We have reconstructed the initial activity of calcareous sediments by 1) measuring the 14C activity of recent pre-bomb-test calcareous deposits, 2) calculating the ratio of the 14C activity of the calcareous sediment to that of the adjacent coeval wood, and 3) extrapolating 14C activity of the deep lacustrine sediment layers to the surface, assuming a constant sedimentation rate. We show here that the uppermost sediment is affected by the global increase of atmospheric 14C activity due to thermonuclear bomb tests in the early 1960s. 14C activity of submerged aquatic plants showed values similar to 14C activity of DIC. Thus, organic residue of the sediment cannot be used for reliable 14C dating because of the unknown fraction of aquatic plant detritus. The initial activity, A0, obtained in a case study of the geochronology of carbonates in the Plitvice Lakes area, ranged from 70.5 to 72.2 pMC for Lake Prošće sediment, and from 75.9 to 76.7 pMC for Lake Kozjak sediment. These values also agree with calculated values based on the downstream increase of 14C activity of DIC in freshwater open to the atmosphere.

The use of accelerator mass spectrometry (AMS) for age determinations of paintings is growing due to decreasing sample size requirements. However, as only the support material is usually dated, the validity of the results may be questioned. This work describes a novel sampling and preparation technique for dating the natural organic binder using radiocarbon (14C) AMS. In the particular case of oil paintings, the natural oil used has a high probability of being representative of the time of creation, hereby circumventing the problem of the originality of the support material. A multi-technique approach was developed for a detailed characterization of all paint components to identify the binder type as well as pigments and additives present in the sample. The technique was showcased on a painting of the 20th century. The results by 14C AMS dating show that both the canvas and binding medium predate the signed date by 4–5 yr. This could be the time span for keeping painting material in the atelier. The method developed provides, especially given the low amounts of material needed for analysis, a superior precision and accuracy in dating and has potential to become a standard method for oil painting dating.

The dates given have been obtained during the year 1959. They have been made with carbon dioxide at 2 atmospheres pressure in a proportional gas-counter, as for the series given in Radiocarbon Supplement, volume 1.

Measurement of 14C in samples of wood of precisely known age have shown that the cosmogenic 14C content of the CO2 in the atmosphere has not remained constant during the period of time covered by radiocarbon dating. As the terrestrial atmosphere mixes with a time constant of less than 3 years, these variations must be essentially independent of geographic location. The 14C in atmospheric CO2 must be a quantity that, at a given time, pertains to the terrestrial atmosphere as a whole. Not only is its knowledge necessary for deriving accurate radiocarbon dates, but it is also valuable in connection with many geophysical and astrophysical problems. Unfortunately, progress in our knowledge of 14C variations in the terrestrial atmosphere has been delayed by hidden experimental errors in results obtained by many laboratories. By rigorous statistical analysis of the La Jolla results, it is now possible to show that the 14C variations are not simple random fluctuations but show distinct regularities. Similar patterns of variations have been found in the growth rate of trees during the last 5000 years. Measurements of radiogenic 10Be currently being done by European workers promise to conclusively elucidate the 14C findings.

A comparison of radiocarbon histograms of samples controlled and uncontrolled for sample provenance and composition factors indicates that differences are sufficiently large to influence the discrimination of alternative hypotheses on the age of the important, early Bellows Dune site in Hawai'i.

The adoption of a new funerary ritual with all its social and cognitive meanings is of great importance to understanding social transformations of past societies. The first known occurrence of cremation in the territory corresponding to modern Belgium dates back to the Mesolithic period. From the end of the Neolithic onward, the practice of cremation was characterized by periods in which this rite was predominant and periods of contractions, defined by a decrease in the use of this funerary ritual. This paper aims to quantify such phenomenon for the first time by modeling discontinuities in burial practices through kernel density analysis of 1428 radiocarbon (14C) dates from 311 archaeological sites located in Belgium from the Mesolithic to the Middle Ages. Despite possible taphonomic and sampling biases, the results highlight the existence of periods with a large uptake of cremation rite followed by periods of contractions; such discontinuities took place in correlation with changes in the socio-economical structure of local communities, as, for example, during the later Middle Bronze Age and at the end of the Roman Period.

This paper reports the results from applying the Cryo2SoniC (Cryobreaking, Sonication, Centrifugation) protocol to some lime mortars sampled from the citadel of Shayzar (Syria). The overall aims of this project are 1) to use the properties offered by high-precision accelerator mass spectrometry (AMS) radiocarbon dating for the evaluation of absolute chronology with its typical robust time constraints (i.e. 25 14C yr), and 2) to apply the dating directly to the citadel structures in order to prevent possible biasing effects potentially affecting indirect 14C dating on organic materials found at the study site. The analyses presented in this paper have been mainly performed as a preliminary check of the Cryo2SoniC methodology in order to assess its applicability to this study site by comparing observed mortar results with archaeological expectations about the citadel development phasing and charcoals found encased in mortars. Petrographic and mineralogical thin-section analyses by optical microscopy (TSOM), X-ray powder diffraction (XRD), and scanning electron microscopy plus energy dispersive spectroscopy (SEM/EDS) investigations were carried out for characterization of the mortar samples to verify the occurrence of some features, related to their production technology, which may introduce dating offsets. The resulting 14C calibrated ages were in agreement with the archaeological expectations based on type and stratigraphic site reconstructions, in situ inscriptions, and written sources. Such results showed also a general (with 1 exception) statistical agreement among the charcoals and the analyzed mortars simultaneously, confirming the archaeological expectations for the Shayzar citadel. Results presented in this paper indicate good accuracy for the applied procedure for chronology reconstruction and highlight the capability of Cryo2SoniC to further characterize the Shayzar site.

This date list covers most of the datings done during the period January 1960 to December 1961.

Over the last few decades, radiocarbon laboratories have used different procedures for measuring a broad range of carbonaceous materials. To produce reliable results, the processes employed for sample processing, graphite target production, and spectrometer measurement must be rigorous, well tested, and reproducible. Most of the procedures have been developed, improved, and published as part of the laboratories’ quality control and research programs, and can be frequently found in the literature. Nevertheless, there are suites of laboratory techniques (or “small useful skills”), products, and other resources that either have never been described in publications, or have been somewhat hidden in much larger scientific articles and reports. We feel that with the rapid rise of newer laboratories and facilities, a set of resourceful suggestions might come in handy. Here we gathered these skill sets that can be used in all aspects of 14C sample processing, with the intention to simplify and expedite procedures, from glass-tube making to graphitization and measurements. We also included some miscellaneous items to help in laboratory setup.

Radiocarbon dating is widely used when studying recent volcanic activity in the Kamchatka Peninsula due to the abundance of organic matter that is associated with the volcanic deposits. Here, we present the results of 14C dating of major volcanic events within the active South Kamchatka volcanic zone. South Kamchatka includes 8 recently active volcanic centers (stratovolcanoes, calderas, and large craters) that have been erupting during the Holocene. Their tephras represent useful markers for both the southern part of the peninsula and the Northern Kurile Islands. Since these marker tephra layers facilitate stratigraphic and tephrochronological studies in this area, it was important to determine their ages. We have obtained 73 new individual 14C dates on paleosol, peat, charcoal, and wood associated with the marker tephra layers, then complemented these data with 37 earlier published dates and analyzed the resulting data set. We selected the reliable dates and then obtained average 14C ages of marker tephra layers. The details of these procedures, as well as brief descriptions of South Kamchatka Holocene eruptions and their tephra beds, are presented in the paper.

This date list covers age measurements carried out at the Radiocarbon Dating Laboratory of the German Academy of Sciences of Berlin (DAW) since 1963 and is a continuation of our first date list (Berlin I). Procedures and methods of preparing the samples are essentially the same. We completed our laboratory with a second electronic counting apparatus. Two further proportional counters with internal anticoincidence (Houtermann-Oeschger counters) are made from an old railway-car axle. The total volume of these counters is 4 L, the effective volume 2.2 L, the background 2.0 counts/min at 700 Torr (acetylene filling), and the contemporary standard value (0.95 NBS oxalic acid) is 20 counts/min. Each sample is measured twice, first for 48 hr and after 8 days for another 24 hr. Data have been calculated on the basis of a C14 half-life of 5570 yr (Godwin, 1962). Errors listed include the standard deviations (1σ) of the counting rates of the contemporary samples, the background and the unknown samples. Calculated errors less than 100 yr have been increased to that figure as a minimum.

Corrections have not been made for C13 content. Mass spectrometrics C13 measurements of some samples indicate that errors resulting from fractionation are minimal.

The following list consists of dates for archaeologic and geologic samples mostly measured over the period from January 1980 to June 1981. The dates were obtained by liquid scintillation counting of benzene using the laboratory procedures outlined in previous lists (see, eg, BM VIII, R, 1976, v 18, p 16).

We report the first attempt to date Icelandic groundwater by the radiocarbon dating technique. We propose that boron concentrations of the water samples can be taken as a measure of the amount of dead CO2 in the groundwater leached from rock. By assuming that the ratio of boron to CO2 is the same in the rock and groundwater it is possible to correct the 14C concentration for the contribution of rock-derived carbon in the groundwater and thus calculate the initial (undiluted) 14C concentration. When this correction is applied, the values for the cold and warm waters lie in the range 60 to 110 pMC, which is in accordance with the estimated residence time for the groundwater. We have also calculated the fractions of atmospheric and organic carbon in the water, based on the δ13C measurements, and the results agree well with the general hydrology and vegetational cover of the areas. Results from geothermal systems indicate that it is possible to use 14C to estimate relative age differences of the water in a particular geothermal area.

In 2008, the atmospheric CO2 measurements at the Hegyhátsál rural tower station were extended further by 14CO2 air sampling from two elevations (115 and 10 m a.g.l.), in cooperation with HEKAL (ICER). Since then, a complete six-year-long (2008–2014) dataset of atmospheric CO2, Δ14C, fossil, and modern CO2 excess (relative to Jungfraujoch) has been assembled and evaluated. Based on our results, the annual mean CO2 mole fraction rose at both elevations in this period. The annual mean Δ14CO2 values decreased with a similar average annual decline. Based on our comparison, planetary boundary layer height obtained by modeling has a larger influence on the variation of mole fraction of CO2 (relative to Jungfraujoch), than on its carbon isotopic composition, i.e. the boundary layer rather represents a physical constraint. Fossil fuel CO2 excess at both elevations can rather be observed in wintertime and mainly due to the increased anthropogenic emission of nearby cities in the region. The mean modern CO2 excess at both elevations was even larger in winter, but it drastically decreased at 115 m by summer, while it remained at the winter level at 10 m.

The following list consists of dates of archaeological samples, obtained by gas-proportional counting of ethane, between 1985 and the end of 1991. During this time a close cooperation has been established with the Israel Antiquities Authority, which now has an archaeologist (D.S.) participating in the operation of the lab and serving as a liaison officer with the archaeological community.

Owing to the large basin area of the Caspian Sea, fluctuations in its level reflect climatic changes in the northern hemisphere. To reconstruct these fluctuations, I collected mollusk shells, plant debris, carbonates and organic matter samples for 14C dating from deposits of ancient salt marshes, depressions and bars formed during significant sea-level decline. I studied the impact of eolian sedimentation via parallel dating of carbonates and other materials. The data demonstrate that sea level rises during periods of cooling and falls during warming periods; this is true for both long-term (2–2.5 ka) and short-term climatic changes.

Continuous 14C data of 1 or 2 weekly samples of atmospheric CO2 are presented, collected near two nuclear power plants (NPP-Biblis and NPP-Philippsburg) located in the rather densely populated upper Rhine valley. Tree-leaf and tree-ring samples from the area of a boiling water reactor in northern Germany (NPP-Würgassen) are also presented and discussed. Additional atmospheric 14CO2 samples from two continental ‘clean-air’ stations in Germany and Austria were used as reference for the polluted areas. For January 1982, these samples yield a ‘clean-air’ 14C concentration in central Europe of Δ14C=255±5‰ (7.7pCi/gC = 1.45pCi/m3 air).

Human and animal bone collagen from different Steppe Bronze Age cultures, including the Yamnaya, East Manych Catacomb, and Lola cultures, show large variations in δ13C and δ15N values. More positive values of δ13C and δ15N are caused by change in diet and/or a more arid climate. Human bones show reservoir effects caused by aquatic diet components. These effects can be quantified by paired dating of human bone and associated terrestrial samples. Previous research showed reservoir corrections for several cultures of the Eurasian steppes Bronze Age, leading to a revision of the local chronologies. Additional investigations showed that some paired dates do not reveal reservoir effects. Recently, our database was extended significantly with new 13C, l5N, and 14C analyses of the Lola, Krivaya, and Babino cultures. The size of the reservoir offset for the studied cultures is discussed.

Sherds can be dated by four independent methods: 14C beta counting on associated material, accelerator mass spectrometry on carbon traces on and within the sherd, thermoluminescence studies on minerals within the sherd, and stylistic form. Age analyses of materials and sherds from several sites are shown in this work. Each technique has its own frequently encountered non-laboratory sources of error. A combination of at least two independent techniques is indispensable for the highest level of confidence.

Eleven samples of aquatic plants from three Estonian lakes were analyzed for their radiocarbon content in a collaboration between the laboratories in Tallinn and Uppsala. δ13C values for the actual species were compiled to allow normalization of activities measured in Tallinn without δ13C values. The range for well determined species is usually a few per mil and the statistical uncertainty ≥1‰. δ13C values vary considerably for different Potamogéton species and Myriophýllum spp. Lake Äntu Sinijärv and Lake Päidre are hard-water lakes containing 300 and 200 mg HCO3–/L, respectively. One sample consisted of a carbonate crust deposited on a Ceratophýllum demersum plant in L. Äntu Sinijärv. Its Δ14C value was −147.3 ± 6.7‰ in 1990, whereas the plant had a value of −74.1 ± 8.0‰ (δ13C = −35.0‰). The same species in L. Päidre had a Δ14C value of +8.0 ± 8.8‰ (δ13C = −25.2‰) in 1992. Other species in L. Päidre contained more 14C, from a Δ14C value of about +30‰ to about +155‰, the latter value measured in Tallinn on floating leaves of Nuphar lútea, close to that of the contemporaneous atmospheric CO2. In the third lake, Lake Punso, containing ≤30 mg HCO3–/L, the stems of Nuphar lútea exhibited in 1990 a memory effect: the activity, Δ14C = 209.6 ± 10.3‰, significantly exceeded that of the contemporaneous atmospheric CO2. However, the floating leaves of the same plant had the Δ14C value 143.1 ± 10.0‰, close to the atmospheric 14C level in 1990. The memory is explained by nutrients stored in the root stock, used when the growth starts.