Radiocarbon (14C) wiggle-match dating is a technique with a substantial potential to improve the precision of dating timbers in situations where dendrochronology is not tenable. However, one of the key reasons why obtaining a dendrochronological determination might be difficult is the short-lived nature of timbers on a range of archaeological sites, something that also affects the efficiency of the wiggle-match dating technique. Combined with the potential for high expense that the technique presents, it is paramount that wiggle-match dating research design has a good empirical basis. To this end we dated 50 consecutive, individual rings from a timber that grew during the Hallstatt radiocarbon calibration plateau (ca. 750–400 cal BC) in southwest Scotland. The results indicate that (1) the precision and accuracy of wiggle-match dates carried out on short-lived sequences during the Hallstatt plateau may suffer due to insufficient resolution of the calibration data, (2) sampling time-frames roughly equivalent to the underpinning calibration data are recommended (for the period in question this means decadal blocks), and (3) short-lived sequences are at risk of losing accuracy if the actual past trend of radiocarbon diverges from the mean of the radiocarbon calibration curve.

The laboratory started dating in 1966 using liquid scintillation techniques. Considerable effort has been expended on improvements in both sample preparation and detection (Pietig and Scharpenseel, 1964 and 1966). Yields now approach 100% and 4 to 6 samples are completed each week. A solution of 3 cc synthesized benzene and 1 cc “dead” commercial toluene is employed for ordinary measurements. Toluene contains PPO and POPOP scintillators that give final concentrations of 0.4% and 0.01%, respectively, when diluted with sample benzene. The counting arrangement with normal shielding gives a net modern count rate of 25.6 cpm (78% efficiency) with a background of 9.7 cpm. A special counter equipped with 5 cm mercury and 10 cm lead shielding as well as an anti-coincidence “umbrella” of polystilbeneplastic scintillator has considerably better characteristics. In addition to reduced background, samples as large as 100 cc can be accommodated. The exceptional performance obtained here is presently reserved for natural radioactivity measurements, such as T-3 and C1–36.

Between 1984 and 1995 over 450 organic samples were collected from monuments built during the Old and Middle Kingdoms. The most suitable samples were selected for dating. The purpose was to establish a radiocarbon chronology with samples from secure context and collected with the careful techniques required for 14C samples. This chronology is compared to the historical chronology established by reconstructing written documentation.

Measurements of 14C activity of atmospheric CO2, vegetables, and tree rings in the area of the 632 MWe power plant Krško in Slovenia, NW Yugoslavia, have been in progress since January, 1984. Sampling stations are located in the area ca 400km2 and are distributed in the direction of the prevailing westerly winds. The closest sampling point is 1.5km NE of the plant exhaust stack, the farthest sampling point is 30km E of the plant. A sampling site at National Park Plitvice in central Croatia was chosen as the 14C reference point not affected by the power plant.

An average excess of 2.2% above the reference point activity during normal periods of reactor operation was observed 1.5km from the plant smokestack. Calculations of the 14C release from the power plant was estimated at 0.1 TBq/a. The tree ring activity near the plant followed the 14C activity of the Northern Hemisphere in the past decade. No influence of the power plant release was observed on the tree ring activity.

We undertook a strengths, weaknesses, opportunities, and threats (SWOT) analysis of Northern Hemisphere tree-ring datasets included in IntCal20 in order to evaluate their strategic fit with the demands of archaeological users. Case studies on wiggle-matching single tree rings from timbers in historic buildings and Bayesian modeling of series of results on archaeological samples from Neolithic long barrows in central-southern England exemplify the archaeological implications that arise when using IntCal20. The SWOT analysis provides an opportunity to think strategically about future radiocarbon (14C) calibration so as to maximize the utility of 14C dating in archaeology and safeguard its reputation in the discipline.

The list includes age measurements carried out from December 1964 to October 1965. As in the previous list (Rome III) the samples dated are almost all of archaeological interest and are drawn from Italian and some European and Asiatic territories.

In the 2000s, radiocarbon in dissolved inorganic carbon was measured during 7 revisit cruises along the lines of the World Ocean Circulation Experiment in the Pacific Ocean. Comparison of 14C data along these lines from the 1990s and 2000s revealed decadal changes of 14C concentration in the thermocline, most of which were due to temporal changes in the bomb-produced 14C. Vertical profiles and vertical-integrated inventories of the bomb 14C in the subarctic and equatorial regions did not change appreciably. In the southern subtropical region, 14C decreased in the upper thermocline from the surface to ∼500 m depth. In contrast, 14C increased in the lower thermocline below ∼500 m depth. The opposing directions in 14C change resulted in small temporal changes in the total inventory of bomb 14C. On the other hand, the water-column inventory significantly decreased in the northwestern subtropical region due to the 14C decrease in the upper thermocline. These decadal changes in bomb 14C indicate that the turnover time of thermocline circulation in the northwestern subtropical region is faster than that in the southern subtropical region, and imply an interbasin transport of bomb 14C from the North Pacific to other basins.

The general reliability of 14C dating in archaeology induced us to try to extend the method to other datable materials that may be uncovered, even those which have till now been neglected or considered unreliable. Improvements in AMS techniques will also help us date very small samples or those with low carbon content. For these reasons we have undertaken a systematic study of the application of 14C dating to potsherds which are usually abundant in prehistoric sites and often more representative of human activity than other materials such as charcoal (Evin, 1983).

Radiocarbon dating of many types of samples has continued at the La Jolla Radiocarbon Laboratory since the last date list was published (Bien and Pandolfi, 1972). Since the 1969 relocation of the laboratory to its present location on Mt Soledad, at least 5 low-level 14C systems have generally been in operation. The laboratory has continued to employ acetylene gas proportional counting. Samples were usually measured for 2 to 3 days in each of 2 different detectors. The properties of the 5 counters used in the measurements of samples are as follows (background and net standard counts per minute, respectively, with acetylene of 900mmHg pressure are given in parentheses): 1) Bern counter: Oeschger-type counter-guard ring unit with 1.7L sensitive center volume (2.1, 21.5), 2) MBLE counter: Oeschger-type counter-guard ring unit with 1.6L center volume (1.3, 17.4), 3) 1L counter with separate Q-gas flow guard ring (4.2, 12.9), 4) 0.4L counter with separate guard ring (1.2, 4.2), and 0.1L counter with separate guard ring (0.7, 1.2).

A preliminary investigation of the biocarbon fraction in carbon dioxide emissions of power plants using both fossil- and biobased fuels is presented. Calculation of the biocarbon fraction is based on radiocarbon content measured in power plant flue gases. Samples were collected directly from the chimneys into plastic sampling bags. The 14C content in CO2 was measured by accelerator mass spectrometry (AMS). Flue gases from power plants that use natural gas, coal, wood chips, bark, plywood residue, sludge from the pulp factory, peat, and recovered fuel were measured. Among the selected plants, there was one that used only fossil fuel and one that used only biofuel; the other investigated plants burned mixtures of fuels. The results show that 14C measurement provides the possibility to determine the ratio of bio and fossil fuel burned in power plants.

I attempted to separate smoke-derived carbon from carbon derived from clay by variable-temperature burning. First, using liquid scintillation counting (LSC) and accelerator mass spectrometry (AMS), I dated experimental potsherds containing these two sources of carbon. I used the same techniques to date archaeological samples. The results on archaeological sherds confirm the difficulty of establishing a standard procedure for pottery dating. Nevertheless, reliable dates on smoke-blackened potsherds are potentially obtainable with AMS dating of thin lamellas in the sherd surface following adequate NaOH treatment.

The Late Bronze Age to Iron Age transition in the coastal southern Levant involves a major cultural change, which is characterized, among other things, by the appearance of Philistine pottery locally produced in styles derived from outside the Levant. This transition in the coastal southern Levant is conventionally dated to the 12th century BC, based on historical and archaeological artifacts associated with the Philistine pottery. Radiocarbon dating can provide a more precise independent absolute chronology for this transition, but dating for the period under discussion is complicated by the wiggles and relatively flat slope in the calibration curve, which significantly reduce precision. An additional complication is that the stratigraphic record below and above the transition at this site, as well as at most other sites in the region, is far from complete. We thus used a variety of microarchaeological techniques to improve our understanding of the stratigraphy, and to ensure that the locations with datable short-lived materials were only derived from primary contexts, which could be related directly to the associated material culture. The 14C dates were modeled using Bayesian statistics that incorporate the stratigraphic information. Using this integrative approach, we date the appearance of the Philistine pottery in Tell es-Safi/Gath in the 13th century BC.

No important instrumental modifications have been made since publication of our last list (Yale VII). As before, we are indebted to many collaborators for samples and for assistance with descriptions and comments. Technical assistance has been provided by George Young, Carolyn Haupt, and Jonathan Wood. The generous support of the National Science Foundation, under grants G-19080 (to Stuiver), G-19335 (to Deevey), and G-24049 (to Rouse) is gratefully acknowledged.

Radiocarbon natural abundances (Δ14C) are being increasingly used to trace carbon cycling in stream ecosystems. To understand the ultimate sources of carbon, we determined the stable carbon isotope ratios (δ13C) and Δ14C values of dissolved inorganic and organic carbon (DIC and DOC, respectively) and of particulate organic carbon (POC) in two small streams in central Japan, one of which flows over limestone bedrock (Seri) and the other does not (Fudoji). Investigations over four seasons revealed that the Δ14C values of the DIC (from −238‰ to −174‰ for Seri and −23‰ to +10‰ for Fudoji) were less variable than those of the other carbon fractions (DOC: from −400‰ to −138‰ for Seri and −2‰ to +103‰ for Fudoji; POC: from −164‰ to −60‰ for Seri and −55‰ to +37‰ for Fudoji). Based on mass balance calculations using the δ13C and Δ14C values, the proportions of carbon in the DIC originated from (1) atmospheric CO2 were 47% to 57% for Seri and 74% to 90% for Fudoji, (2) organic matter degradation were 29% to 35% for Seri and 4% to 21% for Fudoji, and (3) carbonate rock were 14% to 22% for Seri and 4% to 6% for Fudoji. We compared the results with previous studies that had been conducted in larger rivers and showed that in small streams, the dissolution of atmospheric CO2 and weathering of carbonate rock are more important factors in the carbon cycling than the biological degradation of organic matter.

Radiocarbon dating (Libby, 1955) has been an important tool in the marine sciences since the early 1950s (eg, Arrhenius, Kjellberg & Libby, 1951; Ericson et al, 1956; Broecker, Ewing & Heezen, 1960; Emery & Bray, 1962) and the basic principles and analytic procedures of the method have changed little. In the late 1970s, the Accelerator Mass Spectrometer (AMS) method of 14C dating was developed (Bennett et al, 1977, 1978), the major advantages being that samples several thousand times smaller than needed for beta-decay counting can be dated, and analysis time is reduced to ca 1 hr from the 1–6 days needed for beta-decay methods.

In this study, δ13C and δ15N of bone samples from 83 skeletons (79 humans, 2 horses, and 2 dogs) excavated from pagan and early Christian graves from 21 localities in Iceland are used to reconstruct diet of the early settlers in Iceland and possible differences in diet depending on the distance between the excavation site and the seashore. We have radiocarbon dated 47 of these skeletons and used the carbon isotopic composition (δ13C) to estimate and correct for the marine reservoir effect (the 14C difference between terrestrial and mixed marine organisms). The reservoir-corrected ages lie in the range of AD 780–1270 (68.2% probability). Reservoir age corrections were checked by comparing 14C dates of a horse (terrestrial diet), a dog (highly marine diet), and a human (mixed diet) from the same burial. The range in measured marine protein percentage in individual diet is from about 10% up to 55%, mostly depending on the geographical position (distance from the sea) of the excavation site. We had access to the skeleton (AAR-5908) of the Skálholt bishop Páll Jónsson whose remains are enshrined at the Episcopal residence in Skálholt, southern Iceland. According to written sources, the bishop died in AD 1211. Using our dietary reconstruction, his bones were about 17% marine, which is within the range of human skeletons from the same area, and the reservoir-corrected calibrated 14C age of the skeleton is in accord with the historical date.

This study tested whether accurate dating by accelerator mass spectrometry (AMS) radiocarbon wiggle-matching of short tree-ring series (~30 annual rings) in the Medieval period could be achieved. Scientific dating plays a central role in the conservation of historic buildings in England. Precise dating helps assess the significance of particular buildings or elements of their fabric, thus allowing us to make informed decisions about their repair and protection. Consequently, considerable weight, both financial and legal, can be attached to the precision and accuracy of this dating. Dendrochronology is the method of choice, but in a proportion of cases this is unable to provide calendar dates. Hence, we would like to be able to use 14C wiggle-matching to provide a comparable level of precision and reliability, particularly on shorter tree-ring sequences (~30 annual growth rings) that up until now would not routinely be sampled. We present the results of AMS wiggle-matching five oak tree-ring sequences, spanning the period covered by the vast majority of surviving Medieval buildings in England (about AD 1180–1540) when currently we have only decadal and bidecadal calibration data.

Calcareous deposits known as tufa or travertine contain biogenic carbon and are a potential source of geochronologic information. Many dated samples from Karstic regions in Yugoslavia proved that 14C analyses of tufa can provide reliable data reflecting climatic conditions in the past. Systematic dating of tufa samples revealed two distinct groups of deposits: recent tufa deposits, with a sharp age limit of ∼6000 ± 500 years BP, and old tufa deposits with 14C age ranges from 25,000 ± 2300 years BP to the lowest limit of our 14C dating system (∼37,000 years). A histogram based on the initial activity AO = 0.85 shows the age distribution of randomly sampled tufas vs sample frequency. A time gap between ∼6000 BP and ∼23,000 BP is evident, reflecting cooler climatic conditions. The start of peat deposition is coincident with that of tufa growth in the Holocene.

Paleoclimatic implications of tufa growth periods obtained by 14C dating are as follows: climatic conditions that favor tufa formation at least in karstic regions, are very stringent. Therefore, climatic conditions, such as mean annual temperature and humidity, as well as hydrologic and vegetational conditions, must have been very similar in periods of tufa growth. While recent tufa deposits are coincident with the warm Holocene period, old tufa can be associated with warm interstadials in the Würm.

The following is a list of dates obtained since the time of the compilation of List VII in December 1961. The method is essentially the same as that used for the work described in the previous list. Two CO2-CS2 Geiger counter systems are used. The equipment and counting technique have been described elsewhere (Crane, 1961a, 1961b). The dates and the estimates of error in this list follow the practice recommended by the International Radiocarbon Dating Conference of 1962, in that (a) dates are computed on the basis of a half life of 5568 years, (b) a.d. 1950 is used as the zero of the age scale and (c) the errors quoted are the standard deviations obtained from the numbers of counts only. In all previous Michigan date lists we have quoted errors at least twice as great as the statistical errors of counting, in order to take account of other errors in the over-all process. If the reader wishes to obtain a standard deviation figure which will allow ample room for the many other sources of error in the dating process, we suggest he double the figures that are given in this list. The procedures for converting the dates to the more recent half life scale and to a scale having its zero at any time other than 1950 need not be given here as they have been covered in this journal and elsewhere. Where there is no comment, it is because the submitter of the sample had none to make.

The C14 dates given below are a continuation of the work presented in our earlier lists (Stockholm I, II, III, IV, and V). The apparatus and technique are the same as described in Stockholm V.