The measurements reported in this list have been made in the Isotope Laboratory at the Institute of Geophysics, UCLA during 1962. Dates have been calculated on the C14 half life of 5568 years and using 95% NBS oxalic acid as modern standard, in agreement with the decision of the Fifth Radiocarbon Dating Conference (Godwin, 1962).

The curves recommended for calibrating radiocarbon (14C) dates into absolute dates have been updated. For calibrating atmospheric samples from the Northern Hemisphere, the new curve is called IntCal20. This is accompanied by associated curves SHCal20 for the Southern Hemisphere, and Marine20 for marine samples. In this “companion article” we discuss advances and developments that have led to improvements in the updated curves and highlight some issues of relevance for the general readership. In particular the dendrochronological based part of the curve has seen a significant increase in data, with single-year resolution for certain time ranges, extending back to 13,910 calBP. Beyond the tree rings, the new curve is based upon an updated combination of marine corals, speleothems, macrofossils, and varved sediments and now reaches back to 55,000 calBP. Alongside these data advances, we have developed a new, bespoke statistical curve construction methodology to allow better incorporation of the diverse constituent records and produce a more robust curve with uncertainties. Combined, these data and methodological advances offer the potential for significant new insight into our past. We discuss some implications for the user, such as the dating of the Santorini eruption and also some consequences of the new curve for Paleolithic archaeology.

Ultrafiltration of bone collagen, dissolved as gelatin (M ~100,000 D), has received considerable attention as a means to remove small contaminants and thus produce more reliable dates (Brown et al. 1988; Bronk Ramsey et al. 2004; Higham et al. 2006; Mellars 2006). However, comparative dating studies have raised the question whether this cleaning step itself may introduce contamination with carbon from the filters used (Bronk Ramsey et al. 2004; Brock et al. 2007; Hüls et al. 2007).

Here, we present results of further ultrafiltration experiments with modern and fossil collagen samples using Vivaspin 20™ and Vivaspin 15R™ ultrafilters. Evidently, the Vivaspin 20 (VS 20) ultrafilter with a polyethersulfone (PES) membrane retains more material in the >30 kD fraction than the Vivaspin 15R (VS 15R) filter with a regenerated cellulose membrane (Hydrosat), which may be related to increased retention of proteins due to suboptimal electrostatic conditions during ultrafiltration with the PES membrane. In addition, this filter type shows clear evidence for contamination with fossil carbon, presumably from membrane fibers, in the <30 kD fraction. Radiocarbon measurements on ultrafiltrated fossil collagen seem to indicate small contributions of modern carbon via glycerin left on and within the filter membranes of both types. Although SEM pictures show film remnants on the fibrous filter structure of cleaned filter membranes, EDX analysis on the VS 20 membrane to not support the assumption this may be glycerin. Our observations indicate the risks and benefits of the use of ultrafiltration in cleaning collagen samples for 14C dating need to be further quantified, especially for the cleaning of fossil bone collagen of good quality samples.

The cosmogenic radionuclide 10Be is produced by cosmic-ray spallation in Earth's atmosphere. Its production rate is regulated by the geomagnetic field intensity, so that its accumulation rate in aeolian sediments can, in principle, be used to derive high-resolution records of geomagnetic field changes. However, 10Be atmospheric fallout rate also varies locally depending on rainfall rate. The accumulation rate of 10Be in sediments is further complicated by overprinting of the geomagnetic and precipitation signals by 10Be attached to remobilized dust, which fell from the atmosphere at some time in the past. Here, we demonstrate that these signals can be deconvoluted to derive both geomagnetic field intensity and paleoprecipitation records of Asian Monsoon intensity in an 80,000-yr-long 10Be record from Chinese loess. The strong similarity between our derived paleomagnetic intensity record and the SINT 200 (Guyodo and Valet 1996) and NAPIS 75 (Laj et al. 2002) stacked-marine records suggests that this method might be used to produce multimillion-yr-long records of paleomagnetic intensity from loess. This technique also reveals a new method for extracting quantitative paleoprecipitation records from continental interior regions. Our derived precipitation record is broadly similar to the speleothem δ18O-based records of paleo-Asian Monsoon intensity from Dongge (Yuan et al. 2004) and Hulu (Wang et al. 2001) caves, and suggests that the paleo-Asian Monsoon intensity may be responding to a combination of both Northern and Southern Hemisphere insolation forcing.

We review developments in radiocarbon measuring techniques from the Libby counter through proportional gas counters and liquid scintillation spectrometers to the more recent developments of accelerator mass spectrometry (AMS), followed by a coupling of gas chromatography with AMS for compound-specific 14C analyses. While during the first 60 yr of 14C measurements beta counting, specifically gas counting, was the dominant technique, in the future of 14C science AMS will be the dominant technology.

The eruption of the volcano at Thera (Santorini) in the Aegean Sea undoubtedly had a profound influence on the civilizations of the surrounding region. The date of the eruption has been a subject of much controversy because it must be linked into the established and intricate archaeological phasings of both the prehistoric Aegean and the wider east Mediterranean. Radiocarbon dating of material from the volcanic destruction layer itself can provide some evidence for the date of the eruption, but because of the shape of the calibration curve for the relevant period, the value of such dates relies on there being no biases in the data sets. However, by dating the material from phases earlier and later than the eruption, some of the problems of the calibration data set can be circumvented and the chronology for the region can be resolved with more certainty.

In this paper, we draw together the evidence we have accumulated so far, including new data on the destruction layer itself and for the preceding cultural horizon at Thera, and from associated layers at Miletos in western Turkey. Using Bayesian models to synthesize the data and to identify outliers, we conclude from the most reliable 14C evidence (and using the INTCAL98 calibration data set) that the eruption of Thera occurred between 1663 and 1599 BC.

Twenty paired 14C and U/Th dates covering most of the past 50,000 yr have been obtained on a stalagmite from the Cango Caves in South Africa as well as some additional age-pairs on two stalagmites from Tasmania that partially fill a gap between 7 ka and 17 ka ago. After allowance is made for the initial apparent 14C ages, the age-pairs between 7 ka and 20 ka show satisfactory agreement with the coral data of Bard et al. (1990, 1993). The results for the Cango stalagmite between 25 ka and 50 ka show the 14C dates to be substantially younger than the U/Th dates except at 49 ka and 29 ka, where near correspondence occurs. The discrepancies may be explained by variations in 14C production caused by changes in the magnetic dipole field of the Earth. A tentative calibration curve for this period is offered.

We compare radiocarbon accelerator mass spectrometry (AMS) ages of wood samples subjected to a conventional acid-base-acid pretreatment with stepped combustion (ABA-SC) with results from the same samples subjected to an acid-base-wet oxidation pretreatment with stepped combustion (ABOX-SC) and cellulose extraction with stepped combustion (CE-SC). The ABOX-SC procedure has been shown previously to lead to lower backgrounds for old charcoal samples. Analyses of relatively uncontaminated “14C-dead” samples of wood suggest that backgrounds of 0.11 ± 0.04 pMC are obtainable for both the ABOX-SC and ABA-SC procedures. Where wood is significantly contaminated the ABOX-SC technique provides significantly better decontamination than either the ABA-SC technique or cellulose extraction alone, although CE-SC can produce comparably low backgrounds to the ABOX-SC procedure.

We also report the application of the ABOX-SC, ABA-SC and CE-SC procedures to wood samples associated with the chronologically controversial Rotoehu Ash eruption, New Zealand. New 14C-AMS dates from wood sampled from below the Rotoehu Ash span an age range of 43–50 ka BP consistent with recently presented OSL dates of 42–44 ka obtained for palaeosols beneath the ash.

We measured apparent radiocarbon ages of live-collected, pre-bomb mollusk shells from the northern and central Gulf of California to determine the source of the reservoir ages and the reservoir age correction offsets for calibrating 14C dates of fossil samples. Reservoir ages average 860 yr in the northern Gulf and 725 yr in the central Gulf. The corresponding ∆R values (the deviation from typical worldwide values) are 540 yr and 395 yr, respectively, with variabilities (SD) of 90 and 110 yr. This variability significantly limits the precision of calibrated 14C ages. The apparent 14C age of Colorado River water (as measured in a freshwater mussel, collected in the 1890s, before diversion of river flow) is not sufficiently high (1420 yr) to account for the high reservoir ages in the Gulf. The lack of a relation between the stable isotope composition of Gulf mollusks and their reservoir ages is further evidence that the Colorado River does not make a significant contribution to Gulf reservoir ages. Upwelling of old, deep Pacific-derived water appears to be the cause of the large reservoir ages.

Radiocarbon ages were measured on replicate samples of burnt grain and 5 mollusk species collected from a single sealed layer at an archaeological site (Hornish Point) on the west coast of South Uist, Scotland. The aim was to examine the impact of using different mollusk species on ΔR determinations that are calculated using the paired terrestrial/marine sample approach. The mollusk species examined inhabit a range of environments and utilize a variety of food sources within the intertidal zone. Several authors have suggested that these factors may be responsible for observed variations in the 14C activity of mollusk shells that were contemporaneous in a single location. This study found no significant variation in the 14C ages of the mollusk species, and consequently, no significant variation in calculated values of ΔR. The implication is that in an area where there are no carboniferous rocks or significant local inputs of freshwater to the surface ocean, any of a range of marine mollusk species can be used in combination with short-lived terrestrial material from the same secure archaeological context to accurately determine a ΔR value for a particular geographic location and period in time.

Faunal remains originating from terrestrial and marine mammals, and belonging to the same archaeological deposits were compared to evaluate the marine radiocarbon reservoir ages around the Hokkaido island, Japan. From five shell middens of different ages from the Jomon period (4900 BP) to the Ainu cultural period (800 BP), 107 animal bone samples were selected for radiocarbon measurements. The apparent age differences between Japanese deer and northern fur seal showed the clear effect of deep-water upwelling in this region. Our data showed relatively stable age differences from 4500 BP to 800 BP, with an estimated ΔR values around 380 14C yr. Results are consistent with previous estimation based on simulation models and oceanographic properties.

Dissolved inorganic carbon (DIC) is the main acid buffer in forested lake watersheds in Canada. We used carbon isotopes (13C, 14C) to evaluate the production and cycling of DIC in an acid-sensitive lake watershed of the Precambrian Shield. Soil CO2, groundwater and stream DIC were characterized chemically and isotopically. Soil CO2 concentration profiles reflect both changes in production and in losses due to diffusion. δ13C soil CO2 profiles (δ13C values of −23‰ in summer, slightly enriched during the fall and −25%‰ during the winter) are a reflection of the isotopic composition of the sources and changes in isotopic fractionation due to diffusion. Carbon isotopic composition (13C, 14C) of the groundwater and stream DIC clearly indicate that weathering of silicates by soil CO2 is the main source of DIC in these watersheds. 14C data show that, in addition to recent groundwater, an older groundwater component with depleted 14C activity is also present in the bedrock. The carbon isotope pattern in the groundwater also implies that, besides the main springtime recharge events, contributions to the groundwater may also occur during late winter/early spring.

A computer program for convenient calibration of radiocarbon dates has been developed. The program has a simple user interface, which includes pull-down menus, windows and mouse support. All important information, such as calibration curves, probability density function and results, in text form, are displayed on the screen and easily can be rearranged by the user. Two versions of CalibETH, one for an IBM-PC and one for the Macintosh, are available. CalibETH runs under the graphics interface, GEM, from Digital Research, on an IBM PC.

Dating pollen concentrated from eolian sediments provides a new way to establish a chronological framework on the Loess Plateau of China. We show that pollen deposited simultaneously with sediment in a stable environment can provide reliable ages. We suggest that the reliability of pollen dating can be evaluated by comparison with wood cellulose or charcoal ages from the same stratigraphic level. Dating pollen concentrates from the various profiles indicates paleomonsoon precipitation variability at the loess/desert transitional belt from the late Pleistocene to the early Holocene.

Most of the 14C measurements reported here were made between October 1972 and October 1973. Equipment, measurement, and treatment of samples are the same as reported previously (R, 1968, v 10, p 36–37; 1970, v 12, p 534).

The routine processing and measurement of samples in our Radiocarbon Laboratory began early in 1970 following a one-year testing period during which standard samples (anthracite and NBS oxalic acid) as well as samples of known age were prepared and measured. Our system is based on the studies of de Vries and Barendsen (1953), Fairhall et al. (1961) and Olson and Nickoloff (1965). However, several modifications of the cited methods were introduced and are briefly discussed below. A detailed description of the whole system will be published elsewhere (Srdoč et al., 1970).

We have developed a master δ13C chronology from 14 pinyon pine sites in 6 states of the southwestern U S. Two of the individual isotopic chronologies, reported here for the first time, and 10 of those previously reported (Leavitt & Long, 1986; 1988) are from sites where cores from 4 trees were pooled prior to analysis, and the other 2 are merged from groups of 4 single-tree chronologies (sites) developed in an earlier phase of research (Leavitt & Long, 1985). Regressions of first differences of ring-width indices and δ13C values from each site were used to “correct” individual δ13C chronologies for climate effects which appear primarily related to high-frequency δ13C fluctuations, many of which are common among sites. These climate-corrected chronologies were normalized as deviations from their respective 1800–1849 δ13C means, and these normalized chronologies were averaged into the master. The overall δ13C drop from 1600 to the present is ca 1.2–1.4, consistent with recent ice-core data showing a drop of 1.14 ± 0.15% from 1740 to present (Friedli et al, 1986). However, the δ13C decline in the late 19th and early 20th centuries is greater in the pinyon chronology than that of the ice cores, thus supporting a greater biospheric CO2 input to the atmosphere than that indicated in the ice-core data.

This date list includes samples and sample series finished between January and November 1962. It does not include samples from series not yet been completed, or samples of very limited scientific interest.

Reservoir age offsets are widely used to correct marine and speleothem radiocarbon age measurements for various calibration purposes. They also serve as a powerful tracer for carbon cycle dynamics. However, a clear terminology regarding reservoir age offsets is lacking, sometimes leading to miscalculations. This note seeks to provide consistent conventions for reporting reservoir 14C disequilibria useful to a broad range of environmental sciences. This contribution introduces the F14R and δ14R metrics to express the relative 14C disequilibrium between two contemporaneous reservoirs and the R metric as the associated reservoir age offset.

We present ΔA14C and 39Ar data collected in the Nansen, Amundsen and Makarov basins during two expeditions to the central Arctic Ocean (RV Polarstern cruises ARK IV/3, 1987 and ARK VIII/3, 1991). The data are used, together with published Δ14C values, to describe the distribution of Δ14C in all major basins of the Arctic Ocean (Nansen, Amundsen, Makarov and Canada Basins), as well as the 39Ar distribution in the Nansen Basin and the deep waters of the Amundsen and Makarov Basins. From the combined Δ14C and 39Ar distributions, we derive information on the mean “isolation ages” of the deep and bottom waters of the Arctic Ocean. The data point toward mean ages of the bottom waters in the Eurasian Basin (Nansen and Amundsen Basins) of ca. 250-300 yr. The deep waters of the Amundsen Basin show slightly higher 3H concentrations than those in the Nansen Basin, indicating the addition of a higher fraction of water that has been at the sea surface during the past few decades. Correction for the bomb 14C added to the deep waters along with bomb 3H yields isolation ages for the bulk of the deep and bottom waters of the Amundsen Basin similar to those estimated for the Nansen Basin. This finding agrees well with the 39Ar data. Deep and bottom waters in the Canadian Basin (Makarov and Canada Basins) are very homogeneous, with an isolation age of ca. 450 yr. Δ14C and 39Ar data and a simple inverse model treating the Canadian Basin Deep Water (CBDW) as one well-mixed reservoir renewed by a mixture of Atlantic Water (29%), Eurasian Basin Deep Water (69%) and brine-enriched shelf water (2%) yield a mean residence time of CBDW of ca. 300 yr.