Sediment from Lake Boeckella, Antarctic Peninsula, is richer in Ca, Cd, Cu, P, Sr and Zn than that of six other lakes in the area. The elements originate from Adélie penguin (Pygoscelis adeliae) guano on the lake shores. Changing Cu and P concentrations in the lake sediment are used as a proxy for penguin influence on the lake sediment from ca. 5850 bp to present. A 14C dating model suggests that the 14C correction factor in the lake sediments depends on the penguin proxy, the apparent age of the penguin guano and the amount of particulate carbon originating from the carbon-bearing shales in the watershed. Glacial meltwater and dissolved carbonates do not contain enough “old” carbon to contribute significantly to the correction factor. Ages corrected with the 14C dating model agree with the depth vs. age curve based on independently 14C-dated tephra horizons. The reservoir effect has been constant since at least 5800 bp, implying long-term stability of the currents and water masses in the area. The existing chronology for Lake Boeckella has been recalculated. The period of glacial advance, previously thought to have culminated at 5000 bp, is now thought to have culminated at 4700 bp; deglaciation of the area is thought to have occurred at 6300 bp instead of 8680 bp.

We obtained 14C ages on samples of lake marl and other sediments from cores taken in Gościąż Lake and its environs. Comparison of 14C dates of bulk samples of laminated sediment with varve chronology and available AMS dates of terrestrial macrofossils indicates a reservoir correction of 2000 ± 120 yr for the basal series of lake sediments. 14C dates obtained on peat layers underlying the oldest lacustrine sediments in Gościąż and other lakes consistently locate the beginning of organogenic sedimentation in this area at ca. 13 ka bp. We distinguished three periods of lacustrine gyttja sedimentation in cores taken in Gościąż and adjacent lakes: 11.8–10.2 ka, 8–7 ka and 2.7–2.1 ka bp. From the 14C dates of lithological boundaries in these cores, we reconstruct a pattern of lake-level changes during the last 12 ka, remarkably similar to Swedish lakes and generally agreeing with available records from European and American lakes. The behavior of Gościąż Lake during the last 12 ka fairly well reflects global climate changes in the temperate zone during the Late Glacial and Holocene periods.

We present ΔA14C and 39Ar data collected in the Nansen, Amundsen and Makarov basins during two expeditions to the central Arctic Ocean (RV Polarstern cruises ARK IV/3, 1987 and ARK VIII/3, 1991). The data are used, together with published Δ14C values, to describe the distribution of Δ14C in all major basins of the Arctic Ocean (Nansen, Amundsen, Makarov and Canada Basins), as well as the 39Ar distribution in the Nansen Basin and the deep waters of the Amundsen and Makarov Basins. From the combined Δ14C and 39Ar distributions, we derive information on the mean “isolation ages” of the deep and bottom waters of the Arctic Ocean. The data point toward mean ages of the bottom waters in the Eurasian Basin (Nansen and Amundsen Basins) of ca. 250-300 yr. The deep waters of the Amundsen Basin show slightly higher 3H concentrations than those in the Nansen Basin, indicating the addition of a higher fraction of water that has been at the sea surface during the past few decades. Correction for the bomb 14C added to the deep waters along with bomb 3H yields isolation ages for the bulk of the deep and bottom waters of the Amundsen Basin similar to those estimated for the Nansen Basin. This finding agrees well with the 39Ar data. Deep and bottom waters in the Canadian Basin (Makarov and Canada Basins) are very homogeneous, with an isolation age of ca. 450 yr. Δ14C and 39Ar data and a simple inverse model treating the Canadian Basin Deep Water (CBDW) as one well-mixed reservoir renewed by a mixture of Atlantic Water (29%), Eurasian Basin Deep Water (69%) and brine-enriched shelf water (2%) yield a mean residence time of CBDW of ca. 300 yr.

Radiocarbon and uranium-series ages of the calcareous deposits of the Plitvice Lakes show that travertines were deposited during three warm, humid, interglacial oxygen isotope stages. According to our measurements, only calcite crystals or crystal aggregates represent reliable material for both 230Th/234U and 234U/238/U dating. Compact old travertine in the form of sandstone is less reliable; it can be dated by both methods provided that its detrital contamination is not significant, demonstrated by very low 14C activity (< 1.5–2.0 pMC) and a high 230Th/232Th ratio. Old porous travertine contaminated with recent carbonates and Th-bearing clay (pMC > 5, 230Th/232Th < 5) gives erroneous results by both methods. Stage 1 (Holocene) deposition is shown primarily by 14C dating corroborated by sedimentological and palynologic studies as well as by both 230Th/234U and 234U/238U disequilibrium methods. The intensive growth of travertine barriers coincided with significant climate warming in the Holocene. Stage 5 deposition is confirmed by the 230Th/234U dating of crystalline calcite aggregates embedded in the travertine matrix and by concordant 230Th/234U and 234U/238U ages, assuming that the 234U/238U activity ratio of 1.88 observed in modern streams and in Holocene deposits can be extended to past epochs. The travertine deposition period was very short, peaking ca. 120 ± 10 ka bp. Stage 11 deposition is indicated by 234U/238U dating only, the period being within the 234U decay range, but not that of 230Th. Stage 11 travertine was deposited ca. 420 ± 50 ka bp. We did not find travertine samples with U-series ages indicating a growth period during relatively warm Stages 7 and 9; due to the scarcity of old travertine outcrops, these and possibly other stages cannot be excluded on the basis of presented data. All of these isotopic dating results concur with the field relation of the travertine complex of the Plitvice Lakes.

The shape of a distribution of calibrated 14C dates displays spurious peaks and troughs, brought about by changes in the slope of the calibration curve interacting with the spreading effect of the stochastic distribution of counting errors. The distortion results in a positive correlation between the numbers of dates per calendar year and the slopes of the calibration curves, for assemblages of archaeological dates from such widely separated areas as British Columbia, South Australia and New Zealand. The distortion also increases the possibility of date reversals, and increases the overall spread of calibrated 14C dates. After taking into account this systematic distortion and inbuilt age of charcoal and wood samples, we estimate dates for the initial settlement and first appearance of fortifications, and infer a likely trend of population growth for prehistoric New Zealand.

According to most geological and geomorphological studies, the maximal advance of the Würmian glaciers in the French Alps occurred at least before 40 ka bp and cannot be dated by 14C. Scientists believed that this dating method could be used for dating the last glacial advance and late deglaciation in the region. The scarce and scattered 14C dating results available from geological samples do not confirm an early (ca. 18 or 20 ka bp) age for the total cooling of the ice nor do they prove that residual ice sheets remained at low elevations. Attempting to solve this chronological problem, we compiled current archaeological knowledge of the oldest Late Paleolithic sites. A review of their 14C results shows that no site older than 15 ka bp (with Gravettian, Solutrean or early Magdalenian industries) can be found east of the Saône-Rhône Valley, even at low elevations. Only rare sites, dated to ca. 14.5 ka bp, may be found close to the mountain regions that were suddenly occupied around the beginning of the Bølling period (ca. 13.5 ka bp). Thus, it seems that the eastern Alps offer no evidence for direct association between glacial retreat and human settlement or simultaneous occurrence in early or late deglaciated areas.

We have established a laboratory for extracting ΣCO2 from seawater samples for AMS analysis of the radiocarbon content. The seawater samples are collected at sea, poisoned and stored until analysis in the laboratory. Each sample is acidified; the inorganic carbon is stripped out as CO2 with an inert carrier gas and then converted to graphite. We present results for Buzzards Bay surface H2O and Na2CO3 standards that demonstrate we strip >98% of inorganic carbon from seawater. Stable isotope analyses are performed to better than 0.2‰, and the reproducibility of 14C measurements on Buzzards Bay seawater is better than 13‰. Finally, we compare data from samples collected in 1991 to those collected in the 1970s and to large volume samples.

The first results of radiocarbon dating of the ancient sites in the Russian Far East were published early in the 1960s (Okladnikov 1964). We now have enough data to establish the main features in the 14C chronology of the Stone and Bronze Age cultures in Primorye, one of the archaeologically well-studied regions of the Russian Far East.

The interpretation of 14C histograms is complicated by the non-linearity of the 14C time scale in terms of calendar years, which may result in clustering of 14C ages in certain time intervals unrelated to the (geologic or archaeologic) phenomenon of interest. One can calibrate 14C histograms for such distortions using two basic approaches. The KORHIS method constructs a 14C histogram before calibration is performed by means of a correction factor. We present the CALHIS method based on the Groningen calibration program for individual 14C ages. CALHIS first calibrates single 14C ages and then sums the resulting calibration distributions, thus yielding a calibrated 14C histogram. The individual calibration distributions are normalized to a standard Gaussian distribution before superposition, thus allowing direct comparison among various 14C histograms. Several experiments with test data sets demonstrate that CALHIS produces significantly better results than KORHIS. Although some problems remain (part of the distortions due to 14C variations cannot be eliminated), we show that CALHIS offers good prospects for using 14C histograms, particularly with highly precise and accurate 14C ages.

14C ages of samples from the Ötztal Ice Man, found on the Hauslabjoch in the Tyrolean Alps in September 1991, were determined using accelerator mass spectrometry (AMS). Uncalibrated 14C ages of 4555 ± 34 bp, 4560 ± 65 bp and 4535 ± 60 bp were measured on tissue (mean of four samples), bone and grass, respectively, from the Ice Man. The mean of all of our measurements is 4550 ± 27 bp.

We show that smoothed versions of the high-resolution calibration curve should be used when 14C ages are calibrated with large (> ∼30 14C yr) measurement errors (represented by standard deviation δm) or are mixtures of elements of variable age (natural sample error with standard deviation δn). The degree of smoothing should agree with the standard deviation of total sample error, δt, the square root of the quadratic sum of δm and δn. However, in most cases, δt is not well known, especially due to difficulties in quantifying δn. We present an inverse method that gives a measure of mean δt, for different materials that are widely used in (conventional) 14C dating. Calculations with large (>100) data sets of wood, charcoal, ombrotrophic peat and minerotrophic peat/gyttja samples indicate that δt of such materials is generally much larger than previously assumed, mainly because of large values of δn. This means that particularly in organic deposits, strongly smoothed calibration curves should be used where medium-term 14C variations (wiggles) are completely straightened. This has especially major consequences for calibrating 14C histograms for natural 14C variations. We conclude that 14C histograms consisting of samples of organic deposits do not require correction for medium-term 14C variations and that uncalibrated 14C histograms need not be as suspect as is usually believed.