The Mayombe chain of Congo is part of the West Congo Belt, which belonged to the western Gondwana supercontinent. It consists of Paleoproterozoic gneisses and schists that are tectonically stacked and overthrust Neoproterozoic low-grade metamorphic rocks. Although Neoproterozoic context of the chain is relatively well established, the tectono-metamorphic evolution of its Paleoproterozoic basement still under discussion.

Petrography, garnet chemistry and phase equilibria modelling were used to constrain tectono-metamorphic evolution of meta-plutonic and meta-sedimentary rocks from the Western Domain of the Mayombe chain. Microprobe analysis reveals three garnet types: (i) 2-stage garnets with distinct cores (Grt1) and rims (Grt2), (ii) unzoned garnet showing narrow diffusion zones along cracks and rims and (iii) syn-kinematic garnet with normal growth zoning. These complex and simple features of garnet growth are, respectively, related to a polycyclic evolution linked in this area to: (i) the superposition of Eburnean (c. 2000 Ma) and Pan-African (c. 600 Ma) orogenies and (ii) a monocyclic evolution related to a single Pan-African event taking into account ages of the protoliths. The oldest metamorphic assemblage (Eburnean) is preserved in amphibolite facies conditions marked by the first generation of garnet, whereas the younger (Pan-African) event varies from amphibolite facies in the southwest (4–6 kbar, 550°C–600°C) to greenschist facies in the northeast (4–6 kbar at 450°C–550°C) confirming the westward increase in metamorphic grade during the Pan-African event. Mineral equilibria modelling shows also a relatively HP episode culminated at 11.5–12.5 kbar and 525°C–550°C which tectonic environment stills less understood.

The petrogenesis of Palaeoarchaean mafic–ultramafic rock suites from the western Iron Ore Group, Singhbhum Craton, eastern India, has been evaluated based on the chemistry of constituent mineral phases. The rock suites include basaltic rocks and mafic (gabbro) to ultramafic (serpentinized peridotite) intrusive rocks, which occur in host rocks covering phyllite, ferruginous shale, banded haematite quartzite and jasper. The constituent clinopyroxene shows dominant uralitization, whereas plagioclase grains are generally saussuritized, being marked by relatively tiny granular aggregates of albite, chlorite, epidote and K-feldspar. The ultramafic intrusive rocks are overwhelmingly serpentinized. Clinopyroxene compositions are augitic, whereas relict plagioclase is typically bytownite. Amphiboles of the investigated rock suites are divisible into the ‘uralite’ type (occurring peripherally to clinopyroxene) and the ‘completely changed-over amphibole’ type (with no traces of initial clinopyroxene). Both the amphibole types belong to the ‘calcic group’, showing a compositional spectrum from actinolite–magnesiohornblende–ferrohornblende–ferroactinolite. Opaque minerals include magnetite (both Cr-magnetite and Al-magnetite), chromite (Al-chromite) and ilmenite, whereas serpentine (belonging to the ultramafic intrusive rocks) corresponds to lizardite. Looking at the mineral compositions of the pyroxene, glass and amphibole, the studied rock suites show a wide equilibration temperature–pressure domain range (∼750 °C to ∼1400 °C at ∼0.26 kbar to ∼21 kbar), which corresponds to an ascending magma that underwent a ‘hydration event’ at a shallow level. The assessment of the clinopyroxene and spinel chemistry characteristically suggests an arc setting for the parent magma that has undergone both equilibrium and fractional crystallization in the course of magmatic evolution. During differentiation, the magmatic density remains almost constant, with variable oxygen fugacity.

Igneous rock forming minerals carry valuable information from the deep earth that is not directly accessible at the surface. Each mineral represents the physico-chemical conditions at which various magmatic processes have occured over a wide range of depths from upper mantle to shallow crustal levels. These processes are cryptically inscribed in the whole-rock and mineral compositions (e.g. major elements, trace elements and isotopic ratios) and textures (equilibrium vs. disequilibrium features), together with intensive variables (e.g. pressure, P; temperature, T). Therefore, particular attention should be given to igneous minerals to understand better the processes that took place during their journey from the source through magma chambers and conduit systems to the Earth's surface.

MagMin_PT is an Excel© based user-friendly program, designed to calculate mineral formulae and end-members, and to estimate pressure and temperature (e.g. geothermobarometry) from electron microprobe analytical data. The program operates using the most common igneous rock-forming minerals (olivine, pyroxene, amphibole, biotite, feldspar, magnetite, ilmenite, apatite and zircon), resulting in various classification diagrams and P–T diagrams. The program allows for whole-rock or glass composition to be entered together with the EPMA data to evalaute the equilibration status for most P–T calculation models. Fe2+ and Fe3+ estimation is routinely performed in MagMin_PT based on stoichiometric constraints, and to some extent using machine learning methods for different iron-bearing minerals. MagMin_PT is also able to carry calculations of fugacity, magmatic water content and saturation temperature. Graphical and numerical outputs produced by the program can be easily copied to other media for further processing.

The study area belongs to the Singhbhum metamorphic belt of Jharkhand, situated in the eastern part of India. The spatial distribution of the index minerals in the pelitic schists of the area shows Barrovian type of metamorphism. Three isograds, viz. garnet, staurolite and sillimanite, have been delineated and the textural study of the schists has revealed a time relation between crystallization and deformation. Series of folds with shifting values of plunges in the supracrustal rocks having axial-planar schistosity to the folds have been widely cited. Development of these folds could be attributed to the second phase of deformation. In total, two phases of deformation, D1 and D2, in association with two phases of metamorphism, M1 and M2, have been lined up in the study area. Chemographic plots of reactant and product assemblages corresponding to various metamorphic reactions suggest that the pattern of metamorphic zones mapped in space is in coherence with the temporal-sequential change during prograde metamorphism. The prograde P–T evolution of the study area has been obtained using conventional geothermobarometry, internally consistent winTWQ program and Perple_X software in the MnNCKFMASHTO model system. Our observations suggest that the progressive metamorphism in the area is not related to granitic intrusion or migmatization but that it was possibly the ascending plume that resulted in the M1 phase of metamorphism followed by D1 deformation. The second and prime metamorphic phase, M2, with its possible heat source generated by crustal overloading, was preceded by D1 and it lasted until late- to post-D2 deformation.

I will consider mainly geothermobarometry in medium-grade pelitic rocks, including the garnet-biotite (GB) geothermometer, the Grossular-Al silicate-plagioclase (GASP) geobarometer, and the muscovite-almandine-biotite-sillimanite (MABS) geobarometer. For GB (Holdaway, 2000) experimental data and estimated biotite ΔWTi were used to optimize two exchange parameters and four biotite Margules parameters. Using stepwise linear regression, experimental vs. calculated T were constrained to lie on a line with slope of one and intercept of zero, maximizing r2. The best model involves experiments by Ferry and Spear (1978) and Perchuk and Lavrent’eva (1983), suggesting minimal viAl in the Ferry and Spear product biotite. For GASP (Holdaway, 2001), end-member experimental data do not adequately constrain the equilibrium. I used the GB model above, and allowed the end-member curve to rotate about the best-constrained part of the GASP end-member data. The end-member curve was further constrained with the kyanite-sillimanite (K-S) boundary using published chemical data on 76 pelitic schist samples from 11 localities, rejecting Low-Grs and low-An samples. The Fuhrman and Lindsley (1988) plagioclase model gives the best results. For MABS, work in progress involves 61 samples from the 11 localities which have muscovite analyses. Biotite Margules parameters were based on the GB model and McMullin et al. (1991). The MABS end-member curve was calibrated by comparison of P values determined using trial MABS data and GASP results. The P values for the 61 samples agree well with the K-S boundary, and sillimanite-bearing rocks of west-central Maine all fall in the sillimanite field. Preliminary biotite values are: GAnn = –5149198 – 412.05 T, WAlFe = –14023 + 28.14 T, WAlMg = –259582 + 308.44 T, WTiFe = 124842 – 98.67 T, WTiMg = –186148 + 271.72 T. For geobarometry, the Berman (1988, revised 1992) database was used with adjustable H and S of grossular for GASP and H and S of annite for MABS. The accuracy of currently available databases, activity models and mole fraction models is not adequate for good geothermobarometry, without further refinement. Adjustable parameters tend to compensate for error in activity models, mole fraction models and databases.

Metabasites in the Dalradian Argyll and Southern Highland Groups experienced multiphase deformation and coeval Barrovian-type prograde and retrograde metamorphism during the Caledonian Grampian orogeny. Metamorphic Ca-amphiboles crystallized with plagioclase,epidote,chlorite and quartz, and sometimes with garnet and clinopyroxene. The minor changes in metabasite mineral assemblages and systematic mineral-chemical variations in Ca-amphibole confirm the classical concept of increasing metamorphic grade in metapelitic Chlorite to Sillimanite zones. In the Chlorite zone, high-Ti brown amphibole enclosed by green Ca-amphibole is interpreted as a magmatic relic. In the Chlorite, Biotite,Garnet and Andalusite zones, Ca-amphibole displays zonation with actinolite in cores and magnesio-hornblende to tschermakite in rims. Poor amphibole zonations occur in the Kyanite and Sillimanite zones. Ca-amphibole zonations are best described in terms of IVAl, VIAl and Ti which semiquantitatively monitor temperature and pressure changes. Maximal IVAl in amphibole increase with metamorphic grade. Empirically calibrated amphibole equilibria enabled us to reconstruct coherent prograde P-T paths and maximal P and T from the mineral zones; with Tmax of 680±50°C in the Sillimanite zone and Pmax of 8±1.2 kbar in the Kyanite zone. Prograde P-T paths indicate that elevated geothermal gradients should be considered even at the beginning of the Grampian Barrovian metamorphism.

Amphibolites in the Mesozoic part of the parautochthonous Lower Schieferhülle (LSH), the allochthonous Upper Schieferhülle (USH) and the overlying Austroalpine basement (AA) in and around the western Tauern Window (Eastern Alps) suffered a progressive Alpine deformation. Lineations and foliations L1-S1, L2-S2 defined by preferentially oriented (Na-Ca) amphiboles as well as F3 folds and further foliations Smyl and S4 in the metabasites are structures of successive deformational stages with a constant W-E main extension axis of strain. The (Na-Ca) amphiboles in assemblages with epidote, chlorite, albite/oligoclase and quartz are zoned with similar continuous zonation trends from early actinolite in the cores to magnesio-hornblende and tschermakitic hornblende, and from magnesio-hornblende to late actinolite in the rims in the three lithostratigraphic units. Geothermobarometry involving tremolite-edenite and (pargasite-hastingsite)-tremolite end-member equilibria in amphiboles allowed us to reconstruct prograde-retrograde P-T paths for the Alpine greenschist-amphibolite facies event. The paths passed P/Tmax at 6–7 kbar/600°C. Similar shapes of the paths in AA, USH and Mesozoic LSH indicate a common metamorphic history and a stacking of these units prior to or during the pre-Pmax evolution. Moderate P-T ratios are characteristic for the temperature-dominated compression paths and indicate continental collisional rather than subduction zone metamorphism. The middle to late Alpine greenschist-amphibolite facies event appears as an independent metamorphism along a complete P-T loop which may have followed an earlier and poorly documented high-pressure/low-temperature event.

This paper reports new geochronological data from the island of Andros, one of the less-studied islands of the Cycladic blueschist belt in the central Aegean Sea. On Andros, two tectonic units can be distinguished, the Makrotantalon unit and the Lower unit, which are separated by a low-angle normal fault, related to large-scale regional extension. Mineral assemblages indicate greenschist-facies P–T conditions for the last metamorphic overprint of both units. In contrast to the structurally lower unit, unambiguous indications for an earlier high-pressure stage were not recognized in rocks collected above the tectonic contact. Owing to a polyphase metamorphic evolution and incomplete resetting of the Rb–Sr isotope system during overprinting, phengite geochronology indicates a wide range in dates between c. 104 and 21 Ma for the Makrotantalon unit, as observed in rocks of similar structural position elsewhere in the Cyclades. The new Rb–Sr data support the interpretation, but are not conclusive evidence, that tectonic slices within the hanging wall were affected by two periods of Cretaceous metamorphism (c. 100–90 Ma and c. 80–70 Ma) and a Miocene event (c. 21 Ma). Tectonic juxtaposition was accomplished around c. 21 Ma. The Lower unit is correlative with the Cycladic high-pressure occurrences. Rb–Sr phengite dating yielded the same range in ages as determined elsewhere in the region for white mica of high-pressure rocks (c. 50–40 Ma) and their overprinted, greenschist-facies derivatives (c. 23–21 Ma). An age gradient towards the tectonic contact with the overlying Makrotantalon unit is not developed. The new results fit well into the previously established chronological framework for the larger study area. Indications for regional differences in the timing of the HP stage and/or the greenschist-facies overprint have not yet been found.

Granulites including a charnockite suite, mafic granulites, pelitic granulites, metanorite dykes and their retrograde varieties occur as discontinuous shear zone-bounded bodies within the Archaean basement comprising a granite gneiss–amphibolite–metasedimentary rock association in the central part of the Aravalli Mountains, northwest India. The entire suite, named the Sandmata Complex, preserves a complex history of tectonothermal evolution. Except for their strongly foliated margins, the granulite bodies are largely massive. Partial melting in the ‘country rocks’ led to the development of migmatite gneisses close to the contact of the granulite, a feature not as common in the rocks further away from the granulite contact. Geothermobarometry of massive granulites indicates Tmax>900°C and Pmax∼7.5 kbar. The retrograde granulites, which formed at lower amphibolite/upper greenschist-facies conditions, experienced channelized hydration reactions concomitant with shearing. These rocks locally appear as hornblende–biotite-bearing foliated granulite with or without Cpx or Opx. The rocks seem to have followed an inverse PTt path and have undergone an earlier phase of near-isobaric cooling. Our single zircon Pb–Pb ages indicate that the exhumation of granulites to the shallower amphibolite-facies levels with concomitant melting in the country rocks took place between 1690 Ma and 1621 Ma. Assuming that the granulite-facies metamorphism took place at around 1725 Ma, we relate the entire process of granulite metamorphism and exhumation covering an age range between 1725 and 1621 Ma to the rift basin opening stages of the Delhi Orogenic cycle that culminated at c. 1450 Ma.

Collision-related rocks intrude metamorphic rocks overthrust by ophiolitic units to make up the Central Anatolian Crystalline Complex. A wide variety of rock types were produced by the latest Cretaceous magmatism in the complex. These rocks can be divided into three distinct units: (1) calc-alkaline (Ağaçören, Behrekdağ, Cefalıkdağ, Çelebi, Ekecikdağ, Halaçlı, Karamadazı, Kösefakılı, Terlemez, Üçkapılı, Yozgat); (2) sub-alkaline (Baranadağ); and (3) alkaline (Atdere, Davulalan, Eğrialan, Hamit, İdişdağı, Karaçayır). The calc-alkaline rocks are metaluminous/peraluminous I- to S-type plutons ranging from monzodiorite to granite. The sub-alkaline rocks are metaluminous I-type plutons ranging from monzonite to granite. The alkaline rocks are metaluminous to peralkaline plutons, predominantly A-type, ranging from foid-bearing monzosyenite to granite. These plutons crystallized under varying pressures (5.3–2.6 kbar) and a wide range of temperatures (858–698 °C) from highly oxidized magmas (log fO2 −17 to −12). All intrusive rocks display enrichment in LILE and LREE compare to HFSE and have high 87Sr/86Sr and low 143Nd/144Nd ratios. These characteristics indicate that these rocks are derived from a mantle source containing large subduction components, and have experienced assimilation coupled with fractional crystallization (AFC) during uprise through crust. The coexistence of calc-alkaline and alkaline magmatism in the complex may be ascribed to mantle source heterogeneity before collision. Either thermal perturbation of the metasomatized lithosphere by delamination of the thermal boundary layer or removal of a subducted plate (slab breakoff) are the likely mechanisms for the initiation of the collision-related magmatism in the complex.

The petrography and mineralogy of Iherzolite nodules from an intrusive body of alkaline-ultrabasic rocks on Jetty Peninsula. The nodules are massive with a porphyritic hypidiomorphic granular texture. The main rock-forming minerals are: olivine, pyroxene, garnet and chrome spinel. The nodules are coarse granular spinel-garnet Iherzolites that are chemically similar to pyrope peridotite from Krezemze, Czechoslovakia, and pyrope-bearing peridotite from alkaline ultrabasites of Yakutia, USSR. The Al2O3 content in enstaties and Ca/(Ca + Mg) ratio in co-existing chrome diopside suggest that equilibrium conditions of the mantle mineral assemblage are: T = 875–900°C, P = 20–24 kbar, conditions typical of the spinel-pyrope facies of the upper mantle. Depths of withdrawal of the inclusions do not exceed 60–75 km. Available age determinations of the intrusive alkaline-ultrabasic rocks (145–150 Ma) suggest that alkaline-ultrabasic magmatism and withdrawal of plutonic nodules were related to rifting which resulted in the breakup of the Gondwana supercontinent in the late Mesozoic.

The Steel Mountain terrane of the southern Long Range Mountains forms a fault-bounded massif of (meta)plutonic rocks including the Disappointment Hill complex (DHC), a sequence of granulite-facies lithologies containing charnockite emplaced at 1498 Ma (U-Pb, zircon). Quartzofeldspathic gneiss of the DHC contains garnet + biotite + orthopyroxene ± cordierite assemblages indicative of metamorphic P–T conditions of ca 750°C and 400 MPa. The relatively high thermal gradient (ca 70°C km−1) inferred for the DHC is attributed to a magmatic heat source.

On grounds of lithology, age and metamorphic grade, the DHC correlates to granulites of the Long Range Inlier (LRI) exposed farther north. Both complexes occur in blocks thrust westward over Taconic allochthons capped by ophiolite nappes. The block containing the DHC, however, preserves younger cover rocks, suggesting that it originated at a higher structural level than the LRI. This model is supported by lower pressure estimates for the DHC relative to the LRI (400 MPa vs 500–800 MPa). The DHC forms a link between Grenvillian rocks of the northern Long Range of Newfoundland and those of Cape Breton Island. The structural position of these massifs suggests that their emplacement was a post-Taconic event.