The article presents the results of the absolute dating of 31 pre-Columbian funerary bundles excavated on the Cerro Colorado site located in the northern part of the Peruvian Central Coast, where the Chancay culture developed in the last centuries before the Spanish invasion. The typical custom in this region was to wrap the dead with textiles and a vegetal material, by which the bundle was created. The funerary bundles of the Cerro Colorado differed in terms of the complexity, quantity and quality of the materials used (especially textiles and metal ornament). Before our project, there was not a single radiocarbon (14C) date for an undisturbed Chancay tomb, which made it impossible to understand the temporal dependency between the elaborated, standard, and modest bundles. Our results finally shed light on their proper chronological position, also demonstrating that the most elaborate bundles were created between the 13th and 15th centuries.

The 14C age of charcoal and wood from Lebanon and central Europe is compared partly with the dendrochronologically determined age of the samples and partly with the archaeologically expected value. While the dendrologic values approximately confirm the correction curve of Ralph, Michael, and Han (1973), charcoal of burned layers seemes to be generally 2 to 3 centuries older than expected from contemporary archaeologically retrieved materials.

In his comment, “The Patterns of Neolithization in the North Eurasian Forest Zone: A Comment on Hartz et al. (2012),” Y Kuzmin has raised a number of questions concerning the paper “Hunter-Gatherer Pottery and Charred Residue Dating: New Results on Early Ceramics in the North Eurasian Forest Zone” by Hartz et al. (2012). The following remarks aim to clarify some of these issues.

Plasma oxidation for 14C sampling utilizes low-pressure (133 Pa), low-energy (<50 W), and low- temperature (<50°C) Ar- and O2-plasmas generating CO2 for AMS dating. O2-plasmas on empty chambers remove organic contamination. When clean, a new specimen is inserted and Ar-plasmas dislodge adsorbed atmospheric CO2 from surfaces. Finally, O2-plasmas oxidize organic materials to CO2 for AMS analysis. During some Ar-plasmas we observed anomalous pressure increases and unexpectedly high CO2. Residual gas analysis detected water, hydrogen and oxygen species with Ar and CO2 indicating water plasmas that produced excited oxygen species that prematurely oxidized specimen organic matter. Evolution of excess CO2 during Ar cleaning compromises the ability to affirm that atmospheric CO2 was removed. Standards, TIRI Belfast Pine and VIRI I Whalebone, were dated to determine whether water-induced oxidation was a confounding influence in dating. TIRI wood was sampled twice, once a water-soaked specimen in an Ar plasma and once with water-vapor-plasma only. The TIRI dates agreed with six earlier dates on usual specimens. A colloidal extract from VIRI I whale bone was also sampled and dated twice using both water–plasma oxidation in an Ar-plasma and in an O2-plasma. Dating agreement suggests that water plasmas do not pose undue risks of contamination.

Using liquid scintillation counting (LSC) and accelerator mass spectrometry (AMS), radiocarbon concentrations were measured for wine from 8 wineries located in 7 countries in the Northern and Southern hemispheres. The 14C concentrations of ethanol and residual materials in the wine were correlated (correlation coefficient 0.82). The δ14C measurements of wine samples from the mid-latitudes in the Northern Hemisphere were approximately 1l% lower than the extrapolations from Schauinsland data, suggesting a local fossil fuel effect. δ14C measurements from the wine samples from the Southern Hemisphere were higher than those from the Northern Hemisphere. The offsets of the 4 wine δ14C measurements were significant, with values between approximately 8% and 15%. Because the harvest years of the mixed grapes were estimated to be 7–12 yr older than their vintage years, this leads to a caveat when determining the 14C concentrations of the year using the wine vintage.

In 2015 a dispute arose between an electricity company (EC) and smallholder of a teak plantation when the EC felled 80 trees (without consent of the owner) in a linear transect under a rural power-line-corridor (PLC), fragmenting the teak stand in two portions. The EC stated that there were no planted trees in the area when the PLC was established in 2008. The owner asserted he planted the stand in 2006 so in 2008 the company should have seen the planted trees. We used the bomb radiocarbon (14C) signal of three felled trees and dendrochronological dating of five trees, three felled by the EC and two felled by us in 2016, to do this study to determine the age. We found that the first growth rings were dated to 2005 both in the trees felled by the EC in 2015 and felled by us in 2016, one year before that reported by the owner (2006). This year corresponds to the wood present in the cuttings during the stand’s planting year. These facts are in agreement with the owner’s testimony. The plantation was 10 years old in 2015.

Accelerator systems designed for a wide variety of ion beam analysis (IBA) applications usually have a multitude of beamline components and long beam lines. In the use of these systems, beam optimization is especially important for attaining high-precision accelerator mass spectrometry (AMS) results. The optimization involves multiple parameters, dependencies between parameters, and multiple optimization targets. To improve the repeatability and reliability of AMS results, we have developed a profiling program for automatic beam optimization. In our implementation, the accelerator control parameters, measured beam currents, and AMS detector count rates are all stored in a real-time database. The profiling routine can scan any accelerator parameter and fetch from the database the profile of any measured quantity as a function of the parameter. The routine is usually used to scan over roughly 20 essential parameters of the system and setting them to the optimum values. Automatic optimization is fast, easy to use, robust to noise, and gives reproducible results. In addition, the graphical output in the form of current and count rate profiles is highly informative. Automatic optimization together with other improvements to the AMS setup have enabled us to push the precision of the system to better than 0.2%.

The relic “the sack of Saint Francesco” has for the first time been investigated by scientific means. The sack is kept at the Franciscan Friary of Folloni near Montella in southern Italy. According to legend, the sack appeared on the doorstep of the Friary in the winter of 1224 containing bread sent from St Francesco (St Francis of Assisi), who at that time was in France. The bread was allegedly brought to the friary by an angel. We analyzed samples of the sack to obtain a radiocarbon (14C) date and to search for any remaining traces of bread. The 14C date yielded a calibrated age range of AD 1220–1295 (2σ), which places the textile in the right timeframe according to the legend. Chemical analysis by gas-chromatography with mass spectrometric detection (GC-MS) revealed the presence of ergosterol (5, 7, 22-ergostatrien-3b-ol), a known biomarker of brewing, baking, or agriculture. In this paper we have further substantiated the validity of ergosterol as a biomarker for the past presence of bread. It appears that there is a fine correspondence between the Franciscan legend and the two most decisive scientific methods relevant for analyzing the sack. Although it is not proof, our analysis shows that the sack indeed could be authentic.

This paper presents radiocarbon (14C) dating of Scythian period sites discovered in Northern Altai, Russia, in the 1990s, including large, unlooted barrow cemeteries in the Manzherok region. The results indicate that barrows attributed to the Karakoba culture may represent a long time span from the beginning of the 9th century BC until the beginning of 1st century BC, while those linked with the North Pazyryk culture generally keep within the Scythian period: from the beginning of the 5th century BC to the late 1st century AD. 14C analysis has confirmed the viability of traditional archaeological dating and the contemporaneity of barrows belonging to various cultural traditions (North Pazyryk, Karakoba), and also allowed correlating the horizons of burials to the seismic phenomena observed at the site.

Radiocarbon has been applied as a tracer to study carbon dynamics in different types of tropical soils, under paddy and non-paddy management on Java, Indonesia. The 14C concentrations were measured in samples of total organic carbon as well as in alkali-soluble humic acids, insoluble humin, and plant remains (roots, seeds, leaves) obtained from three sites with Andosols, Alisols, and Vertisols at different altitudes. In addition, the abundance and distribution of plant macrofossils in the soil column and organic δ13C values were determined. The results obtained so far are compared with those from a chronosequence of Cambisols in China. They indicate the input of fresh plant materials into the subsoil directly via roots and/or by soil cracks and bioturbation of aboveground litter. The total organic C and 14C concentrations show the usual decrease with increasing depth in paddy and non-paddy soils, reflecting the influence of direct input as well as the downward redistribution of organic material as particulates or dissolved organic carbon (DOC) depending on soil type (pedogenesis, plough-pan formation, drying cracks), crop type and management, and climatic factors. A disturbance of the Andosol around 0.4 m depth and a change in profile properties around 0.63 m in the Alisol limit the general conclusions.

In 1981, the first 14C and Archaeology Symposium was organized because it was felt necessary to have a symposium that focused on the specific problems related to the use of 14C dating in archaeology. The dating method has been constantly changing and approving itself technically as well as in the application of the method. The relationship between the archaeologists and the 14C dating laboratories has, however, never been straightforward. For a lot of 14C laboratories, archaeology was not their core business. For archaeologists, the main problem arose from an insufficient knowledge of natural sciences. The last decennia, however, 14C and archaeology are growing towards one another. One of the reasons might be the introduction of small exclusively 14C-dedicated machines and the availability of fully automatic graphitization lines.

Two recently published sets of radiocarbon dates, one from Mesopotamia and one from Anatolia, gave anomalous results. On the basis of historical analysis, both sets were expected to date to the 7th century BC. However, the 14C results were more than a century older than this. We tested samples from an Egyptian mummy, also historically dated to the 7th century BC, to see if such discrepancies were more widespread at this time. We did not find evidence of such a problem, but the results do provide insights into the reuse of old wood in ancient Egyptian coffins. We include publication of an earlier set of dates from the same mummy and coffin set.

Construction of a new science complex in Osong, Cheongwon-gun, Korea, has allowed the investigation of 14 different Paleolithic localities, excavated during 2005–2007. Here, we investigated localities 1 and 12 of the Mansuri Paleolithic site to obtain chronological information using radiocarbon dating. The soil deposition rates varied from 0.09 to 0.15 mm/yr over the period ranging from 33 to 31 kyr BP for locality 1. Locality 12 samples were more recent, <10 ka, and have similar accumulation rates, averaging 0.11 mm/yr. The soil ages of locality 12 were found to be younger than 10 kyr BP. Results for both soil and organic materials at this locality gave much younger ages at shallower depths than the ages expected by the Korean Paleolithic cultural history for this region. Therefore, these more recent deposits may not be associated with the cultural layers and are interpreted to have been hydrologically modified following emplacement. 14C dates of the soil and organic materials at locality 12 confirm that there is evidence for multiple human occupations throughout the last 9 kyr BP.

This article presents the results of interdisciplinary analysis of samples from the Czarnówko archaeological site in northern Poland, reporting the first radiocarbon dates for the site in comparison with its relative chronology. The site is of high importance because of its scale and opulence of artifacts. It was used for over 900 yr, from the 7th century BC up to the 3rd century AD, by populations of different cultures (the Lusatian, Pomeranian, Oksywie, and Wielbark). Samples of charcoal, wood, and textile were collected from different features, most of them from burials. Charcoal was taken from cremation pits, while wood was sampled from coffins in skeletal burials. Among samples collected during archaeological excavations in 2008 and 2010, 20 were chosen for 14C dating and macro- and microscopic observations. Images taken using a scanning electron microscope revealed the microstructure and preservation level of the specimens. An emphasis was also placed on geomorphological and geological research of the site area to gain information about the environmental conditions influencing the samples’ preservation state, e.g. pH, type, origin and permeability of sediment, and accumulation of organic matter. The obtained calibrated 14C ages are in agreement with the relative chronology based on the typology of artifacts and stratigraphic site reconstructions.

Carbon-based nanomaterials of different dimensions (1–3D, tubes, bundles, films, papers and sponges, graphene sheets) have been created and their characteristic properties have been discussed intensively in the literature. Due to their unique advantageous, tunable properties these materials became promising candidates in new generations of applications in many research laboratories and, recently, in industries as well. Protein-based bio-nanocomposites are referred to as materials of the future, which may serve as conceptual revolution in the development of integrated optical devices, e.g. optical switches, microimaging systems, sensors, telecommunication technologies or energy harvesting and biosensor applications. In our experiments, we designed various carbon-based nanomaterials either doped or not doped with nitrogen or sulfur during catalytic chemical vapor deposition synthesis. Radio- and isotope analytical studies have shown that the used starting materials, precursors and carriers have a strong influence on the geometry and physico-/chemical characteristics of the carbon nanotubes produced. After determining the 14C isotope constitution 53 m/m% balance was found in the reaction center protein/carbon nanotubes complex in a sensitive way that was prepared in our laboratory. The result is essential in determining the yield of conversion of light energy to chemical potential in this bio-hybrid system.

This list includes dates of geologic samples measured using a single-channel liquid scintillation 14C counter at the Geochemical and Statistical Laboratory, Tartu, Estonian SSR. Our modern standard is made of benzene enriched in 14C and its activity is checked with NBS oxalic acid standard sample. Dates are given in conventional radiocarbon years, based on the Libby half-life of 5570 ± 30 yr. AD 1950 is the reference year. Errors refer only to 1σ standard deviation calculated from count rates involved.

During the period between the IVth and IIIrd millennia BC, profound changes for the ancient populations inhabiting the northern region of Italy occurred. The first Indo-European migrations were altering the ethnographic characteristics and, with the production of the first copper artifacts, the Neolithic Age was drawing to an end. The most significant testimony of that dramatic period is unquestionably the Ötztal iceman. In addition, many other valuable archaeological sites, such as Alba (Cuneo, Italy), have been discovered. Although Alba produced the oldest evidence of copper objects in a Neolithic context (5380 ± 40 BP; GX-25859-AMS), more recent discoveries have underlined the importance of this archaeological site. In this paper we will report on a series of radiocarbon measurements of bone remnants which, combined with morphologic, stratigraphic, paleoanthropologic, and paleopathologic studies, have allowed us to gain new insights into the culture and chronology of the European Copper Age.

The authors have developed an active absorption system combining a molecular sieve with a pressure gradient as a way to overcome the shortcomings of the phosphoric acid solution displacement method. Taking advantage of the pressure gradient produced between the inside and outside of a bottle, as water moves through it, CO2 in the atmosphere can actively be absorbed onto a molecular sieve in its pathway. A comparative study showed that the technique was in agreement with the phosphoric acid displacement method, within error. We applied the new method to collect not only atmospheric CO2 samples, but also CO2 samples from soil respiration to verify its utility. Simple yet practical, our method is well suited to extended collection times in a variety of environments, and capable of providing relatively large amounts of carbon for high-precision accelerator mass spectrometry (AMS) 14C analyses of atmospheric samples.