In a previous paper, we used powder X-ray diffraction and changes in magnetic susceptibility to argue the importance of pedogenic maghemite to soils and the efficacy of the chemical extractant citrate-bicarbonate-dithionite (CBD) to preferentially remove pedogenic maghemite from soil samples while not removing coarse-grained magnetite. Although X-ray diffraction provides strong support for this contention, Mössbauer spectroscopy is the method of choice for determining the oxidation state of iron in minerals and for inferring mineralogy of the iron oxide phases. Our objective in this work was to seek confirming evidence of the importance of maghemite as a pedogenic mineral and the usefulness of the CBD procedure in separating pedogenic maghemite from lithogenic magnetite. We present Mössbauer data on magnetic fractions from pre- and post-CBD treated soil samples. Six of the 10 samples had only maghemite as the sextet component and after CBD treatment, four lost between 96 and 100% of the magnetic susceptibility. Two samples were interpreted as highly oxidized magnetite or a mixture of magnetite and maghemite. We cannot distinguish between these with Mössbauer spectroscopy. In the remaining two samples, iron existed as hematite, ilmenite, magnetite and minor (<10%) amounts of maghemite. Our results provide additional support for pedogenic maghemite in soils and for the preferential removal of maghemite by the CBD procedure.

Several aspects of the personality, thought and work of Don Vasco de Quiroga are known today, but a deeper awareness of his legal thinking would enable us to understand better the motives for his actions in New Spain and the Michoacán region. In order to do this we need to place him in the conceptual, institutional and legal context in which he was educated and where he developed throughout his life. Well versed in the different legal systems in use at the time, he absorbed Roman laws, which he respected as the work of esteemed scholars, while at the same time basing his evangelical mission in Mexico on the canons of the Church. And the legal system that was to govern the villages he created according to a new model would be based on custom coming from the grassroots.

The human animal feels fear: the ancient tranquil hordes, inhabitants of infinite plains where time stood still, have dissolved into a swarming, formless mass rushing into the future as if into the void: without a plan, without a leader, without roots; perhaps the only thing that guides it is the vague feeling of being a body whose limbs can not survive if separated.

The acid hydrolysis products of trioctahedral fluorohectorite and phlogopite have been investigated by XRD, MAS NMR spectroscopy and nitrogen BET surface area analysis in an effort to assess the relative importance of edge attack and gallery access mechanisms. A dramatic loss of X-ray crystallinity and the formation of Q3 and Q4 SiO4 sites accompanied the depletion of Mg2+ from the octahedral sheet of both 2:1 layered structures. Depending on the extent of hydrolysis, the products derived from fluorohectorite exhibited surface areas up to 208 m2/g, whereas phlogopite hydrolysis products gave values <20 m2/g. The dramatic differences in surface areas were not related to differences in hydrolysis mechanisms. 19F MAS NMR studies indicated that the hydrolysis of fluorohectorite occurred primarily by an edge attack mechanism equivalent to the hydrolysis pathway for phlogopite. A gallery access mechanism contributed to the hydrolysis of fluorohectorite only at the later stages of octahedral Mg2+ depletion. Solvation effects appeared to be important in determining the surface areas of the reaction products derived from the swelling (fluorohectorite) and non-swelling (phlogopite) precursors.

On my first visit to England, nearly twenty years ago, I experienced a poignant moment of realization, understanding finally why Europeans called Japan a “Far Eastern country,” for it was then that I first saw a Europe-centered world map: Japan really was a small fringe of islands off at the far right edge of the map, in the “Far Eastern” region, from a European point of view.

We investigated the crystallization of ferrihydrite prepared by hydrolysis of Fe(NO3)3 solutions containing phosphate. Crystallization was studied at different pH (3–9), temperatures (298, 323, and 373 K), and initial P/Fe atomic ratios for periods to 730 d. Generally, crystallization was inhibited or only poorly crystallized lepidocrocite was formed at P/Fe > 2.5%. Phosphate favored the formation of hematite over goethite at all temperatures for most of the pH and P/Fe ranges investigated. This result is consistent with a model in which phosphate acts as a template for hematite formation, in analogy with other anions, such as oxalate. However, goethite was preferentially formed at alkaline pH and P/Fe > 1%, probably because high phosphate concentration resulted in a large increase in the negative charge of the ferrihydrite particles. This resulted in turn in less aggregation, a process that is known to precede dehydration to hematite. Phosphate greatly influenced the morphology of hematite and goethite. Hematite was often ellipsoidal or spindle-shaped. Twinned goethite crystals with a hematite core were formed at alkaline pH at P/Fe > 1%. Both hematite and goethite particles incorporated phosphate in an occluded form not desorbable by repeated alkali treatments.

Lode, a dioctahedral illite-rich clay from Latvia belonging to the mica group of clay minerals, undergoes thermal transformation via a series of structurally disordered intermediate phases. Despite containing high levels of paramagnetic Fe substituted into the octahedral sites, 29Si and 27Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectra of sufficient quality are obtained to resolve different structural units, showing clearly defined structural changes which occur in the sample during calcination to 1200 °C. However, Fe plays a significant role in broadening the Al signal, with integrated peak intensities decreasing as temperature increases. Significant differences are revealed in the thermal decomposition process by NMR spectra between pyrophyllite, Ca-montmorillonite and illite clays, possibly due to the different cations present in the interlayer. It has also been shown for illite that no structural differences at the atomic level occur when the dwell time at a particular temperature is varied and no difference is observed between samples that have different thermal histories; however, a minor effect of particle size and surface area is visible in the NMR data.

A reservoir rock is a porous geological formation in contact with 2 liquids, brine and oil. An improved knowledge of rock wettability is of primary importance to estimate the amount of crude oil in underground resources. The petroleum industries have observed that wettability contrasts in sedimentary reservoir rocks are largely correlated to the presence of clays, illite and/or kaolinite in the rocks’ intergranular space.

More precisely, the grain surfaces of illite show a preference for brine. Kaolinite preferentially adsorbs oil, which imparts its hydrophobic characteristics to the mineral surface. Using X-ray absorption spectroscopy (XAS) and Fourier transform infrared (FTIR) spectroscopy, we studied the adsorption process of asphaltenes in the presence of water at the microscopic level. We demonstrate experimentally that the wettability contrasts observed in kaolinite and illite are related to structural differences between these 2 clays, and we show the role of the grain surface hydroxyls. With clay materials, the purity of the samples is the most important limitation of the quantitative use of extended X-ray absorption fine structure (EXAFS).

The internal equilibrium status among chlorite-illite pairs has been evaluated through coupled substitution reactions. Compositional data of chlorites and illites from arenites at present burial temperatures between 90° and 180°C have been used to calculate end member activities and reaction quotients of the combined Tschermak reaction:

$Muscovite+Clinochlore=MgAl-celadonite+Amesite.$

The reaction quotient data in the 90° to 180°C temperature range have then been compared with the equilibrium curve for the same reaction, and found to be in reasonable agreement. This indicates that chlorites and illites in these arenites grow at near equilibrium conditions.

The data set has also been compared with chlorite-illite pairs from hydrothermally altered arenites of the Salton Sea area. For chlorite-illite containing assemblages, these data agree well with the diagenetic ones. The introduction of biotite at higher temperatures alters with the iron-magnesium distribution and breaks down the substitution relationship between chlorite and illite.

The model predicts an increasing stability of muscovite and clinochlore components with increasing temperature, while celadonite and amesite would be stabilized with increasing pressure. This is consistent with high pressure occurrences of phengite. However, at the low pressure region of diagenesis and hydrothermal alteration, the temperature effect is dominant.

An oasis of authorized criticism in the 1960s and the 1970s, and a privileged public arena for ‘extreme non-conformist’ intellectuals in the same period, ecology was also the matrix for the national movements which precipitated the end of the decaying party-state at the end of the 1980s and which had been in gestation since the late 1960s. Ideal metaphor for the fall of a system emblematized by the catastrophe at Chernobyl (April 1986), the ecological crisis - the crisis in the relationship between nature and urban space - made it possible to understand the full extent of the post-war upheavals that had taken place at the heart of Soviet society. The rapid, huge-scale industrialization and urbanization of the country had produced a new educated middle class of ‘specialists’ (technicians, engineers, applied research managers, economists and administrators, and so on), which in the early 1960s constituted the hard core of the first generation of Soviets to be a majority of urban-dwellers. If it was not embodied, as in Western countries, in political movements or parties, the ecological cause was no less institutionalized. The horticultural societies (tovariscestva) on the edge of towns (ogorodniki), the ‘nature protection brigades’ which organized reafforestation campaigns (DOP), the Society for the Protection of Nature (VOOP), or local historical and ethnographical societies (kraevedenie) had a considerable number of supporters. It allowed the expression of a very extensive range of individual and collective sentiments, and of reactions both rejecting and adapting to a radically new natural, social and cultural environment - that of the town and a larger community. For a disorientated society, it was a question of re-appropriating its immediate, daily environment, of attempting to impose, individually or collectively, meaning on its existence and its social trajectory. Ecological sentiment was thus intimately bound up with the emergence of an ‘urban civilization’ in the Soviet Union under Brezhnev.

The crystal structure of cronstedtite-3T from Kutná Hora (Bohemia, Czechoslovakia), space group P31, was refined to Rw(all) = 3.1% for 1336 independent diffractions. There are two and three independent tetrahedral and octahedral positions, respectively, in this structure. The tetrahedra are occupied by 0.75 Si and 0.25 Fe while the octahedra are uniformly occupied by Fe. The refinement process was hindered by two problems: a “strong” superposition structure (all atoms of the octahedral sheets, i.e., ÷ 70% of the total diffraction power contribute almost solely to the family diffractions with mod(h–k, 3) = 0), and a slight disorder of the investigated crystal. The first problem was resolved by a preliminary block-diagonal refinement procedure where the atoms coinciding in the superposition structure were separated into individual blocks. The second problem was resolved by including two scale factors into the final full-matrix refinement: one for family diffractions, the other for the remaining ones which are characteristic for this polytype.

In this paper, we prove the nonvanishing and some special cases of the abundance for log canonical threefold pairs over an algebraically closed field k of characteristic $p> 3$. More precisely, we prove that if $(X,B)$ be a projective log canonical threefold pair over k and $K_{X}+B$ is pseudo-effective, then $\kappa (K_{X}+B)\geq 0$, and if $K_{X}+B$ is nef and $\kappa (K_{X}+B)\geq 1$, then $K_{X}+B$ is semi-ample.

As applications, we show that the log canonical rings of projective log canonical threefold pairs over k are finitely generated and the abundance holds when the nef dimension $n(K_{X}+B)\leq 2$ or when the Albanese map $a_{X}:X\to \mathrm {Alb}(X)$ is nontrivial. Moreover, we prove that the abundance for klt threefold pairs over k implies the abundance for log canonical threefold pairs over k.

The crystal structure of Keokuk kaolinite, including all H atoms, was refined in space group C1 using low-temperature (1.5 K) neutron powder diffraction data (λ = 1.9102 Å) and Rietveld refinement/difference-Fourier methods to Rwp = 1.78%, reduced χ2 = 3.32. Unit-cell parameters are: a = 5.1535(3) Å, b = 8.9419(5) Å, c = 7.3906(4) Å, α = 91.926(2)°, β = 105.046(2)°, γ = 89.797(2)°, and V = 328.70(5) Å3. Unit-cell parameters show that most of the thermal contraction occurred along the [001] direction, apparently due to a decrease in the interlayer distance. The non-H structure is very similar to published C1 structures, considering the low temperature of data collection, but the H atom positions are distinct. The inner OH group is essentially in the plane of the layers, and the inner-surface OH groups make angles of 60°–73° with the (001) plane. Difference-Fourier maps show minor anisotropy of the inner-OH group in the [001] direction, but the inner-surface OH groups appear to have their largest vibrational (or positional disorder) component parallel to the layers. Although no data indicate a split position of any of the H sites in kaolinite, there is support for limited random positional disorder of the H atoms. However, these data provided no support for a space group symmetry lower than C1.

Three ball clays (SP from England, TSMA from France and UK from the Ukraine) were characterized for their dry and wet colloidal properties. On the basis of X-ray diffraction and chemical analyses the clays were classified as kaolinite-rich clay, smectitic kaolinite-rich clay and illitic kaolinite-rich clay. The ζ (zeta) potential at the clay-water interface as a function of pH, in three different electrolytes, was investigated using an electroacoustic technique. Starting from measurements of dynamic mobility, the calculated ζ potential was found to be almost constant as a function of pH for the TSMA and UK clays, while it increased from −20 to −60 for the SP clay, when potassium nitrate was used as an electrolyte. The behavior of the three clays in calcium and magnesium nitrate was slightly different: SP showed a smaller increase in ζ potential, while a small deviation from the constant behavior of the UK clay was found. The results are explained in terms of the surrounding-ion atmosphere in light of the chemical-physical properties measured. Our results may well be of use to those involved in ceramic processing.

During the past decades, the deaf in the United States, as well as those in other countries, have been trying to define themselves within society. They constitute, indeed, a “different” population group, insofar as they are “disabled,” and they also have their own language that they utilize for interpersonal communication. So, as a group, they are called “a group of disabled individuals,” “a distinct Deaf Culture,” “a linguistic minority,” “a society,” “a community,” “a sub-culture,” etc.

This title is playful, of course. It is designed merely to attract curiosity and attention … It dates back to a childhood game of which I have forgotten both rules and stakes. An imaginary sovereign was roused from his indifference and responded with an approximate repetition of Marie-Antoinette's suggestion that if the people were hungry, food should be thrown to them. I took such caricatures of kings as anti-models, replacing bread with symbols. Now we are all too disturbed, individually and collectively, by the economic discomfort which is a generalized hunger and, in too many parts of the world and - not only in the third world - by actual famines, not to be aware, on a daily basis, of the responsibility it is to cultivate and transmit to others substance which is purely symbolic. Certain statistics, which now form part of our daily life, are capable of discrediting definitively the ivory tower which our universities are accused of representing, or of having represented in the past. In my own country, Canada, one child in five lives in poverty. The economic worth of the poorest forty-eight countries in the world is equal to the combined wealth of the ten richest individuals. There were twenty million refugees in 1997. One billion two hundred million human beings are short of fresh water this year, etc. This type of figure is, sadly, all too familiar. And it is a case of preaching to the converted to assert the extent to which culture, education and all their constituent disciplines are nourishment of a different order to physical food, because intellectual work is genuine work, providing a living for those who work at it professionally, and above all also those who benefit from its immediate and continuing fruits - i.e. ideally, the whole of society, and in all countries. In this respect - and this is implicit, but through depending habitually on what is implicit nothing is ever sufficiently explicit - it is generally acknowledged (thanks to UNESCO in particular) to what extent the development of economic resources is linked with the advancement and communication of knowledge, on a scale which is regional as well as national, within cities, rural communities, families.

The boundary between diagenesis and metamorphism most likely involves the change of illite into mica. Observations of this change can be made using decomposed X-ray diffraction (XRD) spectra of illitic clay mineral assemblages in pelitic sedimentary rocks.

XRD analysis of the (003) diffraction peak of diagenetic illites indicates that there are 2 components, one of small coherent diffraction domains and another of larger domain size. Peak width, shape and position define these fractions. The smaller domain size material in diagenetic rocks is highly illitic (>95%) but contains some smectite layers and can be best described by Gaussian shapes. The grains with larger diffracting domains show no expanding layers.

Metamorphic illites (probably muscovites) show no smectite interlayers in any fraction. In the transition from sedimentary and diagenetic to metamorphic illites, new grains of smectite-free illite are formed at the expense of the older minerals. This suggests that the new metamorphic minerals are recrystallized phases. Metamorphism of illites then produces new mica phases.

Experimental alterations of K-feldspar in distilled-deionized water at 150°, 175°, 200°, and 225°C were performed. The alteration products and dissolution mechanism of K-feldspar were examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX), and X-ray photoelectron spectroscopy (XPS). SEM, TEM, and EDX clearly showed formation of fibrous boehmite less than 1.0 μm in length at the early alteration stages. The boehmite fibers decreased in abundance and rounded platy 1 M mica was produced as alteration proceeded. The mica exhibited initially angular shaped small flakes of 0.69 μm in average size, which developed to rounded platy particles of 1.97 μm. The main chemical reactions occurring in this experimental system can be expressed by: $$\begin{array}{l} \mathop {KAlS{i_3}{O_3}}\limits_{\left[ {K - feldspar} \right]} + 6{H_2}O + {H^ + } \to \mathop {AlO\left( {OH} \right)}\limits_{\left[ {boehmite} \right]} + 3{H_4}Si{O_4} + {K^ + }, \\ \mathop {3KAlS{i_3}{O_8}}\limits_{\left[ {K - feldspar} \right]} + 12{H_2}O \to \mathop {KA{l_3}S{i_3}{O_{10}}{{\left( {OH} \right)}_2}}\limits_{\left[ {mica} \right]} + 2{K^ + } + 6{H_4}Si{O_4} + 22{H^ + }. \\ \end{array}$$ XPS showed no significant changes in intensities of photoelectron lines excited from K, Si, and Al in the K-feldspar surface before and after alteration, however the K/Si molar ratios in the solutions were considerably smaller than that of the original K-feldspar. The results of XPS strongly indicate that no dealkalized layer was produced on the surface, and that dissolution of K-feldspar in aqueous solution proceeded congruently by a surface-reaction mechanism. The discrepancy of mass balance in the solutions may be mainly caused by adsorption of K on the surface of boehmite.