Kûngnât Fjeld is an intrusive complex resulting from three intrusive events involving trachyte, mafic trachyte and hawaiite magmas tapped successively from a single magmatic source. In situ differentiation produced gabbroic, syeno-gabbroic, syenitic, and quartz syenitic cumulates showing strong cryptic variation. Layered sequences of syenitic rocks total c. 3500 m. The compositional range is extended by late-stage minor intrusions of microsyenite and peralkaline granite. The principal cumulus minerals are feldspar (Ab40An60 to Or45Ab51An4); olivine (Fo56 to Fo1) and clinopyroxene (Di70Hd27Ac3 to Di6Hd90Ac4 followed by an abrupt change of trend towards Di3Hd78Ac19 in the layered series and nearly pure aegirine in some peralkaline residues). Intercumulus phases are amphibole (hastingsite to ferro-edenite to ferro-actinolite in the layered series with riebeckite to arfvedsonite in some associated granites) and biotite (annite31 to annite98.5).

The Cadomian igneous complex of N. Guernsey includes gabbro, diorite, granodiorite, and adamellite. The gabbro is layered, shows variations in colour index and texture, contains abundant amphibole, and is cut by the diorites. The diorites show little variation in mineral compositions despite considerable variation in modal proportions. They contain numerous thin and roughly parallel veins of leucodiorite and granodiorite, and layers of meladiorite occur in several places within the veined diorites. These meladiorites, previously interpreted as separate intrusions, form individual layers from a few centimetres to several metres thick which can be traced for some tens of metres along strike. The upper surfaces of the meladiorites are planar but the lower tend to be indented and irregular. The layers thin out laterally and usually pass into the host diorite by way of a zone containing dark spots and both the spots and the meladiorite layers are composed of actinolitic hornblende and Mg-biotite.

Chemical and petrographic data are presented for most of the rocks and minerals especially for the meladiorites and their host, the veined diorites. The rock chemistry and particularly the compositions of the amphiboles and micas of the meladiorites and the mafic spots, taken together with the presence of unmixing lamellae in the amphibole and the details of the field relationships, indicate that the rocks tended to equilibrium under subsolidus conditions and are most probably of metasomatic origin.

Acid pipes and pegmatites occur within and are restricted to the meladiorites. The forms of the pipes were previously taken to indicate that they were magmatic at the same time as the meladiorites. The metasomatic origin for the meladiorites proposed here calls into question this magmatic interpretation and it is suggested that the pipe formation is connected with the metasomatic process. It is envisaged that the alteration of the veined diorites took place under conditions in which high gas pressures allowed acidic melt to be produced at temperatures only a little above the solidus of the diorites. The thermal impulse for this recrystallization may have resulted from the polyphase intrusive history of the complex as a whole.

Cr-rich Mg-sapphirines, which are more aluminous in composition than R2+:R3+:Si of 7:9:3 and are therefore considered to be peraluminous, are shown to have an inverse linear relationship between octahedrally co-ordinated Cr and Al. This balanced substitution, which has not previously been described, may be used to explain the major chemical variations exhibited in the described minerals. Since the peraluminous Cr-rich sapphirines are idioblastic it is suggested that they are stable members of the assemblages within which they occur. Peraluminous sapphirine is usually considered to be metastable but in this instance it is possible that chromium may assist in stabilizing its development.

Scattered dunite and lherzolite nodules occur in one of the youngest basanitoid lavas on Ubekendt Ejland. They have protogranular to porphyroclastic textures. The dunites are composed of olivine (Fo93.2−91.9b), enstatite (En93.4−92.8) low in Al2O3 and CaO, and Cr-spinel (61-13% Cr2O3 and 3–55% Al2O3). A solitary lherzolite module has olivine (Fo94.7–94.1), enstatite (En94.7–94.2), Cr-rich spinel, Ti-phlogopite (11% TiO2), and hyalophane. Petrographic evidence suggests that the two latter minerals have not been introduced by magmatic injection from the host in spite of the refractory nature of the coexisting phases, and metasomatic processes prior to the last deformation are therefore indicated. Partial melting of such mantle material would presumably produce small amounts of alkaline liquids even at very high temperatures. Another lherzolite nodule from a lamprophyre dyke has minerals with lower Mg/(Mg + Fe) ratios which, together with its preserved igneous textures, suggest a high-pressure precipitate. The lowest well-esablished equilibrium temperatures of 700–830°C for both dunites and lherzolites indicate a pressure regime of 12-17 kbar, according to the oceanic geotherm, whereas unrealistically high pressure (20–5 kbar) are suggested using the continental shield geotherm.

A Ca-poor rhodonite (CaO 1.31 wt.%), found in a quartz vein cutting manganese ore bodies, north of the Xanthi plutonic complex (northeastern Greece) was studied. Microprobe analyses with optical and physical properties are given. The cell dimensions, obtained by least squares calculation from direct θ value measurements on a Philips PW1100 single-crystal diffractometer are a = 7.626, b = 11.844, c = 6.702 Å, α = 92.44°, β = 94.28°, γ = 105.70°, V = 579.89 Å3, Z = 10, and space group P.

New chemical analyses of roeblingite from Franklin, New Jersey, and Långban, Sweden, are presented. The average composition of Franklin roeblingite is SiO2 24.9, CaO 23.8, SrO 2.4. MnO 2.4, PbO 30.2 SO3 10.4, H2O 6.13%, Sum = 100.23%. The data support space group C2/m and suggest the formula is (Ca,Sr)12 (Mn,Ca)2Pb4(SO4)4Si12O28(OH)20, if there is ordering on the site of rank 2.

The Bonser vein, one of the most productive sources of copper in the English Lake District, contains a mineral assemblage comprising quartz, chlorite, calcite, dolomite, stilpnomelane, magnetite, pyrrhotine, pyrite, marcasite, native bismuth, bismuthinite, laitakarite, joseite, arsenopyrite, chalcopyrite, sphalerite, galena, and cosalite. The phases pyrrhotine, sphalerite, arsenopyrite, laitakarite, joseite, and cosalite were analysed by electron microprobe. The occurrence of laitakarite is the first reported in the British Isles. Textures of the ore and gangue minerals show that the vein minerals were deposited successively in open voids. The sequence of deposition was of quartz forming throughout, early chlorite and stilpnomelane with some dolomite and calcite, magnetite as the earliest opaque phase, followed by arsenopyrite, pyrrhotine, sphalerite, chalcopyrite, pyrite, and marcasite; the bismuth- and lead-bearing minerals were the last to form.

The data on the coexisting phases and their compositions have been used to estimate the temperatures of mineralization and the activities of sulphur and oxygen. Magnetite and arsenopyrite appear to have formed at 350–400% with aS2 reaching 10−12 to 10−14 atm. and aO2 around 10−24 to 10−29 atm. The assemblage of quartz, chlorite, stilpnomelane, calcite, dolomite, pyrrhoine, chalcopyrite, sphalerite, and (late) arsenopyrite was probably deposited at ∼ 240°C, with aS2 decreasing to 10−15 to 10−16 atm and aO2 to 10−38) to 10{su−44 atm. The later minerals probably formed at temperatures as low as 200°C and under similar conditions of sulphur and oxygen activity.

Dwornikite, (Ni1−xFex)SO4 · H2O is a member of the kieserite group, monoclinic with space group C2/c. Specimens from Minasragra, Peru with x ∼ 0.1 have a unit cell with a = 6.839(2), b = 7.582(2), c = 7.474(2) Å, and β = 117.85(2)°. The six strongest lines of the powder pattern are: 3.342 (12, 100), 4.732 (110, 70), 3.024 (200, 70), 4.754 (11, 50), 3.293 (021, 35), 2.491 (022, 35). The mineral occurs as fine grained white aggregates associated with vanadium sulphide ores containing patronite and bravoite, mixed with other oxidation products. New unit cell data for the synthetic end-member compounds NiSO4 · H2O and FeSO4 · H2O, and new X-ray powder data for retgersite (NiSO4 · 6H2O) are provided.

The first occurrence of new mineral ardaite (a chlorine sulphosalt) has been discovered in the Madjarovo polymetallic ore deposit (Bulgaria). The average composition is Pb 56.50, Ag 0.04, Sb 22.48, S 15.56, Cl 3.78, total 98.36 wt.%. The formula is Pb20–18 Sb12–24S34–36.5Cl6–8. The mineral occurs as fine acicular aggregates associated with galena, nadorite, a Cl-bearing robinsonite and Cl-beating semseyite, pyrostilpnite, silver- bearing tetrahedrite and anglesite.

Found at a small prospect in the Artillery Peaks area, Arizona. Luddcnite occurs in oxidized Cu-Zn ores with fluorite, alamosite, and cerussite. Colour nickel green, H = 4, G meas. 4.45.

Strongest X-ray lines are 7.361(10), 3.173(10), 2.918(8), 5.218(7), 4.226(5), 3.411(5), 2.888(5), 3.650(4). A possible cell found by Ito method is a = 7.85, b = 20.06, c = 14.72 Å, β = 90.78° (monoclinic). Optically (+), α = 1.852, γ = 1.867.

Chemical analysis by wet methods gave CuO 13.2%, PbO 35.1, SiO2 25.7, H2O 20.5, TiO2 (leucoxene impurity) 4.7. Not all water need be essential, hence Cu2Pb2Si5 O14·nH2O. The new mineral and name have been approved in advance of publication by the Commission on New Minerals and New Mineral Names, IMA.

A chalky white, fibrous mineral, in the amygdales of Tertiary basalts from the Gobbins area, Co. Antrim, has been discovered to be a new mineral. It consists of fibrous dusters of lath-shaped crystals showing straight extinction with negative elongation. Its refractive index is ɛ 1.489, ω 1.494 (both ± 0.003) and specific gravity is 2.194 (meas.), 2.147 (calc.). The mineral is tetragonal with ɛ = c (elongation); a = 10.145, c = 9.788 Å. The strongest powder lines (in Å, intensity in brackets) are: 7.10, 4.10, 3.19(100); 3.10, 2.69(80); 5.07(50); 2.64(40). A spectrographic analysis shows major Si, Al, minor Ca, Na, Cu, and trace Fe. Two chemical and one probe analysis give the ideal formula Na4(Ca,Mg,K2)Al6Si10 O32.12H2O. The name gobbinsite (approved by the IMA Commission on New Mineral Names) is suggested after the locality. The type specimen (I7881) is preserved in the Ulster Museum.

Rotation and Weissenberg photographs of gobbinsite and garronite show doubled reflections, which are explained on the basis of submicroscopic twinning on (101). Relationship between gobbinsite and garronite is discussed and evidence is presented for the occurrence of minute amounts of a merlinoite-type mineral that forms regular intergrowths with gobbinsite and garronite.

Two palladium arsenide-antimonides have been found as small inclusions associated with native gold at Hope's Nose. One of the minerals has been identified as isomertieite; the other is chemically very similar to mertieite-II (Cabri et al., 1975). Electron probe microanalysis gives the formula of the isomertieite as (Pd10.89 Au0.08Cu0.03)Σ11.00(Sb2.01As1.99)Σ4.00 and of mertieite II as (Pd7.90Au0.07Cu0.01)Σ7.98(Sb2.43As0.59)Σ3.02. The relectance spectra of isomertieite in air and in oil at intervals of 10 nm from 400–700 nm are tabulated. The luminance values of the Hope's Nose isomertieite are 55.5 % in air and 42.5% in oil. The type specimen of isomertieite from Itabira, Minas Gerais, Brazil, has been re-examined; a new electron probe analysis is given and improved reflectance spectra are tabulated. The latter gives luminance values of 54.3% in air and 41.3% in oil.

The Vulsinian district is the largest and northernmost of the Roman Provinces. There is very little modern mineralogical data on the Italian Pliocene to Recent perpotassic alkaline volcanic rocks and this account deals with the compositions of the phenocrysts in the Vulsinian lavas.

The lavas comprise two suites: a leueite-bearing undersaturated series of leucitites, leueite tephrites, leucite phonolites, and trachytes; and a subordinate hy-normative series of mainly trachytes and latites. All lavas are porphyritic with mostly 1–15 vol. % phenoerysts. No cumulates were found. Major elements, and Cr and Ni were determined in the phenocrysts by microprobe analysis and more than 20 trace elements were determined on mineral separates by PIXE.

The undersaturated suite. Ubiquitous clinopyroxene phenoerysts belong to the Di-Hedss series and range from Di97 to Di46. Important amounts of Fe3+ are always present. In the mafic rocks the diopside is chromian, but Ti is low. AI mainly substitutes in the Z positions in all lavas. Only minor Na enrichment occurs with increasing total Fe (0–7 mole % acmite) and thus Ca ferri-Tschermak's component is important. In many of the maric lavas diopside mantles green cores of salite, which has a composition very like the salite of felsic lavas. Leucites contain 5–22 mole % orthoelase in solid solution, but show no systematic variation. Plagioclase, mostly An93-An72, occurs in the felsie lavas, and alkali feldspar only in some phonolites. They both have exceptionally high concentrations of Sr and Ba, with a maximum of 1.3 wt. % SrO and 5.6 wt. % BaO in hyalophanes. Olivine, Fo92-Fo66, occurs in some leucititic lavas in mostly accessory amounts. Phlognpite, magnetite and nepheline are accessory phases of the felsic lavas. Apatite only occur as micro-phenocrysts of the fclsic lavas. Haüyne in trace amounts is found in a few phonolites. Pargasitic amphibole microphenocrysts are found in one lava.

In most marie members diopside ±leuctie ±olivine were liquidus phases. This study does not confirm that these rocks are related by crystal fractionation. In more felsie lavas clinopyroxene (salite-ferrosalite) and leucite are joined by: plagioclase, magnetite ±phlogopite, and Ba-rich alkali feldspar ±haüyne. The felsic rocks are thought to be related by crystal fractionation.

Salitic green cores of phenocrystic pyroxene, mantled by diopside in rocks which also carry normally-zoned diopside, are relicts which provide evidence of either a relatively high PH2O, prior to the crystallization of diopside or magma mixing in the earlier life of these lavas. Pyroxene chemistry points towards low-pressure crystallization (2 kbar), generally in a dry environment.

The hy-normative suite. All lavas have phenocrysts of augite, sanidine, plagioclase, magnetite, biotite, and olivine. The pyroxene is less calcic and has less alumina, but is otherwise rather similar to the salites of the undersaturated suite. Compared to the undersaturated suite, feldspars do not have high Sr and Ba, magnetite has higher TiO2 and olivine crystallized from even the felsic lavas. The pyroxenes show the signs of low-pressure crystallization.

Nucleation and crystal growth of plagioclase have been studied in two basaltic melts by one atmosphere, constant-rate and variable-rate cooling experiments using the wire-loop technique (Donaldson et al., 1975). Constant-rate cooling studies indicate that the length of the incubation period prior to nucleation varies systematically with the degree of supercooling and with the cooling rate. Attempts to determine the rates at which the marginal parts of two dykes (from the Isle of Arran, SW Scotland) cooled, by the attempted reproduction of the natural textural features, in constant-rate cooling experiments suggest that for one of the dykes, plagioclase phenocrysts at the contact could have grown at a cooling rate of approximately 3°C/hour and the groundmass plagioclase laths at faster cooling rates in excess of 10°C/hour. For the other dyke the plagioclase laths in the rocks 0.5 cm from the dyke contact probably grew at rates slower than 2°C/hour. Attempts to validate experimentally the Jaeger (1957) cooling model for the two dykes suggest that the dykes cooled at much slower rates than the theory predicts.