Lamalunga Cave (Altamura, Southern Italy) is renowned for the discovery in 1993 of an excellently preserved Neanderthal skeleton. Given the importance of the findings and the potential use of Lamalunga speleothems for paleoclimate reconstructions, a detailed monitoring program was undertaken to investigate the connections between microclimate parameters and speleothem growth. The cave air temperature is characterized by annual sinusoidal cycles with increasing phase shift and decreasing thermal amplitude from ± 2.1°C to ± 0.04°C as a function of increasing rock overburden, and daily to sub-daily cycles induced by surface air pressure (SAP) variations characterized by strong 24-hour and 12-hour solar harmonic frequencies, with thermal amplitude decreasing from 0.0054°C to 0.0021°C in the deeper parts of the cave. The ventilation regime is mainly controlled by SAP fluctuations. Fast SAP rises can trigger “emptying events” during which most of the cave air is replaced and the CO2 concentration falls towards near-atmospheric values. The steady and gentle ventilation created by SAP fluctuations also influences the growth and morphology of calcite coralloids, with larger popcorn assemblages concentrated in the northern galleries and delicate branching morphologies prevailing along the South Gallery where stable temperature and relative humidity conditions occur. The study is a seminal example of how high-precision measurements of cave air temperature can provide a wealth of information on cave ventilation and thermal regime and provide valuable support for robust paleoclimate reconstruction from speleothems.

The thermal diffusivity of diopside, jadeite and enstatite were measured at simultaneous pressures and temperatures of up to 7 GPa and 1200 K using the X-radiographic Ångström method. The measurements herein show that the pressure dependency of thermal diffusivity in pyroxenes is significantly greater than in olivine or garnet and that in the MORB-layer of a subducting slab the thermal diffusivity of pyroxenes are a factor of 1.5 greater than that of olivine. The temperature dependence of all the data sets is well described by a low-order polynomial fit to 1/K and the pressure dependence is exponential in 1/K, formulations which are consistent with the damped harmonic oscillator model for thermal properties.

A new method to measure thermal diffusivity in samples at simultaneous high pressure and high temperature is presented. The sample is placed inside a cylindrical heater and subjected to a heater power that varies sinusoidally with time. The diffusion of the temperature variations into the sample is monitored using radiographic imaging of marker foils. This provides measurements of the phase lag and amplitude variation of the temperature cycle at a range of radii from the sample axis without the need for multiple thermocouples. The technique is tested using a NaCl sample at 4 GPa; the best-fit thermal diffusivity for NaCl at 4 GPa and 673 K is 2.4±0.5x10-6 m2/s.

This paper presents a relatively simple numerical method to investigate the flow and heat transfer of laminar power-law fluids over a semi-infinite plate in the presence of viscous dissipation and anisotropy radiation. On one hand, unlike most classical works, the effects of power-law viscosity on velocity and temperature fields are taken into account when both the dynamic viscosity and the thermal diffusivity vary as a power-law function. On the other hand, boundary layer equations are derived by Taylor expansion, and a mixed analytical/numerical method (a pseudosimilarity method) is proposed to effectively solve the boundary layer equations. This method has been justified by comparing its results with those of the original governing equations obtained by a finite element method. These results agree very well especially when the Reynolds number is large. We also observe that the robustness and accuracy of the algorithm are better when thermal boundary layer is thinner than velocity boundary layer.

We have studied the influence of experimental factors and specimen geometry on the quality of the mass spectra in copper (Cu) during pulsed-laser atom-probe tomography. We have evaluated the effects of laser pulse energy, laser pulse frequency, specimen base temperature, specimen tip radius, and specimen tip shank half-angle on the effects of mass resolving power, (m/Δm), at full-width at half-maximum and at full-width at tenth-maximum, the tail size after the major mass-to-charge state (m/n) ratio peaks, and the mass spectra. Our results indicate that mass resolving power improves with decreasing pulse energy between 40 and 80 pJ and decreasing base temperature between 20 and 80 K. The mass resolving power also improves with increasing tip radius and shank half-angle. A pulse frequency of 250 kHz slightly improves the mass resolving power relative to 100 or 500 kHz. The tail size decreases with increasing pulse energy. The mass resolving power improves when the cooling time is reduced, which is influenced by the thermal diffusivity of Cu and the specimen base temperature.

L'objectif de l'étude est de caractériser thermiquement des nouveaux matériaux, utilisés dans les protections thermiques : les matériaux thermo-dégradables. À cet effet, des moyens de mesure répondant aux spécificités, intrinsèques et d'utilisations, des matériaux thermo-dégradables ont été développés par l'onera.