The Seversky Donets River (Northern Donets) basin in eastern Ukraine and the Lower Don River valley in Russia were inhabited by populations that have been considered to be one of the earliest pottery-using cultures in Europe. The early pottery sites are all located on riverbanks and contain middens with many mollusk shells and fish bones. This suggests the intense exploitation of freshwater resources. The accuracy of radiocarbon dates obtained from these locations is of crucial importance for understanding the development of new technologies, diversification of the food consumed and its preparation strategies, as well as the degree of sedentism in this region, associated with the beginnings of pottery-making technology. The chronology of Neolithic sites in this region, however, was developed on the basis of 14C dates commonly obtained through the dating of freshwater mollusk shells, pottery with mollusk shell temper, or organic residue on pottery shards. Such samples are potentially affected by the freshwater reservoir effect, raising concerns about the accuracy of those dates. This paper presents accelerator mass spectrometry (AMS) 14C dates from a small pilot study from sites in eastern Ukraine in order to test for the presence of the reservoir effect in this region. The AMS 14C dates presented in this paper challenge the 14C chronology based on mollusk shell or organic residue, which appears to generate much older dates than those on wood charcoal or terrestrial animal bone.

Seventeen samples of burnt olive pits discovered inside a jar in the destruction layer of the Iron Age city of Khirbet Qeiyafa were analyzed by accelerator mass spectrometry (AMS) radiocarbon dating. Of these, four were halved and sent to two different laboratories to minimize laboratory bias. The dating of these samples is ~1000 BC. Khirbet Qeiyafa is currently the earliest known example of a fortified city in the Kingdom of Judah and contributes direct evidence to the heated debate on the biblical narrative relating to King David. Was he the real historical ruler of an urbanized state-level society in the early 10th century BC or was this level of social development reached only at the end of the 8th century BC? We can conclude that there were indeed fortified centers in the Davidic kingdom from the studies presented. In addition, the dating of Khirbet Qeiyafa has far-reaching implications for the entire Levant. The discovery of Cypriot pottery at the site connects the 14C datings to Cyprus and the renewal of maritime trade between the island and the mainland in the Iron Age. A stone temple model from Khirbet Qeiyafa, decorated with triglyphs and a recessed doorframe, points to an early date for the development of this typical royal architecture of the Iron Age Levant.

Radiocarbon content in biogenic samples is widely used to study the variation of atmospheric CO2 due to anthropogenic activities. A total of 26 samples of evergreen and deciduous tree leaves, as well as seasonal small plant leaves, were analyzed for this study. Sampling was carried out at the end of the vegetation season from rural villages surrounding a cement factory in Mount Lebanon Province, Lebanon. Reference samples of identical species were collected during the same period from a clean zone. The conventional 14C method was used for the determination of Δ14C values. The data showed that the 14C concentration in the studied sites was significantly lower than the clean area, due to the release of anthropogenic CO2. In order to estimate the Suess effect, the fossil fuel fraction was determined based on equations of mass balance for CO2 concentration, stable isotopic composition of carbon, and 14C concentration. The results showed that selected locations are affected differently according to their distance from the factory and the wind direction.

This article discusses methodological issues related to the radiocarbon dating of Khirbet Qeiyafa, mainly the question of whether the site should be dated solely according to samples retrieved there or dated as part of a regional sequence of stratigraphically based ceramic typology phases. For the latter, we deploy the large number of 14C determinations now available for several sites in the Shephelah, which are located in close proximity to each other, in order to establish a Bayesian model for the absolute chronology of the Iron I–IIA phases in the region. We argue that the information assembled from six neighboring sites in the Shephelah pushes forward the date of Qeiyafa to the 10th century, a date later than the one the excavators estimated based on the more limited 14C information from the site alone.

Ten medieval permanent teeth were subjected to incremental dentine sectioning and stable isotope analysis to investigate dietary changes in high resolution. In addition to this, eight increments were also selected for radiocarbon measurements to examine possible intra-individual age differences. Results reveal the cessation of weaning, various dietary profiles, and in some cases significantly different 14C ages obtained from a single tooth. This case study illustrates how 14C measurements can function as a proxy alongside the commonly used carbon and nitrogen stable isotope values to interpret the diet of past individuals.

Lime burials are a characteristic phenomenon of the protohistoric funerary tradition on the Balearic Islands. At Cova de Na Dent, six samples, representing the entire stratigraphy of the lime burial, were taken for analysis. The radiocarbon dates suggested that the lowest levels of the burial were Late Bronze Age. This is in contradiction with the general belief that the lime burials are a late Iron Age phenomenon. Therefore, a new analysis strategy is put forward, focusing on the so-called 1st fraction, the first CO2 released during the acid lime reaction, which is supposed to be free of fossil carbon. The analysis demonstrates the impossibility to eliminate the fossil carbon fraction completely. This is probably due to the different geological formation of the local limestone deposits (ancient reef barriers) compared to the previous lime burials of Mallorca all coming from mountain areas. 14C analysis from a cremation layer without lime at the onset of the lime burial reveals an Iron Age origin of the Cova de Na Dent lime burial.

Shellmounds are archaeological sites found across the Brazilian coast and form an important record of the human occupation of this area during the Holocene. The presence of both terrestrial and marine remains within the same archaeological context enables the comparison of different carbon reservoirs. There is only a small number of similar studies for the coast of south-southeastern Brazil. Previous work was based on the analysis of pre-bomb shells from museum collections and paired charcoal/marine shells from archaeological sites. This article assesses the potential use of terrestrial shells as representative of atmospheric carbon reservoir in the calculation of the marine reservoir effect (MRE) of the southeastern Brazilian coast. The presence of both terrestrial and marine shells over several archaeological layers represents a great potential for calculating reservoir corrections and their temporal variation.

From material culture evidence dating as early as 7500 cal BC, it has been established that populations from the interfluvic coast in northern Chile adapted to a maritime economic livelihood. During the 2nd millennium BC, local populations began to experience major social changes arising mainly from an increase in contacts with agropastoral populations from the highlands of the Andes. New radiocarbon data and stable isotope (δ15Ncol, δ13Ccol, and δ13Cap) analyses of human bone remains from interfluvic coastal individuals were obtained. The data showed that these individuals, at the time of contact with highland populations, maintained a mode of subsistence relying principally on marine protein. This suggests that, although instances of social change may have arisen, the livelihoods linked to the consumption of marine resources would have remained constant, demonstrating a high degree of resistance in changing local lifestyles.

A 15th century Russian icon from the Novgorod region was analyzed using both dendrochronological and radiocarbon methods [liquid scintillation counting (LSC) and accelerator mass spectrometry (AMS)]. This orthodox icon represents the Mother of God (Dexiokratusa). Fine art experts attribute the icon to between the late 14th to the early 15th centuries. The last complete tree ring was dated to AD 1409. There are indications that the trees were cut down during the summer of AD 1410. Taking into account the time for seasoning (about 8 months), the icon would have been painted in AD 1411. Wiggle-matching of the six AMS samples failed. Two of six AMS dates correspond to dendrochronological dates, while four of the six AMS dates showed differences with the dendrochronological dates by 5–39 yr. This discrepancy raises the issue of a possible regional offset from the calibration curve for the 13th century AD in NW Russia.

This article presents radiocarbon data for known-age, pre-bomb marine gastropods, Busycon sinistrum and Strombus alatus, collected between AD 1924 and 1946 from nearshore environments of the Florida Panhandle, on the northern Gulf of Mexico. Δ14C was measured in whole crushed juvenile specimens (n = 7) and terminal edges of adult specimens (n = 6). A subsample of adult specimens (n = 3) was subjected to additional, intrashell sampling to observe short-term variability in 14C conditions. Δ14C values were consistent within and among B. sinistrum specimens, and we propose a reservoir age offset (ΔR) of −9 ± 25 14C yr for B. sinistrum from the northwest coast of Florida. S. alatus shells exhibited significant variability from one individual to another, and also within individual specimens. ΔR values for S. alatus range from −3 ± 30 to 659 ± 30 14C yr. These differences may result from a combination of factors, including subregional variability in inputs of 14C-depleted waters and life-history factors including mobility, mode of feeding, and ontogenetic niche shifts.

California's Northern Channel Islands have long been an epicenter of specialized fishing economies dating from 13,000 yr ago to the mid-19th century. With thousands of well-preserved shell middens, some dominated by single shellfish species and little to no material culture, it can be difficult to distinguish between specialized prehistoric and historical deposits at some site types. Beginning at least in the Early Holocene and continuing into the Historic period, California mussels, turban snails, and abalone were targeted for specialized collection and processing by Native Americans and later Chinese and Euro-American fishers. Here, we demonstrate how selective accelerator mass spectrometry (AMS) radiocarbon dating of specialized abalone processing camps can help distinguish between prehistoric and historical sites. While unconventional, our case study demonstrates the utility of 14C dating at sites less than 300 yr old.

Surface-breaking ruptures on shallow crustal faults in the southern Puget Lowland in western Washington State about a millennium ago prompted abrupt changes in land level and triggered tsunamis in Puget Sound. The displacement on the Seattle fault most likely occurred in the 1050–1020 cal BP interval. Structures further south (the Tacoma and Olympia faults, and one or more faults in the southern Hood Canal zone) ruptured at about the same time, or slightly earlier. The low frequency of radiocarbon ages from archaeological sites in the region in the aftermath of the “millennial series” of earthquakes, when compared to bootstrapped samples from a database of 1255 ages from the Pacific Northwest as a whole, suggests that these very large earthquakes had significant socioeconomic consequences. The cultural record from coastal archaeological sites shows that although survivors camped on the shore in the aftermath, many coastal villages appear to have been abandoned, and were not reoccupied for several centuries. There is little evidence, however, to suggest that people migrated from southern Puget Sound to neighboring areas, and no evidence of social conflict in the adjacent areas that might have served as havens.

This article investigates variations of Δ14C and δ13C of total organic carbon (TOC) in sediments as well as in humic acids, lipid, and phospholipid fractions isolated from the surface (0–3 cm) sediment samples collected in the Curonian Lagoon and in the Baltic Sea. This study was performed to estimate relative contributions of the marine and terrestrial inputs to organic carbon in sediments, to assess a possible effect of petroleum hydrocarbon contamination on radiocarbon signatures, and to elucidate a possible leakage of chemical warfare agents (CWA) at the Gotland Deep dumpsite. Depleted Δ14C values of the TOC (down to −453‰) and of the total lipid extracts (down to −812.4‰) were detected at the CWA dumpsite. Application of the compound-specific method indicated a possible effect of CWA on depleted Δ14C and δ13C values in the investigated organic carbon fractions. The obtained results have indicated the different origin and behavior of lipids and TOC at the CWA dumpsite as compared to the area affected by the terrestrial-freshwater OC input. The Δ14C data of the TOC and total lipid extracts showed that recent sediments at the CWA dumpsite contain an excess of fossil carbon capable of influencing the 14C dating at the site.

This fourth date list for the long cultural sequence in El Mirón Cave (Cantabria, Spain) reports on 19 new AMS assays for Solutrean, Initial, Lower, and Middle Magdalenian and Azilian levels, ranging from about 19 to 11 uncalibrated kyr. Key results are provision of further precision on the transition between the Solutrean and Magdalenian at the end of the Last Glacial Maximum and the very exact dating of a Magdalenian human burial and its relationship to both major living floors and closely associated rock art in the cave.

Stable isotope ratios of carbon, nitrogen, and sulfur in human bone collagen are used routinely to aid in the reconstruction of ancient diets. Isotopic analysis of human remains from sites in the Iron Gates section of the Lower Danube Valley has led to conflicting interpretations of Mesolithic diets in this key region of southeast Europe. One view (Bonsall et al. 1997, 2004) is that diets were based mainly on riverine resources throughout the Mesolithic. A competing hypothesis (Nehlich et al. 2010) argues that Mesolithic diets were more varied with at least one Early Mesolithic site showing an emphasis on terrestrial resources, and riverine resources only becoming dominant in the Later Mesolithic. The present article revisits this issue, discussing the stable isotope data in relation to archaeozoological and radiocarbon evidence.

The Colorado Creek section of Alaska is an important paleontological site first excavated and reported on in the early 1980s and 1990s. The remains of two individual mammoths (the “Upper” and “Lower”), and elements of horse, bison, and caribou make this a unique faunal assemblage for a region in interior western Alaska, and the western edge of eastern Beringia. The mammoth remains were the only portions of the faunal assemblage radiocarbon dated in the 1980s. The Upper mammoth ages were widespread between 13,000 and 16,200 BP with the older dates being more accepted for the death of the individual. A single age on the Lower mammoth was produced at 22,880 14C yr BP. New accelerator mass spectrometry (AMS) dates generally confirm the accepted ages for the two mammoths and provide more precise ages of 16,200 ± 50 and 22,710 ± 90 14C yr BP for the Upper and Lower mammoths, respectively. AMS dates on caribou and horse are similar to ages on the Upper mammoth and show an overlap in their ecological ranges in interior western Alaska between 16,000 and 17,000 14C yr BP during the Late Glacial, similar to other areas of the state. The sole AMS date on bison produced an infinite 14C age (>43,500 14C yr BP), considerably older than the Upper and Lower mammoths’ remains, and indicates that older deposits are present at the site. A dearth of dated Quaternary paleontological specimens from western Alaska hinders our understanding of this region's paleoecology. This study enhances our conception of the geographic and chronological spread of late Pleistocene large terrestrial mammals in Alaska and Beringia.

Northeastern North America has produced an incredible number of late Pleistocene faunal remains; however, many of these were discovered and excavated prior to the development of radiocarbon dating. Moreover, many of the 14C dates that do exist for such specimens were assayed prior to the development of purified collagen extraction methods, were performed on botanical remains of unspecified association with the faunal remains, or were accepted without concerns of young-carbon contamination from museum preservatives. Here, we present a set of high-precision accelerator mass spectrometry (AMS) dates obtained on Pleistocene faunal specimens from Connecticut, New Jersey, and Pennsylvania. Our data contain both newly discovered specimens and specimens that have resided in museum collections for over a century.

Here, we reply to the attempt by Bonsall et al. (2015) to re-assess our results from the sulfur isotopic study of bone collagen from Mesolithic and Neolithic sites along the Danube in the Iron Gates Gorges area (Nehlich et al. 2010). Although we are highly interested to see our data re-assessed, we found certain misinterpretations, mistaken assumptions, and factual errors regarding our results. Therefore, we want to respond and re-assess our previous data, too. We establish for a few individuals a quantitative dietary reconstruction to demonstrate the reliability of our earlier interpretations.

Archaeological excavations in two coastal sites of Greece, Ftelia on Mykonos and Cyclops Cave on Youra, have provided suitable material (charcoal/marine mollusk shell paired samples deposited simultaneously in undisturbed anthropogenic layers) to estimate regional changes of the sea surface radiocarbon reservoir effect (ΔR) in the Aegean Sea. Moreover, pre-bomb 14C ages of marine mollusk shells of known collection date, from Piraeus and Nafplion in Greece and Smyrna in Turkey, also contributed to the marine reservoir calculation during recent years. In this article, these already published results, 10 in total, are considered and calibrated again using the latest issues of the calibration curves IntCal13 and Marine13. The same calibration data were applied to 11 more paired samples from the archaeological sites of Palamari on Skyros and Franchthi Cave in the Argolic Gulf, published here for the first time, in order to investigate the fluctuation of the reservoir ages R(t) and ΔR values in the Aegean Sea from ∼11,200 BP (∼13,000 cal BP) to present. Our data show that R(t) and ΔR values are not constant through time and may vary from 1220 ± 148 to −3 ± 53 yr and −451 ± 68 to 858 ± 154 14C yr, respectively. An attempt was also made to correlate these fluctuations with eastern Mediterranean paleo-environmental proxies and other relevant paleoceanographic data found in the literature.

Radiocarbon dates (n = 18) from three archaeological sites on Adak Island, Alaska, were analyzed to understand the marine reservoir offset. Samples of marine and terrestrial origins recovered from the same archaeological context were compiled in nine pairs. The mean ΔR value calculated for them totaled 545 ± 10 yr. This value can be regarded as a sound estimate of the marine reservoir offset in the central Aleutians.