Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-30T10:44:01.373Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface modification of microporous carbonaceous fiber for the growth of zinc oxide micro/nanostructures for the decontamination of malathion

Published online by Cambridge University Press:  26 January 2018

Ashitha Gopinath  and
Krishna Kadirvelu
Ashitha Gopinath
Affiliation:
DRDO-BU Center for Life Sciences, Bharathiar University Campus, Coimbatore 641046, India
Krishna Kadirvelu*
Affiliation:
DRDO-BU Center for Life Sciences, Bharathiar University Campus, Coimbatore 641046, India
*
Address all correspondence to Krishna Kadirvelu at [email protected]
Get access

Abstract

Nitric acid oxidation at various concentrations was used to change the surface chemistry of activated carbon fiber (ACF). Boehm titration, zeta potential results confirmed the presence of acidic functional groups on the surface of ACF. Physicochemical characterizations verified the growth of zinc oxide (ZnO) on surface-oxidized fiber. ZnO/ACF rods and flowers formed at pH 7 and 9 were used for decontamination of malathion at solution pH in the presence of ultrasonic waves and ultraviolet radiations. The disappearance of malathion in the solution followed pseudo-first-order kinetics. Total organic carbon analysis confirmed the decontamination of malathion in aqueous media.

Type
Research Letters
Information
MRS Communications , Volume 8 , Issue 1 , March 2018 , pp. 152 - 159
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Suzuki, M.: Activated carbon fiber: fundamentals and applications. Carbon 32, 577–586 (1994).CrossRefGoogle Scholar
2. Kadirvelu, K., Faur-Brasquet, C., and Cloirec, P.L.: Removal of Cu (II), Pb (II), and Ni (II) by adsorption onto activated carbon cloths. Langmuir 16, 8404–8409 (2000).Google Scholar
3. Subrenat, A.S. and Le Cloirec, P.A.: Volatile organic compound (VOC) removal by adsorption onto activated carbon fiber cloth and electrothermal desorption: an industrial application. Chem. Eng. Commun. 193, 478–486 (2006).Google Scholar
4. Chen, G., Wang, Y., Shen, Q., Song, Y., Chen, G., and Yang, H.: Synthesis and enhanced photocatalytic activity of 3D flowerlike ZnO microstructures on activated carbon fiber. Mater. Lett. 123, 145–148 (2014).Google Scholar
5. Thi, V.H.T. and Lee, B.K.: Great improvement on tetracycline removal using ZnO rod-activated carbon fiber composite prepared with a facile microwave method. J. Hazard. Mater. 324, 329–339 (2017).Google Scholar
6. Zhang, H., Wang, L., J.-F., and Tong and Yi, X.-S.: Preparation of zinc oxide whisker on carbon fibers. Key Eng. Mater. 434–435, 790–792 (2010).Google Scholar
7. Fallah, R.N. and Azizian, S.: Removal of thiophenic compounds from liquid fuel by different modified activated carbon cloths. Fuel Process. Technol. 93, 45–52 (2012).Google Scholar
8. Aggarwal, D., Goyal, M., and Bansal, R.C.: Adsorption of chromium by activated carbon from aqueous solution. Carbon 37, 1989–1997 (1999).Google Scholar
9. Jain, A., Balasubramanian, R., and Srinivasan, M.P.: Tuning hydrochar properties for enhanced mesopore development in activated carbon by hydrothermal carbonization. Microporous Mesoporous Mater. 203, 178–185 (2015).Google Scholar
10. Hu, B., Wang, K., Wu, L., Yu, S.H., Antonietti, M., and Titirici, M.M.: Engineering carbon materials from the hydrothermal carbonization process of biomass. Adv. Mater. 22, 813–828 (2010).CrossRefGoogle ScholarPubMed
11. Jung, S.H., Oh, E., Lee, K.H., Yang, Y., Park, C.G., Park, W., and Jeong, S.H.: Sonochemical preparation of shape-selective ZnO nanostructures. Cryst. Growth Des. 8, 265–269 (2008).Google Scholar
12. Wang, J., Qu, F., and Wu, X.: Controlled synthesis and photocatalytic properties of three dimensional hierarchical ZnO microflowers. Mater. Express 3, 256–264 (2013).Google Scholar
13. Yukawa, R., Yamamoto, S., Ozawa, K., Emori, M., Ogawa, M., Yamamoto, S., Fujikawa, K., Hobara, R., Kitagawa, S., Daimon, H., and Sakama, H.: Electron-hole recombination on ZnO (0001) single-crystal surface studied by time-resolved soft x-ray photoelectron spectroscopy. Appl. Phy. Lett. 105, 151602 (2014).Google Scholar
14. Ilyas, S.U., Pendyala, R., and Marneni, N.: Dispersion behaviour and agglomeration effects of zinc oxide nanoparticles in ethanol–water mixtures. Mater. Res. Innov. 18(Suppl. 6), S6–179 (2014).Google Scholar
15. Shao, D., Wei, Q., Zhang, L., Cai, Y., and Jiang, S.: Surface functionalization of carbon nanofibers by sol–gel coating of zinc oxide. Appl. Surf. Sci. 254, 6543–6546 (2008).Google Scholar
16. Tonezzer, M. and Lacerda, R.G.: Integrated zinc oxide nanowires/carbon microfiber gas sensors. Sens. Actuators B 150, 517–522 (2010).Google Scholar
17. Mosayebi, E. and Azizian, S.: Study of copper ion adsorption from aqueous solution with different nanostructured and microstructured zinc oxides and zinc hydroxide loaded on activated carbon cloth. J. Mol. Liq. 214, 384–389 (2016).Google Scholar
18. Myint, M.T.Z., Al-Harthi, S.H., and Dutta, J.: Brackish water desalination by capacitive deionization using zinc oxide micro/nanostructures grafted on activated carbon cloth electrodes. Desalination 344, 236–242 (2014).CrossRefGoogle Scholar
19. Meng, J., Yang, B., Zhang, Y., Dong, X., and Shu, J.: Heterogeneous ozonation of suspended malathion and chlorpyrifos particles. Chemosphere 79, 394–400 (2010).Google Scholar
20. Kralj, M.B., Franko, M., and Trebse, P.: Photodegradation of organophosphorus insecticides–investigations of products and their toxicity using gas chromatography–mass spectrometry and AChE-thermal lens spectrometric bioassay. Chemosphere 67, 99–107 (2007).CrossRefGoogle Scholar
21. Donia, A.M., Atia, A.A., Hussien, R.A., and Rashad, R.T.: Comparative study on the adsorption of malathion pesticide by different adsorbents from aqueous solution. Desalination Water Treat. 47, 300–309 (2012).CrossRefGoogle Scholar
22. Singh, B., Kaur, J., and Singh, K.: Biodegradation of malathion by Brevibacillus sp. strain KB2 and Bacillus cereus strain PU. World J. Microbiol. Biotechnol. 28, 1133–1141 (2012).Google Scholar
23. Mohamed, K.A., Basfar, A.A., Al-Kahtani, H.A., and Al-Hamad, K.S.: Radiolytic degradation of malathion and lindane in aqueous solutions. Radiat. Phys. Chem. 78, 994–1000 (2009).Google Scholar
24. Athauda, T.J., Hari, P., and Ozer, R.R.: Tuning physical and optical properties of ZnO nanowire arrays grown on cotton fibers. Appl. Mater. Interfaces 5, 6237–6246 (2013).Google Scholar
25. Faur-Brasquet, C., Kadirvelu, K., and Le Cloirec, P.: Removal of metal ions from aqueous solution by adsorption onto activated carbon cloths: adsorption competition with organic matter. Carbon 40, 2387–2392 (2002).Google Scholar
26. Mangun, C.L., Benak, K.R., Daley, M.A., and Economy, J.: Oxidation of activated carbon fibers: effect on pore size, surface chemistry, and adsorption properties. Chem. Mater. 11, 3476–3483 (1999).Google Scholar
27. Hashisho, Z., Rood, M.J., Barot, S., and Bernhard, J.: Role of functional groups on the microwave attenuation and electric resistivity of activated carbon fiber cloth. Carbon 47, 1814–1823 (2009).Google Scholar
28. Chen, J.P. and Wu, S.: Acid/base-treated activated carbons: characterization of functional groups and metal adsorptive properties. Langmuir 20, 2233–2242 (2004).Google Scholar
29. Harry, I.D., Saha, B., and Cumming, I.W.: Effect of electrochemical oxidation of activated carbon fiber on competitive and noncompetitive sorption of trace toxic metal ions from aqueous solution. J. Colloid Interface Sci. 304, 9–20 (2006).CrossRefGoogle ScholarPubMed
30. Rouquerol, J., Rouquerol, F., Llewellyn, P., Maurin, G., and Sing, K.S.: Adsorption by Powders and Porous Solids: Principles, Methodology and Applications (Academic Press, Oxford, UK, 2013).Google Scholar
31. Zhang, S.J., Yu, H.Q., and Feng, H.M.: PVA-based activated carbon fibers with lotus root-like axially porous structure. Carbon 44, 2059–2068 (2006).CrossRefGoogle Scholar
32. Chiang, Y.C., Lee, C.C., and Lee, H.C.: Characterization of microstructure and surface properties of heat-treated PAN-and rayon-based activated carbon fibers. J Porous Mater. 14, 227–237 (2007).Google Scholar
33. Liu, W., Shi, M., Ma, E., and Zhao, G.: Microstructure and Properties of Liquefied Wood-Based Activated Carbon Fibers Prepared from Precursors and Carbon Fibers. Wood Fiber Sci. 46, 39–47 (2014).Google Scholar
34. Anand, A., Rani, N., Saxena, P., Bhandari, H., and Dhawan, S.K.: Development of polyaniline/zinc oxide nanocomposite impregnated fabric as an electrostatic charge dissipative material. Polym. Int. 64, 1096–1103 (2015).Google Scholar
35. Lee, Y.S., Kim, Y.H., Hong, J.S., Suh, J.K., and Cho, G.J.: The adsorption properties of surface modified activated carbon fibers for hydrogen storages. Catal. Today 120, 420–425 (2007).Google Scholar
36. Sepulveda-Guzman, S., Reeja-Jayan, B., de La Rosa, E., Torres-Castro, A., Gonzalez-Gonzalez, V., and Jose-Yacaman, M.: Synthesis of assembled ZnO structures by precipitation method in aqueous media. Mater. Chem. Phys. 115, 172–178 (2009).Google Scholar
37. Athauda, T.J., Le Page, W.S., Chalker, J.M., and Ozer, R.R.: High density growth of ZnO nanorods on cotton fabric enables access to a flame resistant composite. RSC Adv. 4, 14582–14585 (2014).CrossRefGoogle Scholar
38. Wang, J., Sun, W., Zhang, Z., Zhang, X., Li, R., Ma, T., Zhang, P., and Li, Y.: Sonocatalytic degradation of methyl parathion in the presence of micron-sized and nano-sized rutile titanium dioxide catalysts and comparison of their sonocatalytic abilities. J. Mol. Catal. A: Chem. 272, 84–90 (2007).Google Scholar
39. Madhavan, J., Kumar, P.S.S., Anandan, S., Grieser, F., and Ashokkumar, M.: Sonophotocatalytic degradation of monocrotophos using TiO2 and Fe 3+ . J. Hazard. Mater. 177, 944–949 (2010).Google Scholar
40. Ramos-Delgado, N.A., Hinojosa-Reyes, L., Guzman-Mar, I.L., Gracia-Pinilla, M.A., and Hernández-Ramírez, A.: Synthesis by sol–gel of WO3/TiO2 for solar photocatalytic degradation of malathion pesticide. Catal. Today 209, 35–40 (2013).Google Scholar
41. Kadam, A.N., Dhabbe, R.S., Kokate, M.R., Gaikwad, Y.B., and Garadkar, K.M.: Preparation of N doped TiO2 via microwave-assisted method and its photocatalytic activity for degradation of malathion. Spectrochim. Acta A: Mol. Biomol. Spectrosc. 133, 669–676 (2014).Google Scholar
Supplementary material: File

Ashitha and Kadirvelu supplementary material 1

Ashitha and Kadirvelu supplementary material

Download Ashitha and Kadirvelu supplementary material 1(File)
File 1.6 MB