Island area, strongly controlled by the subglacial morphology and drained by relatively fast-moving tidewater outlet glaciers, were delineated. A general retreat of ice fronts through four decades, more intensely on the eastern side of the island (to the Bransfield Strait), resulted in the loss of about 7% of the glacial cover area. Superficial snow fades were derived from SPOT multispectral imagery and, together with field observations, allowed the transient-snowline elevation to be obtained The latter is estimated to have risen from about 200-250 m in the mid-1950s to 300-350 m by 1988. Spot radio-echo sounding surveys give an overview of the bedrock morphology.