A method for constructing a pair of biorthogonal interpolatory multiscaling functions is given and an explicit formula for constructing the corresponding biorthogonal multiwavelets is obtained. A multiwavelet sampling theorem is also established. In addition, we improve the stability of the biorthogonal interpolatory multiwavelet frame by the linear combination of a pair of biorthogonal interpolatory multiwavelets. Finally, we give an example illustrating how to use our method to construct biorthogonal interpolatory multiscaling functions and corresponding multiwavelets.